Safety data sheet October 2017 ( )

Transcription

1 1. Identification of the substance and company 1.1 Product name Swecem PFA 1.2 Relevant identified of the substance and uses advised against 1.3 Manufacture: 2. Hazards identification Used in the production of concrete and asphalt. Raw material in the production of cement. Used as filler in constructions. Landfill through, for example stabilization Emineral a/s, Nefovej 50, DK-9310 Vodskov 1.4 Information: Sale/Logistics 1.5 Responsible for the safety data sheet CTO Helena Eriksson +46 (0) Supplier 1.6 Emergency telephone number SOS Alarm Toxic information +46 (0) Classification Irritation, Category 1-3 Symbol: Ängelholm Sale: Helena Eriksson +46 (0) Label elements 2.3 Other hazards - Signal word: Warning H-phrases H315 Irritate the skin H317 May cause allergic skin reaction H319 Cause serious eye irritation H335 May cause irritated throat P-phrases Prevention P261 Avoid inhalation of dust P280 Use security clothes, gloves, glasses, masks Measures P304+P340 INHALATION: Move the person to fresh air P302+ P362+P353 SKIN CONTACT: Remove contaminated clothes and shower exposed area. P305+P351+P338 EYE CONTACT: Gently rinse with water for several minutes, remove contact lenses if possible, keep rinse P301+P330+P331 INGESTION: Rinse the mouth. DON T induce vomiting

2 3. Composition/information in ingredients 3.1 Chemical name Fly ash, Type B5 3.2 % 100 % 3.3 CAS-no: EC-No: Chemical contents Organic material/rest of coal material (Category A), Cl-, SO3, Free CaO, Reactive CaO, Reactive SiO2, Na2Oaekv, MgO, P2O5 3.6 Hazard statement H315, H317, H319, H Classification CLP H315,Skin Irrit 2, H317,Skin Sens. 1, H319, Eye Irrit 2, H335, STOT RE 3 4. First aid measures 4.1 Inhalation Dust inhalation: Move into fresh air and keep at rest. In case of persistent throat irritation or coughing: Seek medical attention and bring these instructions. 4.2 Skin contact Remove contaminated clothes and rinse skin thoroughly with water. 4.3 Eye contact Do not rub eye. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring along these instructions. 4.4 Ingestion Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions.

3 5. Firefighting measures 5.1 Extinguishing media The product is non-combustible 6. Accidental release measure 6.1 Personal precautions 6.2 Environmental precautions 6.3 Methods for cleaning up Avoid inhalation of dust. Avoid contact with eyes and prolonged skin contact The product should not be dumped in nature but collected and delivered according to agreement with the local authorities. Use a vacuum cleaner. If not possible, moisten dust with water before it is collected with shovel, broom or the like. 6.4 References Sections 4, 5, 7 and 8 7. Handling and storage 7.1 Safe handling advice 7.2 Storage conditions: Avoid inhalation of dust. Avoid contact with eyes and prolonged skin contact. In suitable closed silos, suitable sacks or approved intermediate storage or disposal. Dust problems and spillage must be prevented during storage. 7.3 Final use Section Exposure controls/ Personal protection 8.1 Engineering measures Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust. 8.2 Control parameters 8.3 Personal protection: Pulverized fuel ash, total inhalable dust Exposure limits = 10 mg/m 3 Pulverized fuel ash, respirable dust Exposure limits = 5 mg/m 3 INHALATION Short-term work: Use respiratory equipment with particle filter, type P2/P3. Long-term work: Use respiratory equipment with particle filter, type P2/P3. Respiratory equipment with turbo unit may be used. Risk of oxygen deficit (closed systems, e.g. silo): Use fresh air-supplied respirator SKIN CONTACT: Use suitable work gloves. EYE CONTACT: Tight-fitting goggles. Not relevant if full-mask is used.

4 9. Physical and chemical properties 9.1 Appearance Light grey to grey-brown powder 9.2 ph in water < 12,5 9.3 Relative density (kg/m3): Stability and Reactivity 10.1 Reactivity None 10.2 Chemical stability Stable 10.3 Hazardous reactions None 10.4 Conditions to aviod Section 10.1 och Incompatible materials: Hazardous decomposition products: Section Toxicological information 11.1 Inhalation When adding water, small amounts of ammonia are released which will irritate the respiratory system. Dust may irritate throat and respiratory system and cause coughing Eye contact Irritating and causes redness and pain Skin contact Dust has an irritating effect on moist skin Ingestion Ingestion may cause severe irritation of the mouth, the esophagus and the gastrointestinal tract.

5 12. Ecological information 12.1 Toxicity May contain small amounts of heavy metals which are very toxic to aquatic organisms. The product may affect the acidity (ph-factor) in water with risk of harmful effects to aquatic organisms Degradability: Bioaccumulative potential: Mobility: Results of PBT and vpvb assessment Other adverse effects: Waste treatment methods 13.1 Dispose of waste and residues in accordance with local authority requirements. Remains, which the supplier can t offer to take back, should be delivered to licensed waste disposal site in accordance with the local Waste Disposal Authority. Waste from residues: EWC-code: Transport information 14.1 UN-number Proper shipping name Section Classification Section Packing group Section Environmental hazards Not relevant 14.6 Special precautions None known Transport in bulk according to Annex II of MARPOL 73/78 and IBC code Section 14.1

6 15. Regulatory information 15.1 National regulation 16. Other information The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). EH40/2005, Workplace exposure limits 2005, with amendments. The List of Wastes (England) (Amendment) Regulations (SI 2005 No. 895) Chemical safety Section 10 Hazards identifications and H-phrases Information to creator of this safety sheet Latest update H315, H317, H319, H335 Henrik Palmkvist, henrik.palmkvist@swecem.com 2nd edition , updated contact information