Version 2.0 SDB_GB Revision Date Print Date Identification of the substance/mixture and of the company/undertaking

Transcription

1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the : Insulating varnish Substance/Mixture 1.3 Details of the supplier of the safety data sheet Company : ELANTAS Italia S.r.l. Strada Antolini Collecchio Italy Telephone : Telefax : address : msds.elantas.italia@altana.com 1.4 Emergency telephone number +39 (0) (8-17 h) 2. Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Flammable Harmful Irritant R10: Flammable. R20/21: Harmful by inhalation and in contact with skin. R38: Irritating to skin. 2.2 Label elements Labelling (REGULATION (EC) No 1272/2008) Labelling according to EC Directives (1999/45/EC) Hazard pictograms : Harmful R-phrase(s) : R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. S-phrase(s) : S36/37 Wear suitable protective clothing and gloves. 1 / 13

2 S60 This material and its container must be disposed of as hazardous waste. Hazardous components which must be listed on the label: Xylene, mixture of isomers Sensitising components : 2-butanone oxime cobalt bis(2-ethylhexanoate) May produce an allergic reaction. 2.3 Other hazards No information available. 3. Composition/information on ingredients 3.2 Mixtures Chemical nature : Alkyd Resin Solution Hazardous components Chemical Name Xylene, mixture of isomers CAS-No. EC-No. Registration number Classification (67/548/EEC) R10 Xn; R20/21 Xi; R38 Classification (REGULATION (EC) No 1272/2008) Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 Concentration [%] >= 30 - < 50 Reaction mass of ethyl benzene and xylene R10 Xn; R20/21 Xi; R38 Flam. Liq. 3; H226 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 Eye Irrit. 2; H319 STOT SE 3; H335 STOT RE 2; H373 Asp. Tox. 1; H304 >= 7 - < 10 2-butanone oxime Carc.Cat.3; R40 Xn; R21 Xi; R41 R43 Carc. 2; H351 Acute Tox. 4; H312 Eye Dam. 1; H318 Skin Sens. 1; H317 >= 0,25 - < 0,5 2-hydroxybiphenyl Xi; R36/37/38 N; R50 Eye Irrit. 2; H319 STOT SE 3; H335 Skin Irrit. 2; H315 Aquatic Acute 1; H400 >= 0,25 - < 0,5 2 / 13

3 low boiling point hydrogen treated naphtha N; R51/53 Xn; R65 R10 R66 R67 STOT SE 3; H336 Asp. Tox. 1; H304 Aquatic Chronic 2; H411 Flam. Liq. 3; H226 >= 0,1 - < 0,25 cobalt bis(2- ethylhexanoate) Xn; R22 N; R50/53 Xi; R38 R43 Xn; Repr.Cat.3; R62 Acute Tox. 4; H302 Skin Irrit. 2; H315 Skin Sens. 1; H317 Repr. 2; H361f Aquatic Acute 1; H400 Aquatic Chronic 1; H410 >= 0,1 - < 0,25 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled In case of skin contact In case of eye contact If swallowed : Move to fresh air. Consult a physician after significant exposure. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. : Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. Obtain medical attention. 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Alcohol-resistant foam Dry chemical 5.2 Special hazards arising from the substance or mixture 3 / 13

4 Specific hazards during firefighting 5.3 Advice for firefighters Special protective equipment for firefighters Further information : Do not allow run-off from fire fighting to enter drains or water courses. : In the event of fire, wear self-contained breathing apparatus. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Use personal protective equipment. Ensure adequate ventilation. 6.2 Environmental precautions Environmental precautions : Do not flush into surface water or sanitary sewer system. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion : Avoid exceeding of the given occupational exposure limits (see section 8). Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. : Avoid formation of aerosol. Keep away from sources of ignition - No smoking. Take measures to prevent the build up of electrostatic charge. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : No smoking. Keep container tightly closed in a dry and well-ventilated 4 / 13

5 place. Other data : No decomposition if stored and applied as directed. 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Value Control parameters Xylene, TWA 50 ppm mixture of 220 mg/m3 isomers Update Basis GB EH40 Further information : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. STEL 100 ppm 441 mg/m GB EH40 Further information : Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. TWA 50 ppm 221 mg/m /39/EC Further information : skin: Identifies the possibility of significant uptake through the skin Indicative STEL 100 ppm 442 mg/m /39/EC Further information cobalt bis(2- ethylhexanoa te) Further information : skin: Identifies the possibility of significant uptake through the skin Indicative TWA 0,1 mg/m GB EH40 : 53+54: Substances that can cause occupational asthma (also known as asthmagens and respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an immunological, irritant or other mechanism. Once the airways have become hyper-responsive, further exposure to the substance, sometimes even to tiny quantities, may cause respiratory symptoms. These symptoms can range in severity from a runny nose to asthma. Not all workers who are exposed to a sensitiser will become hyper-responsive and it is impossible to identify in advance those who are likely to become hyper-responsive. 54 Substances that can cause occupational asthma should be distinguished from substances which may trigger the symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not include the disease themselves. The latter substances are not classified asthmagens or respiratory sensitisers. Wherever it is reasonably practicable, exposure to substances that can cause occupational asthma should be prevented. Where this is not possible, the primary aim is to apply adequate standards of control to prevent workers from becoming hyper-responsive. For substances that can cause occupational asthma, COSHH requires that exposure be reduced as low as is 5 / 13

6 reasonably practicable. Activities giving rise to short-term peak concentrations should receive particular attention when risk management is being considered. Health surveillance is appropriate for all employees exposed or liable to be exposed to a substance which may cause occupational asthma and there should be appropriate consultation with an occupational health professional over the degree of risk and level of surveillance. Capable of causing occupational asthma. The identified substances are those which: - are assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication 'Asthmagen? Critical assessments of the evidence for agents implicated in occupational asthma' as updated from time to time, or any other substance which the risk assessment has shown to be a potential cause of occupational asthma. Capable of causing cancer and/or heritable genetic damage. The identified substances include those which: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may cause heritable genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or process listed in Schedule 1 of COSHH. Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used Carcinogenic applies for cobalt dichloride and sulphate. The 'Sen' notation in the list of WELs has been assigned only to those substances which may cause occupational asthma. Cobalt DNEL Xylene, mixture of isomers : End Use: Workers Potential health effects: Acute effects, Short-term exposure, Systemic effects Value: 289 mg/m3 End Use: Workers Potential health effects: Acute effects, Short-term exposure, Local effects Value: 289 mg/m3 End Use: Workers Exposure routes: Skin contact Potential health effects: Long-term exposure, Systemic effects 180 mg/kg End Use: Workers Potential health effects: Long-term exposure, Systemic effects Value: 77 mg/m3 Potential health effects: Short-term exposure, Systemic effects Value: 174 mg/m3 Potential health effects: Short-term exposure, Local effects Value: 174 mg/m3 6 / 13

7 Exposure routes: Skin contact Potential health effects: Long-term exposure, Systemic effects 108 mg/kg Exposure routes: Ingestion Potential health effects: Long-term exposure, Systemic effects 1,6 mg/kg Potential health effects: Long-term exposure, Systemic effects Value: 14,8 mg/m3 low boiling point hydrogen treated naphtha : End Use: Workers Potential health effects: Long-term systemic effects Value: 330 mg/m3 End Use: Workers Exposure routes: Skin contact Potential health effects: Long-term systemic effects 44 mg/kg Potential health effects: Long-term systemic effects Value: 71 mg/m3 Exposure routes: Skin contact Potential health effects: Long-term systemic effects 26 mg/kg Exposure routes: Ingestion Potential health effects: Long-term systemic effects 26 mg/kg PNEC Xylene, mixture of isomers : Fresh water Value: 0,327 mg/l Marine water Value: 0,327 mg/l Fresh water sediment Value: 12,46 mg/kg Marine sediment Value: 12,46 mg/kg Soil 7 / 13

8 Value: 2,31 mg/kg Sewage treatment plant Value: 6,58 mg/l Intermittent releases Value: 0,327 mg/l 8.2 Exposure controls Engineering measures Use only appropriately classified electrical equipment and powered industrial trucks. Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an approved filter. Hand protection Eye protection Skin and body protection Hygiene measures Protective measures : Solvent-resistant gloves The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Before removing gloves clean them with soap and water. : Eye wash bottle with pure water Tightly fitting safety goggles : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. : Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. : Ensure that eye flushing systems and safety showers are located close to the working place. Do not wear contact lenses. Environmental exposure controls General advice : Do not flush into surface water or sanitary sewer system. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : orange Odour : characteristic 8 / 13

9 Flash point : 27 C Lower explosion limit Upper explosion limit : 0,8 %(V) : 7 %(V) Auto-ignition temperature : > 400 C Boiling point/boiling range : C Density : g/l at 20 C 10. Stability and reactivity 10.1 Reactivity Stable under recommended storage conditions Chemical stability No decomposition if stored and applied as directed Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions., No decomposition if used as directed. : Vapours may form explosive mixture with air Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid : Heat, flames and sparks. : Strong acids and strong bases Strong oxidizing agents Strong reducing agents Alkali metals Alkaline earth metals 10.6 Hazardous decomposition products Hazardous decomposition products : Stable under recommended storage conditions. Heating can release vapours which can be ignited. Burning produces noxious and toxic fumes. : Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke. 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity 9 / 13

10 Skin corrosion/irritation Skin irritation : May cause skin irritation and/or dermatitis. Serious eye damage/eye irritation Eye irritation : Vapours may cause irritation to the eyes, respiratory system and the skin. Respiratory or skin sensitisation Sensitisation : No data available Further information : Solvents may degrease the skin. 12. Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher Other adverse effects Additional ecological : There is no data available for this product. information 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Offer surplus and non-recyclable solutions to a licensed disposal company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. 14. Transport information 14.1 UN number ADR : UN / 13

11 IMDG : UN 1263 IATA : UN UN proper shipping name ADR IMDG IATA 14.3 Transport hazard class(es) : PAINT : PAINT : Paint ADR : 3 IMDG : 3 IATA : Packing group ADR Packing group : III Classification Code : F1 Hazard Identification Number : 33 Labels : 3 IMDG Packing group : III Labels : 3 EmS Code : F-E S-E IATA Packing instruction (cargo : 366 aircraft) Packing instruction : 355 (passenger aircraft) Packing group : III Labels : Environmental hazards ADR Environmentally hazardous IMDG Marine pollutant : no : no 14.6 Special precautions for user not applicable 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 11 / 13

12 REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). Major Accident Hazard Legislation : This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57). : 96/82/EC Update: Flammable. 6 Quantity 1: t Quantity 2: t : 96/82/EC Update: Petroleum products: (a) gasolines and naphthas, (b) kerosenes (including jet fuels), (c) gas oils (including diesel fuels, home heating oils and gas oil blending streams) 13 Quantity 1: t Quantity 2: t 15.2 Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R21 Harmful in contact with skin. R22 Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Full text of H-Statements referred to under sections 2 and / 13

13 H226 H302 H304 H312 H315 H317 H318 H319 H332 H335 H336 H351 H361f H373 H400 H410 H411 Further information Training advice Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Harmful if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Suspected of damaging fertility. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. : Provide adequate information, instruction and training for operators. The information contained herein is based on the present state of our knowledge and does therefore not guarantee certain properties. 13 / 13