SAFETY DATA SHEET Epoxy hardener 43 Fast

Transcription

1 Epoxy hardener 43 Fast Page 1 of 5 SAFETY DATA SHEET Epoxy hardener 43 Fast 1. Identification of the substance/preparation and of the company/undertaking Date issued Product name Epoxy hardener 43 Fast Article no Use of the substance/preparation Hardener for epoxy resin. Distributor Company name Färg-In AB Postal address Bodalsvägen 6 Postcode S City Kristinehamn Country SWEDEN Tel Fax ulf.lundgren@fargin.se Website Enterprise no. SE Contact person Ulf Lundgren Emergency telephone Poison control center:see National Thelephone Number (112) 2. Hazards identification Classification according to 67/548/EEC or 1999/45/EC Description of hazard C,N; R20/22,R34,R36/37/38,R42/43,R51/53 Causes burns. Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. Composition/information on ingredients Component name Identification Classification Contents Polyoxypropylenediamine CAS no.: C,Xn; R22,R34,R52/ % Alkylated polyamine adduct CAS no.: Xi; R36/37/38,R % Ethylenediamine CAS no.: EC no.: Index no.: R10 Xn; R21/22 R42/43 Flam. Liq. 3; H226 Acute tox. 4; H312 Acute tox. 4; H302 Resp. Sens. 1; H334 < 1 % Triethanolamine CAS no.: Xi; R36,R % Piperazine, liquid CAS no.: EC no.: Index no.: Rep 3; R62, R63 R42/43 < 2 %

2 Epoxy hardener 43 Fast Page 2 of 5 2-Piperazin-1-ylethylamine CAS no.: EC no.: Index no.: Repr. 2; H361fd Resp. Sens. 1; H334 Xn; R21/22 R43 R52, R53 Acute tox. 4; H312 Acute tox. 4; H302 Aquatic Chronic 3; H412 m-phenylenebis(methylamine) CAS no.: C; R20/22,R34,R43, % R52/53 p-tert-butylphenol CAS no.: Xi,N; R36/37/38,R51/ % Column headings CAS no. = Chemical Abstracts Service; EU (Einecs or Elincs number) = European inventory of Existing Commercial Chemical Substances; Ingredient name = Name as specified in the substance list (substances that are not included in the substance list must be translated, if possible). Contents given in; %, %wt/wt, %vol/wt, %vol/vol, mg/m3, ppb, ppm, weight%, vol% HH/HF/HE T+ = Very toxic, T = Toxic, C = Corrosive, Xn = Harmful, Xi = Irritating, E = Explosive, O = Oxidizing, F+ = Extremly flammable, F = Very flammable, N = Environmental hazard Component comments The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. < 1 % 4. First-aid measures General Inhalation Skin contact Eye contact Ingestion Contact physician if discomfort continues. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Move into fresh air and keep at rest. Get medical attention. Wash off promptly and flush contaminated skin with water. Promptly remove clothing if soaked through and flush skin with water. Contact physician if irritation continues. Promptly wash eyes with plenty of water while lifting the eye lids. Contact physician if irritation persists. DO NOT induce vomiting. Get medical attention immediately. 5. Fire fighting measures Suitable extinguishing media Improper extinguishing media Fire and explosion hazards Fire fighting procedures 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning Water spray, foam, dry powder or carbon dioxide. Do not use water jet as an extinguisher, as this will spread the fire. When heated and in case of fire, toxic vapours/gases may be formed. Use air-supplied respirator, gloves and protective goggles. Cool containers exposed to flames with water until well after the fire is out. Avoid contact with skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Avoid discharge into drains, water courses or onto the ground. Do not discharge into drains, water courses or onto the ground. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body. Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see section 13.

3 Epoxy hardener 43 Fast Page 3 of 5 7. Handling and storage Handling Storage Avoid contact with skin and eyes. Immediately change contaminated clothes. Store in closed original container in a dry place. Store at room temperature. Protect from heat and direct sunlight. Water reactive storage. 8. Exposure controls/personal protection Exposure limit values Component name Identification Value Year Piperazine, liquid CAS no.: EC no.: Index no.: Exposure controls Other Information about threshold limit values According to National regulations. 8 h.: 0,1 mg/m3 15 min.: 0,3 mg/m3 Occupational exposure controls Provide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded. Respiratory protection Gas mask with organic vapour canister and dust and mist filter. (typ NPF 20) When spraying use suitable air-supplied respirator. Hand protection Wear protective gloves. Impermeable material. Use full length gloves. Hand protection: Nitrile. Butyl rubber. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Eye protection Wear tight-fitting goggles or face shield. Skin protection (other than of the hands) Other Information 9. Physical and chemical properties Physical state Colourless-pale yellow liquid. Odour Slight odour. Amine. Solubility in water Insoluble or slightly miscible. Specific gravity Value: kg/m3 (25 ºC) Comments, ph (as supplied) Strongly alkaline. Flash point Value: > 100 C Spontaneous combustability Value: > 200 C Viscosity Value: 0,05-0,2 Pa.s (25 ºC) 10. Stability and reactivity Wear suitable protective clothing as protection against splashing or contamination. When using do not eat, drink or smoke. Conditions to avoid Avoid heat. > 100 ºC Materials to avoid Strong oxidising substances. Strong acids. Hartser. Water, steam, water mixtures. Hazardous decomposition products None at ambient temperatures. Stability Stable under normal temperature conditions and recommended use. 11. Toxicological information Components' toxicological data Other information regarding health hazards Inhalation Harmful by inhalation. Irritating to respiratory system. Skin contact Strongly irritating. Prolonged contact may cause burns. 2011

4 Epoxy hardener 43 Fast Page 4 of 5 Eye contact Ingestion Sensitisation 12. Ecological information Components' toxicological data Other ecological information Ecotoxicity Mobility Environmental details, conclusion 13. Disposal considerations Product classified as hazardous waste Packaging classified as hazardous waste Specify the appropriate methods of disposal 14. Transport information Product name (national) Dangerous goods ADR Dangerous goods RID Dangerous goods IMDG Dangerous goods ICAO/IATA 15. Regulatory information Hazard symbol Irritating. Corrosive. Harmful: may cause lung damage if swallowed. Pulmonary sensitiser. May cause an allergic skin reaction. The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. The product has poor water-solubility. The product may not be released into soil, drains or waterways. Yes Yes Dispose of waste and residues in accordance with local authority requirements. AMINES, LIQUID, CORROSIVE, N.O.S. Hazard no.: 80 EmS: F-A, S-B Composition on the label Polyoxypropylenediamine: %, Alkylated polyamine adduct: %,

5 Epoxy hardener 43 Fast Page 5 of 5 R phrases S phrases Ethylenediamine: < 1 %, Triethanolamine: 1-10 %, Piperazine, liquid: < 2 %, 2-Piperazin-1-ylethylamine: < 1 %, m-phenylenebis(methylamine): %, p-tert-butylphenol: % R20/22 Harmful by inhalation and if swallowed. R34 Causes burns. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets. 16. Other information List of relevant H-phrases (Section 2 and 3). List of relevant R phrases (under headings 2 and 3). Checking quality of information Responsible for safety data sheet H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes Severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361fd Suspected of damaging fertility. Suspected of damaging the unborn child. H412 Harmful to aquatic life with long lasting effects. R10 Flammable. R20/22 Harmful by inhalation and if swallowed. R21/22 Harmful in contact with skin and if swallowed. R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment. R52 Harmful to aquatic organisms. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R53 May cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. R63 Possible risk of harm to the unborn child. This information is based on the information we knew at the time of preparation and they have been given in good faith and provided that the product is used under normal conditions and in accordance with the specified conditions of use. Any other use of the date indicated, eventually together with other products or processes, is at your own risk. Färg-In AB