Safety Data Sheet Organic Benzoin (Styrax tonkinensis & Ethanol) Resinoid 55% / Ethanol 45% Laos - GB-org-05

Transcription

1 2 4 CHATHAM PLACE, BR IGH TON, BN1 3 TN (U K) TE L. (U K) In tern ation al Tel info@nhror ganicoi ls.com Web Site: Safety Data Sheet Organic Benzoin (Styrax tonkinensis & Ethanol) Resinoid 55% / Ethanol 45% Laos - GB-org Identification of the substance & of the company PRODUCT Name: Benzoin Botanical Name: Styrax tokinensis Craib INCI Name: Styrax toninensis resin extract / alcohol Use: Fragrance or/and flavour substance N CAS EINECS / N EINECS (n EC) / N CAS TSCA / N CoE 439n/E1510 N FEMA 2133/2419 SUPPLIER Name of supplier: NHR Organic Oils, 24 Chatham Place, Brighton, BN1 3TN, UK Tel: 44 (0) info@nhrorganicoils.com 2. Hazard identification SUBSTANCE CLASSIFICATION Classification according to EC Regulation 1272/2008 Flam. Liq. 3 ( FL 3 ) - H226 - Flammable liquid and vapour. Acute Tox. 4 ( ATO 4 ) - H302 - Harmful if swallowed. Asp. Tox. 1 ( AH 1 ) - H304 - May be fatal if swallowed and enters airways. Skin Irrit. 2 ( SCI 2 ) - H315 - Causes skin irritation. Eye Irrit. 2 ( EDI 2 ) - H319 - Cause serious eye irritation. Skin Sens. 1 ( SS 1 ) - H317 - May cause an allergic skin reaction. Aquatic Chronic 3 ( EH C3 ) - H412 - Harmful to aquatic life with long lasting effects. Classification according to EC Regulation 67/548 Xn - Harmful R10 - Flammable R22 - Harmful if swallowed R36/38 - Irritating to eyes and skin R43 - May cause sensitisation by skin contact R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment LABELLING Hazard pictograms

2 GHS02 - H226 Flammable liquid and vapour GHS07 - H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation GHS08 - H302 Harmful if swallowed H317 May cause an allergic skin reaction. H319 Cause serious eye irritation. H412 Harmful to aquatic life with long lasting effects. Signal Word Danger Precautionary statements P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor, physician. P302 + P352 - IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 - Dispose of contents/the container in accordance with current legislation. 3. Product Make Up TYPE Mixture of 100% natural compounds Called resinoid diluted in ethanol Organic product certified by Soil Association Certification Ltd DANGEROUS COMPOUNDS Classification according to EC Regulation 1272/2008 Benzoic acid < = 50% N CAS : N EINECS : Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319 Ethyl alcohol < = 45,00 % N CAS : N EINECS : Flam. Liq. 2, H225 Benzyl benzoate < = 4,00 % N CAS : N EINECS : Acute Tox. 4, H302; Aquatic Chronic 2, H411 Vanillin < = 3,00 % N CAS : N EINECS : Skin Sens. 1, H317

3 Isoeugenol < = 1,00 % N CAS : N EINECS : Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 Classification according to EC Regulation 67/548 Benzoic acid = 50% N CAS : N EINECS : Xn, R22, R36/38 Ethyl alcohol < = 45,00 % N CAS : N EINECS : F, R11 Benzyl benzoate < = 4,00 % N CAS : N EINECS : N, Xn, R22, R51/53 Vanillin < = 3,00 % N CAS : N EINECS : Xi, R43 Isoeugenol < = 1,00 % N CAS : N EINECS : Xn, R21/22, R36/38, R43 4. First Aid Measures Excessive inhalation: Remove victim to fresh air. Keep them warm and allow them to rest quietly. If harmful effects persist or worsen, call a doctor. If patient is unconscious, place them in the lateral recovery position and call a doctor immediately. Make sure the area is well ventilated. Skin contact: Rinse with plenty of water and change clothing if necessary. If irritation persists or if skin lesions of any kind appear, seek medical advice. Eye contact: Rinse immediately with plenty of running water (minimum 2 litres), opening the eyes wide under the tap. If possible, lift the upper eyelid and rinse. If irritation persists or if skin lesions of any kind appear, consult an eye specialist, taking the product with you. If you wear contact lenses, remove lenses and rinse your eyes immediately. Do not put them back in. Throw contaminated lenses away even if new. Do not wear contact lenses after the accident without the advice of an eye specialist. Ingestion: Rinse the mouth out with water. Remove victim to fresh air. Keep them warm and allow them to rest quietly. Do not induce vomiting unless otherwise directed by a medical professional. If vomiting occurs spontaneously, keep head low down to prevent aspiration into the lungs. If harmful effects persist or worsen, call a doctor. If patient is unconscious, place them in the lateral recovery position and call a doctor immediately. Make sure the area is well ventilated. Contact a poison specialist if large quantities have been ingested.

4 5. Fire-fighting measures Method of extinction Recommended: Carbon dioxide (CO2) or powder fire extinguisher Usable: Foam or alogenous fire extinguisher To avoid: Direct jet of water Particular protective measures when firefighting: appropriate protective Avoid exposure to fumes and vapour. If necessary, use clothing. PERSOL Remove all possible ignition sources. Ventilate the premises 6. Accidental release measures Do not smoke ENVIRONMENT Avoid contaminating drainage systems, surface and ground waters. Dispose of any contaminated cleaning equipment and empty containers in accordance with the regulations currently in place. 7. Handling and Storage SAFE HANDLING Avoid contact, do not inhale hot vapour, do not ingest, do not smoke, wear protective clothing. Do not touch or step in spilled product. Ensure adequate ventilation. Keep in original container or if needed, transfer into a glass or stainless steel container or any other approved container. Keep tightly sealed at all times. Do not reuse empty containers as they can hold residues. Do not discharge in the environment. STORE SAFELY Keep in original container Do not heat over a naked flame, do not expose the vapours to a naked flame or any other ignition source (hot surfaces, electrical equipment). Do not smoke when handling or standing in the vicinity of the product. If it is necessary to raise the temperature, do so over a bain-marie (over boiling water) and only for a short time. Earth all electrical equipment and check wiring regularly. Store in air tight containers, preferably in amber glass or stainless steel containers. Keep away from sunlight Avoid drastic changes in temperatures, try and keep temperature constant between 10 and 15 C. Store under a nitrogen blanket if possible. 8. Exposure controls / Personal protection Not regulated. Handle in well ventilated areas. Wear protective glasses, gloves and clothing. Follow usual hygiene rules. Keep working clothes separately. Keep away from food and beverages. Wash hands after work. Ensure easy access to a fire extinguisher 9. Physical & Chemical characteristics The characteristics herewith are determined by directive: 67/548/CEE, annex V, part A Colour Amber to reddish brown

5 Physical appearance Odour: Liquid Balsamic, sweet with hint of vanilla and ethanol Health, security and environment information PH: Boiling point Flash point: + 22ºC Melting Point: Flammability: Explosion limit: Combustions properties: Vapour pressure: Density at 20ºC: to Solubility in water: Insoluble Solubility in ethanol: Soluble Partition coefficient O / W: Viscosity: Vapour density: Evaporation rate: Others Refractive index: to Optical rotation: Auto ignition TºC Main Ingredients Benzoic acid - 14 to 50% Ethyl alcohol - 45% Benzyl benzoate - <= 3% Vanillin - <= 3% Alpha hydorxyacetophenone - <= 3% Reactivity: Chemical stability: 10. Stability & reactivity is shock, vibration and pressure resistant in proper storage and under normal usage conditions Stable over time if storage conditions described in 7 are observed. This product does not decompose under normal storage conditions, but will oxydize if exposed to heat and sun-light. 11. Toxicological information (RIFM, INRSD, IFRA monographs) The data below comes from the literature and research made available. NHR Organic Oils has not carried out or used any third party to carry out animal experimentation on any of their products. Oral toxicity: Skin irritation: Eye irritation: Respiratory sensitisation: Carcinogenicity: LD org.50 :3880 mg/kg for the rat Yes Yes, serious May cause an allergic skin reaction Not identified as a carcinogen

6 Mutagenicity: Carcinogenicity Information on fragrance ingredients Not identified as a mutagen None Not regulated Eco-toxicity: Mobility: Persistence and degradability: Bio-accumulative potential: Notice: 12. Ecological information Danger to aquatic environment according to Regulation (EC) 1272/2008 Low mobility in ground Low persistence level and high biodegradability The product does not result in any bio-accumulative phenomenon Bio-degradable product, however do not discharge into the natural environment (waters, sewage or water systems) 13. Waste consideration Do not discharge in drains or in water courses. Waste should be recycled and disposed of according to the legislation in place. 14. Transport information Comply with national and international regulations in force. Transport Rules Hazard class Packing Group UN number Dispatch Name Custom rate Code Road RID/ADR Sea IMDG 3 III 1169 Liquid Aromatic Extracts Air IATA-DGR 15. Other information The information which this safety data sheet contains is based on the state of our knowledge relating to the product concerned, at the date indicated. They are in conformity with the legislation in place and are given in good faith. The attention of the users is drawn to the possible incurred risks when a product is used for other uses than that for which it is in- tended. The user must take responsibility for the care and obligations which fall on to him in the storage and use of this product. Date: 25 March 2017