SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 907/2006/EC, Article 3 SECTION : Identification of the substance/mixture and of the company/undertaking.. Product identifier Product name.2. Relevant identified uses of the substance or mixture and uses advised against Product Use Description.3. Details of the supplier of the safety data sheet Company Address Web date / [SU2] Consumer uses: Private households (= general public = consumers); [PC9a] Coatings and paints, thinners, paint removers; [AC] Wood articles; Fiddes & Son Ltd Florence Works, Brindley Road, Cardiff, South Glamorgan, CF 8TX Telephone +44 (0) Fax +44 (0) address of the competent person.4. Emergency telephone number info@fiddes.co.uk info@fiddes.co.uk Emergency telephone number Company INFOTRAC 24HR SECTION 2: Hazards identification 2.. Classification of the substance or mixture 2... Classification - 999/45/ЕC Main hazards Classification - EC 272/ Label elements Hazard pictograms Xn; R20/2/22-65 Xi; R36/38-43 N; R5/53 R0 Symbols: Xn: Harmful. N: Dangerous for the environment. Flammable. Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Flam. Liq. 3: H226; Acute Tox. 4: H302; Asp. Tox. : H304; Skin Irrit. 2: H35; Skin Sens. : H37; Eye Irrit. 2: H39; Acute Tox. 4: H332; Aquatic Chronic 2: H4; Signal Word Hazard Statement Danger Flam. Liq. 3: H226 - Flammable liquid and vapour. Acute Tox. 4: H302 - Harmful if swallowed. Asp. Tox. : H304 - May be fatal if swallowed and enters airways. Skin Irrit. 2: H35 - Causes skin irritation. Copyright 205 ChemSoft Limited. All rights reserved

2 2.2. Label elements Prevention Response Storage Disposal Skin Sens. : H37 - May cause an allergic skin reaction. Eye Irrit. 2: H39 - Causes serious eye irritation. Acute Tox. 4: H332 - Harmful if inhaled. Aquatic Chronic 2: H4 - Toxic to aquatic life with long lasting effects. date P20 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P270 - Do no eat, drink or smoke when using this product. P27 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. 2/ P30+P30 - IF SWALLOWED: IF SWALLOWED: Immediately call a POISON CENTER/doctor/. P303+P36+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P35+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P33 - Do NOT induce vomiting. P370+P378 - In case of fire: Use foam/c02 to extinguish. P02 - Keep out of reach of children. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. Dispose of this material and its container to hazardous or special waste collection point. SECTION 3: Composition/information on ingredients 3.2. Mixtures 67/548/EEC / 999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Ethanol % F; R M-factor. Turpentine, oil (Turpentine) % R0 Xn; R20/2/22-65 Xi; R36/38 R43 N; R5/53 Acetic acid % (Acetic acid) % R0 C; R35 2-Dimethylaminoethanol % R0 Xn; R20/2/22 C; R34 EC 272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Ethanol % Flam. Liq. 2: H225; M-factor. Turpentine, oil (Turpentine) % Flam. Liq. 3: H226; Acute Tox. 4: H332; Acute Tox. 4: H32; Acute Tox. 4: H302; Asp. Tox. : H304; Eye Irrit. 2: H39; Skin Irrit. 2: H35; Skin Sens. : H37; Aquatic Chronic 2: H4; Acetic acid % (Acetic acid) % Flam. Liq. 3: H226; Skin Corr. A: H34; 2-Dimethylaminoethanol % Flam. Liq. 3: H226; Acute Tox. 4: H332; Acute Tox. 4: H32; Acute Tox. 4: H302; Skin Corr. B: H34; SECTION 4: First aid measures 4.. Description of first aid measures Inhalation Eye contact Remove casualty from exposure ensuring one's own safety whilst doing so. Rinse immediately with plenty of water for 5 minutes holding the eyelids open. Copyright 205 ChemSoft Limited. All rights reserved

3 4.. Description of first aid measures Skin contact Wash with soap and water. Ingestion DO NOT INDUCE VOMITING Most important symptoms and effects, both acute and delayed Inhalation Harmful by inhalation. Eye contact Harmful. Skin contact Harmful in contact with skin. Ingestion Harmful if swallowed Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion SECTION 5: Firefighting measures 5.. Extinguishing media Use extinguishing media appropriate to the surrounding fire conditions Special hazards arising from the substance or mixture Burning produces irritating, toxic and obnoxious fumes Advice for firefighters Wear suitable respiratory equipment when necessary. date 3/ SECTION 6: Accidental release measures 6.. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.. Precautions for safe handling Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Avoid release to the environment. Refer to special instructions/safety data sheets. Do not allow product to enter drains. For small quantities:. Clean area thoroughly with detergent. See section 2, 3, 8, 3 for further information Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Adopt best Manual Handling considerations when handling, carrying and dispensing. Keep only in the original container in a cool, well-ventilated place. Keep container tightly closed in a cool place. Store at temperatures between 5 C and 8 C. SECTION 8: Exposure controls/personal protection 8.. Control parameters 8... Exposure Limit Values See section 8.2 for further information. Copyright 205 ChemSoft Limited. All rights reserved

4 4/7 date Exposure Limit Values 2-Dimethylaminoethanol WEL 8-hr limit ppm: 2 WEL 8-hr limit mg/m3: 7.4 WEL 5 min limit ppm: 6 WEL 5 min limit mg/m3: 22 WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - Acetic acid % (Acetic acid) DIR: 9/322 8hTWA ppm: 0 8hTWA mg/m3: 25 STEL ppm: - STEL mg/m3: - NOT: - Ethanol WEL 8-hr limit ppm: 000 WEL 8-hr limit mg/m3: 920 WEL 5 min limit ppm: - WEL 5 min limit mg/m3: - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - Turpentine, oil (Turpentine) WEL 8-hr limit ppm: 00 WEL 8-hr limit mg/m3: Exposure controls WEL 5 min limit ppm: 50 WEL 5 min limit mg/m3: 850 WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total Appropriate engineering controls Eye / face protection Skin protection - Handprotection Skin protection - Other Respiratory protection Environmental exposure controls Ensure adequate ventilation of the working area. Wear eye/face protection. Chemical resistant gloves (PVC). Wear suitable protective clothing. Wear suitable respiratory equipment when necessary. Avoid release to the environment. SECTION 9: Physical and chemical properties 9.. Information on basic physical and chemical properties Appearance Liquid Colour Amber Odour Ammoniacal ph No data available Flash point 24 C Flammability (solid, gas) No data available Partition coefficient No data available Autoignition temperature No data available Viscosity No data available Explosive properties No data available Oxidising properties No data available Solubility Slightly miscible in water 9.2. Other information Copyright 205 ChemSoft Limited. All rights reserved

5 5/7 date Other information Conductivity No data available Surface tension No data available SECTION 0: Stability and reactivity 0.. Reactivity No data available Chemical stability Stable under normal conditions Possibility of hazardous reactions 0.4. Conditions to avoid Heat, sparks and open flames Incompatible materials Oxidising agents Hazardous decomposition products Burning produces irritating, toxic and obnoxious fumes. SECTION : Toxicological information..4. Toxicological Information No data available SECTION 2: Ecological information 2.. Toxicity No data available 2.2. Persistence and degradability 2.3. Bioaccumulative potential Partition coefficient No data available 2.4. Mobility in soil 2.5. Results of PBT and vpvb assessment 2.6. Other adverse effects SECTION 3: Disposal considerations 3.. Waste treatment methods Disposal of packaging SECTION 4: Transport information Dispose of as special waste in compliance with local and national regulations. After final product withdrawl, all residues must be removed from containers (drip-free, powder-free or paste-free). Empty containers can be sent for disposal or recycling. Copyright 205 ChemSoft Limited. All rights reserved

6 6/7 date Hazard pictograms 4.. UN number UN UN proper shipping name PAINT 4.3. Transport hazard class(es) ADR/RID 3 Subsidiary risk - IMDG 3 Subsidiary risk - IATA 3 Subsidiary risk Packing group Packing group III 4.5. Environmental hazards Environmental hazards Yes Marine pollutant Yes ADR/RID Hazard ID 33 Tunnel Category (D/E) IMDG EmS Code F-E S-E IATA Packing Instruction (Cargo) 366 Maximum quantity 220 L Packing Instruction (Passenger) 355 Maximum quantity 60 L SECTION 5: Regulatory information 5.. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations 5.2. Chemical safety assessment COMMISSION REGULATION (EU) No 453/200 of 20 May 200 amending Regulation (EC) No 907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 488/94 as well as Council Directive 76/769/EEC and Commission Directives 9/55/EEC, 93/67/EEC, 93/05/EC and 2000/2/EC. REGULATION (EC) No 907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 8 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 488/94 as well as Council Directive 76/769/EEC and Commission Directives 9/55/EEC, 93/67/EEC, 93/05/EC and 2000/2/EC. Copyright 205 ChemSoft Limited. All rights reserved

7 date 7/ SECTION 6: Other information Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 General information This document differs from the previous version in the following areas:. 2 - Prevention. 2 - Response. 2 - Storage. 2 - Disposal. 4 - IMDG. R0 - Flammable R - Highly flammable. R20/2/22 - Harmful by inhalation, in contact with skin and if swallowed. R34 - Causes burns. R35 - Causes severe burns. R36/38 - Irritating to eyes and skin. R43 - May cause sensitisation by skin contact. R5/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 - Harmful: may cause lung damage if swallowed. Flam. Liq. 3: H226 - Flammable liquid and vapour. Acute Tox. 4: H302 - Harmful if swallowed. Acute Tox. 4: H32 - Harmful in contact with skin. Skin Corr. B: H34 - Causes severe skin burns and eye damage. Acute Tox. 4: H332 - Harmful if inhaled. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. Copyright 205 ChemSoft Limited. All rights reserved