Material Safety Data Sheet Ammonium dichromate MSDS# Section 1 - Chemical Product and Company Identification MSDS Name: Ammonium dichromate
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1 Material Safety Data Sheet Ammonium dichromate MSDS# Section 1 - Chemical Product and Company Identification MSDS Name: Ammonium dichromate Catalog Numbers: , , A/4400/50, A/4400/53, A/4400/60, A/4400/65, A/4440/50, A/4440/60 Synonyms: Ammonium bichromate; Ammonium dichromate(vi). Company Identification: Fisher Scientific UK Bishop Meadow Road, Loughborough Leics. LE11 5RG For information in Europe, call:(01509) Emergency Number, Europe: Section 2 - Composition, Information on Ingredients CAS#: Chemical Name: Ammonium dichromate %: 99 EINECS#: Hazard Symbols: T+ N E Risk Phrases: / /53 8 Section 3 - Hazards Identification EMERGENCY OVERVIEW Explosive when dry. Harmful in contact with skin. Toxic if swallowed. Very toxic by inhalation. Irritating to respiratory system and skin. Risk of serious damage to eyes. May cause sensitization by skin contact. May cause heritable genetic damage. Contact with combustible material may cause fire. May cause cancer by inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.cancer suspect agent. Potential Health Effects Eye: May cause severe eye irritation and possible injury. Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be harmful if absorbed through the skin. Ingestion: Harmful if swallowed. Inhalation: May be fatal if inhaled. Causes respiratory tract irritation. Chronic: Prolonged or repeated inhalation may cause nosebleeds, nasal congestion, erosion of the teeth, perforation of the nasal septum, chest pain and bronchitis. Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause sensitization dermatitis and possible destruction and/or ulceration. May cause liver and kidney damage. May cause cancer in humans. Section 4 - First Aid Measures Eyes:
2 Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes. Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask. Notes to Physician: Persons with asthma, allergies, and know sensitization to chromic acid or chromates may be at increased risk from exposure to this product. Effects may be delayed. For methemoglobinemia, administer oxygen alone or with Methylene Blue depending on the methemoglobin concentration in the blood. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. This material poses an explosion hazard when dry. Extinguishing Media: Use water only! Contact professional fire-fighters immediately. Cool containers with flooding quantities of water until well after fire is out. For large fires, flood fire area with water from a distance. Do NOT use dry chemicals, CO2, Halon or foams. Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Wet area to prevent drying out. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill. Keep combustibles (wood, paper, oil, etc.,) away from spilled material. Section 7 - Handling and Storage
3 Handling: dust Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Minimize generation and accumulation. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not store near combustible materials. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Do not store near combustible materials. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from acids. Keep away from reducing agents. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# : United Kingdom, WEL - TWA: ( chromium (vi) compounds): 0.05 mg/m3 TWA (as Cr) United Kingdom, WEL - STEL: ( chromium (vi) compounds): 0.15 mg/m3 STEL (as Cr) United States OSHA: 5 µg/m3 TWA (Chromium (VI) compounds).0.1 mg/m3 Ceiling (as CrO3, applies to any operations or sectors for which the H exavalent Chromium standard [29 CFR ] is stayed or is otherwise not in effect) (Chromates).2.5 µg/m3 Action Level (as Cr.); 5 Belgium - TWA: ( chromium (vi) compounds- water soluble): 0.05 mg/m3 VLE (as Cr) France - VME: ( chromium (vi) compounds): 0.05 mg/m3 VME (as Cr) Germany: ( chromium (vi) compounds): 0.05 mg/m3 VME (as Cr) Japan: ( chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr); 0.01 mg/m3 OEL (certain compounds, as Cr) Malaysia: ( chromium (vi) compounds- water soluble): 0.05 mg/m3 TWA (as Cr) Netherlands: ( chromium (vi) compounds- water soluble): 0.05 mg/m3 STEL Netherlands: ( chromium (vi) compounds- water soluble): mg/m3 MAC Spain: 0.05 mg/m3 VLA-ED (as Cr) Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin
4 exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - Physical and Chemical Properties Physical State: Crystals Color: orange to red Odor: odorless ph: 3.45 for 10% soln. Vapor Pressure: Viscosity: Boiling Point: Freezing/Melting Point: 170 deg C ( F) Autoignition Temperature: 225 deg C ( deg F) Flash Point: Explosion Limits: Lower: Explosion Limits: Upper: Decomposition Temperature: Solubility in water: Soluble Specific Gravity/Density: Molecular Formula: (NH4)2Cr2O7 Molecular Weight: Section 10 - Stability and Reactivity Chemical Stability: Stable. However, may decompose if heated. Conditions to Avoid: Ignition sources, dust generation, excess heat. Incompatibilities with Other Materials Reducing agents, strong acids, alcohols, aluminum, hydrazine, plastics, potassium chlorates, sodium nitrate, sulfur, combustible organics, carbides, wood. Hazardous Decomposition Products Oxides of nitrogen, toxic chromium oxide fumes. Hazardous Polymerization Will not occur. Section 11 - Toxicological Information RTECS#: CAS# : HX HX LD50/LC50: RTECS:. Other: Oral, rat: LD50 = 67.5 mg/kg; Inhalation, rat: LC50 = mg/l/4h; Dermal, rabbit: LD50 = 1640 mg/kg (reported by Bayer) Carcinogenicity: Ammonium dichromate - California: carcinogen, initial date 2/27/87 (Chromium (VI) compounds). NTP: Known carcinogen (Chromium (VI) compounds). IARC: Group 1 carcinogen Other: No information found. Section 12 - Ecological Information Ecotoxicity: Fish: Mosquito Fish: LC50 = 136 mg/l; 96 Hr; UnspecifiedFish: Mosquito Fish: LC50 = 212 mg/l; 48 Hr; Unspecified Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations.
5 Section 14 - Transport Information IATA Shipping Name: AMMONIUM DICHROMATE Hazard Class: 5.1 UN Number: 1439 Packing Group: II IMO Shipping Name: AMMONIUM DICHROMATE Hazard Class: 5.1 UN Number: 1439 Packing Group: II RID/ADR Shipping Name: AMMONIUM DICHROMATE Hazard Class: 5.1 UN Number: 1439 Packing Group: II USA RQ: CAS# : 10 lb final RQ; 4.54 kg final RQ Section 15 - Regulatory Information European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T+ N E Risk Phrases: R 46 May cause heritable genetic damage. R 49 May cause cancer by inhalation. R 1 Explosive when dry. R 21 Harmful in contact with skin. R 25 Toxic if swallowed. R 26 Very toxic by inhalation. R 37/38 Irritating to respiratory system and skin. R 41 Risk of serious damage to eyes. R 43 May cause sensitization by skin contact. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 8 Contact with combustible material may cause fire. Safety Phrases: S 53 Avoid exposure - obtain special instructions before use. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# : 3 Canada CAS# is listed on Canada's DSL List US Federal TSCA CAS# is listed on the TSCA Inventory. Section 16 - Other Information MSDS Creation Date: 7/19/1999 Revision #5 Date 8/18/2006
6 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages
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