: ELMOTHERM VA42 SPRAY

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the : Spray insulating varnish Substance/Mixture 1.3 Details of the supplier of the safety data sheet Company : ELANTAS Italia S.r.l. Strada Antolini Collecchio Italy Telephone : Telefax : address : msds.elantas.italia@altana.com 1.4 Emergency telephone number +39 (0) (8-17 h) 2. Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Flammable aerosols, Category 1 H222: Extremely flammable aerosol. Skin irritation, Category 2 H315: Causes skin irritation. Serious eye damage, Category 1 H318: Causes serious eye damage. Specific target organ toxicity - single H336: May cause drowsiness or dizziness. exposure, Category 3, Central nervous system Classification (67/548/EEC, 1999/45/EC) Extremely flammable Harmful Irritant 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Hazard pictograms : R12: Extremely flammable. R20/21: Harmful by inhalation and in contact with skin. R36: Irritating to eyes. Signal word : Danger Hazard statements : H222 Extremely flammable aerosol. 1 / 17

2 H315 H318 H336 Causes skin irritation. Causes serious eye damage. May cause drowsiness or dizziness. Precautionary statements : Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Storage: P403 + P233 Immediately call a POISON CENTER or doctor/ physician. Store in a well-ventilated place. Keep container tightly closed. Hazardous components which must be listed on the label: acetone methylpropan-1-ol Additional Labelling: EUH208 May produce an allergic reaction. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. S16 Keep away from sources of ignition - No smoking. S 2 Keep out of the reach of children. Contains: 2-butanone oxime 2.3 Other hazards No available. 3. Composition/ on ingredients 3.2 Mixtures Chemical nature : Polymer with pigment affinic groups Hazardous components Chemical Name CAS-No. EC-No. Registration number acetone Classification (67/548/EEC) F; R11 Xi; R36 Classification (REGULATION (EC) No 1272/2008) Flam. Liq. 2; H225 Eye Irrit. 2; H319 Concentration [%] >= 15 - < 20 2 / 17

3 R66 R67 STOT SE 3; H336 Xylene, mixture of isomers R10 Xn; R20/21 Xi; R38 Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 >= 12,5 - < 20 butanone F; R11 Xi; R36 R66 R67 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 >= 1 - < 3 2-methylpropan-1-ol R10 Xi; R37/38-R41 R67 Flam. Liq. 3; H226 STOT SE 3; H335, H336 Skin Irrit. 2; H315 Eye Dam. 1; H318 >= 1 - < 3 cyclohexanone R10 Xn; R20/21/22 Xi; R38 Xi; R41 Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Acute Tox. 4; H302 2; H315 Eye Dam. 1; H318 >= 1 - < 3 2-butanone oxime Carc.Cat.3; R40 Xn; R21 Xi; R41 R43 Carc. 2; H351 Acute Tox. 4; H312 Eye Dam. 1; H318 Skin Sens. 1; H317 >= 0,1 - < 0,25 WEL substance : dimethyl ether F+; R12 Flam. Gas 1; H220 Press. Gas >= 30 - < 50 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled : Move to fresh air. Consult a physician after significant exposure. 3 / 17

4 In case of skin contact In case of eye contact If swallowed : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Dry powder Water spray Alcohol-resistant foam Carbon dioxide (CO2) 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. 5.3 Advice for firefighters Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. : Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. 4 / 17

5 6.2 Environmental precautions Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material and dispose of as hazardous waste. 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion : Avoid exceeding of the given occupational exposure limits (see section 8). Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Container may be opened only under exhaust ventilation hood. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. : Use explosion-proof equipment. Keep away from sources of ignition - No smoking. Do not spray on a naked flame or any incandescent material. Take measures to prevent the build up of electrostatic charge. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Store in cool place. Electrical installations / working materials must comply with the technological safety standards. Other data : No decomposition if stored and applied as directed. 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Value Control Update Basis 5 / 17

6 dimethyl ether parameters TWA ppm mg/m /39/EC : Indicative TWA 400 ppm 766 mg/m3 STEL 500 ppm 958 mg/m3 acetone TWA 500 ppm mg/m /39/EC : Indicative TWA 500 ppm mg/m3 STEL ppm mg/m3 Xylene, mixture of isomers TWA 50 ppm 220 mg/m3 : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL 100 ppm 441 mg/m3 : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. TWA 50 ppm 221 mg/m /39/EC : skin: Identifies the possibility of significant uptake through the skin Indicative STEL 100 ppm 442 mg/m /39/EC : skin: Identifies the possibility of significant uptake through the skin 6 / 17

7 Indicative butanone TWA 200 ppm 600 mg/m /39/EC : Indicative STEL 300 ppm 900 mg/m /39/EC : Indicative TWA 200 ppm 600 mg/m3 : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL 300 ppm 899 mg/m3 : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. 2- methylpropa n-1-ol TWA 50 ppm 154 mg/m3 STEL 75 ppm 231 mg/m3 cyclohexano ne TWA 10 ppm 40,8 mg/m /39/EC : skin: Identifies the possibility of significant uptake through the skin Indicative STEL 20 ppm 81,6 mg/m /39/EC : skin: Identifies the possibility of significant uptake through the skin Indicative TWA 10 ppm : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. 7 / 17

8 STEL 20 ppm : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. DNEL acetone : Potential health effects: Acute local effects Value: 2420 mg/m3 Potential health effects: Long-term exposure Value: 1210 mg/m3 Exposure routes: Skin contact Potential health effects: Long-term exposure 186 mg/kg Exposure routes: Skin contact Potential health effects: Long-term exposure 62 mg/kg Potential health effects: Long-term exposure Value: 200 mg/m3 Exposure routes: Ingestion Potential health effects: Long-term exposure 62 mg/kg Xylene, mixture of isomers : Potential health effects: Acute effects, Short-term exposure, Systemic effects Value: 289 mg/m3 Potential health effects: Acute effects, Short-term exposure, Local effects Value: 289 mg/m3 Exposure routes: Skin contact 8 / 17

9 180 mg/kg Value: 77 mg/m3 Potential health effects: Short-term exposure, Systemic effects Value: 174 mg/m3 Potential health effects: Short-term exposure, Local effects Value: 174 mg/m3 Exposure routes: Skin contact 108 mg/kg Exposure routes: Ingestion 1,6 mg/kg Value: 14,8 mg/m3 2-methylpropan-1-ol : Potential health effects: Long-term local effects Value: 310 mg/m3 Exposure routes: Ingestion Potential health effects: Long-term systemic effects 25 mg/kg Potential health effects: Long-term local effects Value: 55 mg/m3 cyclohexanone : Potential health effects: Short-term exposure, Systemic effects Value: 80 mg/m3 Exposure routes: Skin contact 9 / 17

10 Potential health effects: Short-term exposure, Systemic effects 4 mg/kg Potential health effects: Short-term exposure, Local effects Value: 80 mg/m3 Exposure routes: Skin contact 4 mg/kg Value: 40 mg/m3 Potential health effects: Long-term exposure, Local effects Value: 40 mg/m3 Exposure routes: Skin contact Potential health effects: Short-term exposure, Systemic effects 1 mg/kg Potential health effects: Short-term exposure, Systemic effects Value: 20 mg/m3 Exposure routes: Ingestion Potential health effects: Short-term exposure, Systemic effects 1,5 mg/kg Potential health effects: Short-term exposure, Local effects Value: 40 mg/m3 Exposure routes: Skin contact 1 mg/kg Value: 10 mg/m3 Exposure routes: Ingestion 10 / 17

11 1,5 mg/kg Potential health effects: Local effects Value: 20 mg/m3 PNEC acetone : Fresh water Value: 10,6 mg/l Marine water Value: 1,06 mg/l Fresh water sediment Value: 30,4 mg/kg Marine sediment Value: 3,04 mg/kg Soil Value: 29,5 mg/kg Intermittent releases Value: 21 mg/l Sewage treatment plant Value: 19,5 mg/l Xylene, mixture of isomers : Fresh water Value: 0,327 mg/l Marine water Value: 0,327 mg/l Fresh water sediment Value: 12,46 mg/kg Marine sediment Value: 12,46 mg/kg Soil Value: 2,31 mg/kg Sewage treatment plant Value: 6,58 mg/l Intermittent releases Value: 0,327 mg/l 2-methylpropan-1-ol : Fresh water Value: 0,4 mg/l 11 / 17

12 Marine water Value: 0,04 mg/l Fresh water sediment Value: 1,52 mg/kg Marine sediment Value: 0,152 mg/kg Soil Value: 0,0699 mg/kg Sewage treatment plant Value: 10 mg/l Intermittent releases Value: 11 mg/l cyclohexanone : Fresh water Value: 0,0329 mg/l Marine water Value: 0,0329 mg/l Fresh water sediment Value: 0,0951 mg/kg Marine sediment Value: 0,0512 mg/kg Soil Value: 0,0143 mg/kg Sewage treatment plant Value: 10 mg/l Intermittent releases Value: 1 mg/l 8.2 Exposure controls Personal protective equipment Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. Organic vapour type Hand protection Eye protection : Solvent-resistant gloves The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Before removing gloves clean them with soap and water. : Eye wash bottle with pure water Safety glasses with side-shields conforming to EN / 17

13 Skin and body protection Hygiene measures Protective measures : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing Environmental exposure controls General advice : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : aerosol Colour : dark red Flash point : < -1 C Auto-ignition temperature : > 250 C Initial boiling point : < 35 C Density : 0,76 g/cm3 10. Stability and reactivity 10.1 Reactivity Stable under recommended storage conditions Chemical stability No decomposition if stored and applied as directed Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions., No decomposition if used as directed Conditions to avoid Conditions to avoid : Heat, flames and sparks Incompatible materials 13 / 17

14 Materials to avoid : Strong acids and strong bases Strong oxidizing agents Strong reducing agents 10.6 Hazardous decomposition products Hazardous decomposition products : Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke. 11. Toxicological 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity : Acute toxicity estimate: > 2.000,00 mg/kg Method: Calculation method Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Skin irritation : Acute toxicity estimate: > 5 mg/l Exposure time: 4 h Method: Calculation method : Acute toxicity estimate: > mg/kg Method: Calculation method : May cause skin irritation in susceptible persons. Serious eye damage/eye irritation Eye irritation : According to the classification criteria of the European Union, the product is not considered as being an eye irritant. Respiratory or skin sensitisation Sensitisation : No data available : Solvents may degrease the skin. 12. Ecological 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential Bioaccumulation : This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vpvb) Mobility in soil 14 / 17

15 12.5 Results of PBT and vpvb assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher Other adverse effects Additional ecological : There is no data available for this product. 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Offer surplus and non-recyclable solutions to a licensed disposal company. : Empty remaining contents. Empty pressure vessels should be returned to the supplier. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. 14. Transport Land transport ADR / RID: Class: 2 Packaging group: UN number: 1950 ADR/RID-Labels: 2.1 Description of the goods: AEROSOLS, FLAMMABLE Sea transport IMDG: Class: 2.1 Packaging group: UN number: 1950 Labels: 2.1 EmS: F-D S-U Description of the goods: AEROSOLS, FLAMMABLE Marine pollutant no Air transport IATA-DGR : Class: 2.1 Packaging group: II UN/ID No.: UN / 17

16 Labels: 2.1 Description of the goods: Aerosols, flammable 15. Regulatory 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57). Major Accident Hazard Legislation : 96/82/EC Update: Extremely flammable 8 Quantity 1: 10 t Quantity 2: 50 t 15.2 Chemical Safety Assessment 16. Other Full text of R-phrases referred to under sections 2 and 3 R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R20/21 Harmful by inhalation and in contact with skin. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R21 Harmful in contact with skin. R36 Irritating to eyes. R37/38 Irritating to respiratory system and skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Full text of H-Statements referred to under sections 2 and / 17

17 H220 H222 H225 H226 H302 H312 H315 H317 H318 H319 H332 H335 H336 H351 Training advice Extremely flammable gas. Extremely flammable aerosol. Highly flammable liquid and vapour. Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. : Provide adequate, instruction and training for operators. The contained herein is based on the present state of our knowledge and does therefore not guarantee certain properties. 17 / 17