Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Revision Date: 09/24/2008 Issue date: 09/24/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE 7387 DEPEND ACTIVATOR Item No. : / IDH No Product type: Activator Region: United States Company address: Henkel Corporation 1001 Trout Brook Crossing Rocky Hill, Connecticut Contact Information: Telephone: Emergency telephone: Internet: 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER n-heptane ppm TWA 2000 mg/m³ TWA ppm STEL 500 ppm TWA Aldehyde-amine condensate Isobutane ppm TWA Isopropyl alcohol ppm TWA 400 ppm STEL 400 ppm TWA 980 mg/m³ TWA 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid Aerosol HEALTH: 1* Color: Amber FLAMMABILITY: 4 Odor: Aliphatic PHYSICAL HAZARD: 0 Personal Protection: See Section 8 WARNING: FLAMMABLE LIQUID AND VAPOR. CAUSES EYE AND SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Irritating to skin. Solvent action can dry and defat the skin, causing the skin to crack, leading to dermatitis. Vapors may irritate eyes. Contact with eyes will cause irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspirated material can enter the lungs and result in pneumonitis. Eye, skin, and respiratory disorders. Heart disease. See Section 11 for additional toxicological information. Item No. : / IDH No Product name: LOCTITE 7387 DEPEND ACTIVATOR 1 of 4

2 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. If discomfort persists seek medical attention. Wash with soap and water. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. If conscious, drink plenty of water. Do not induce vomiting. Keep individual calm. Obtain medical attention. 5. FIRE-FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: <0 C (32 F) (Base only) Foam, dry chemical or carbon dioxide. Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition, and flash back. Oxides of carbon. Oxides of nitrogen. Irritating organic vapors. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Remove all ignition sources. Ensure adequate ventilation. Soak up with inert absorbent. Store in a closed container until ready for disposal. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Avoid breathing vapor and mist. Wash thoroughly after handling. During use and until all vapors are gone: Keep area ventilated - do not smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical tools and appliances, and any other sources of ignition. Store away from heat, sparks, flames, or other sources of ignition. For safe storage, store at or below 38 C (100 F). Incompatible products: Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (800) EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Chemical resistant, impermeable gloves. Safety goggles or safety glasses with side shields. See Section 2 for exposure limits. Item No. : / IDH No Product name: LOCTITE 7387 DEPEND ACTIVATOR 2 of 4

3 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Aerosol Color: Amber Odor: Aliphatic Vapor pressure: 35 mmhg at 20 ºC (68 F) (Base only) ph: Not applicable Boiling point/range: 50 C (122 F) Approximately 50 C (122 F) (Base only) Melting point/range: Specific gravity: Base only Vapor density: Evaporation rate: Solubility in water: Immiscible Partition coefficient (n-octanol/water): VOC content: 83.84%; grams/liter (EPA Method 24) 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Stable. Will not occur. Oxides of carbon. Oxides of nitrogen. Irritating organic vapors. Strong oxidizers. Strong acids and strong bases. Acid chlorides. Acid anhydrides. Alkali metals. Ammonia. Amines. Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatabilty" (Section 10). 11. TOXICOLOGICAL INFORMATION Carcinogen Status Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen n-heptane Aldehyde-amine condensate Isobutane Isopropyl alcohol Literature Referenced Target Organ & Other Health Effects Hazardous components n-heptane Aldehyde-amine condensate Isobutane Isopropyl alcohol Health Effects/Target Organs Central nervous system, Irritant No data Cardiac, Central nervous system, Lung Allergen, Blood, Central nervous system, Irritant, Kidney, Liver, Brain, Spleen 12. ECOLOGICAL INFORMATION Ecological information: Item No. : / IDH No Product name: LOCTITE 7387 DEPEND ACTIVATOR 3 of 4

4 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of according to Federal, State and local governmental regulations. D001: Ignitable. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR): Aerosols, flammable Hazard class or division: 2.1 Identification number: UN 1950 Exceptions: Consumer Commodity ORM-D (Not more than 1 Liter) International Air Transportation (ICAO/IATA): Aerosols, flammable, n.o.s Hazard class or division: 2.1 Identification number: UN 1950 Exceptions: May Qualify as Consumer Commodity ID8000 (Not more than 500 ml) WaterTransportation (IMO/IMDG): Aerosols Hazard class or division: 2 Identification number: UN1950 Exceptions: Limited quantity (Not more than 1 L) Marine pollutant: United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. TSCA 12 (b) Export Notification: n-heptane ( ). CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65:. Immediate Health Hazard, Delayed Health Hazard, Fire above reporting de minimus. This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. A, B.2, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: 5 Prepared by: Kyra Kozak Woods, Manager, Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Item No. : / IDH No Product name: LOCTITE 7387 DEPEND ACTIVATOR 4 of 4

5 Material Safety Data Sheet Revision Number: Issue date: 02/06/ PRODUCT AND COMPANY IDENTIFICATION Product type: Acrylic Adhesive Item number: Region: United States Company address: Contact information: Henkel Corporation Telephone: Trout Brook Crossing Emergency telephone: Rocky Hill, Connecticut Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *2 Color: Amber FLAMMABILITY: 2 Odor: Sharp, Irritating PHYSICAL HAZARD: 1 Personal Protection: See MSDS Section 8 WARNING: COMBUSTIBLE LIQUID AND VAPOR. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. May cause irritation to nose and throat. May cause allergic skin reaction. May cause skin irritation. Vapors may irritate eyes. Contact with eyes will cause irritation. May be harmful if swallowed. May cause gastrointestinal tract irritation if swallowed. Eye, skin and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Tetrahydrofurfuryl methacrylate Chlorosulphonated polyethylene Methacrylic acid Ethylhexyl methacrylate Epichlorohydrin-4,4'-isopropylidene diphenol resin Talc Under the Clean Air Act this product is exempted from labeling as an ozone depleting chemical (40 CFR (b)(1)). Page 1 of 5

6 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Wash with soap and water. Remove contaminated clothing and footwear. Wash clothing before reuse. If symptoms develop and persist, get medical attention. Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Never give anything by mouth to an unconscious person. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: 83 C (181.4 F) Tagliabue closed cup Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Oxides of nitrogen. Toxic chlorides. Irritating organic vapours. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Remove all sources of ignition. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Handling: Storage: Keep away from heat, spark and flame. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not taste or swallow. Use only with adequate ventilation. For safe storage, store at or below 38 C (100.4 F) Store away from heat, sparks, flames, or other sources of ignition. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) Page 2 of 5

7 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Tetrahydrofurfuryl methacrylate Chlorosulphonated polyethylene Methacrylic acid 20 ppm TWA 2-Ethylhexyl methacrylate Epichlorohydrin-4,4'-isopropylidene diphenol resin Talc 2 mg/m3 TWA Respirable fraction. 20 MPPCF TWA 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable. 0.3 mg/m3 TWA Total dust. 50 ppm Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Use a NIOSH approved air-purifying respirator with an organic vapor cartridge. Safety goggles or safety glasses with side shields. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene, Butyl-rubber, or nitrile-rubber gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Amber Odor: Sharp, Irritating Odor threshold: ph: Not applicable Vapor pressure: < 10 mm Hg (80 F (26.7 C)) Boiling point/range: > 300 F (> C) Melting point/ range: Specific gravity: 1.16 Vapor density: Flash point: 83 C (181.4 F) Tagliabue closed cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Slight Partition coefficient (n-octanol/water): VOC content: 1.59 %; 18.4 g/l 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable Will not occur. Oxides of carbon. Oxides of sulfur. Toxic chlorides. Irritating organic vapours. Strong oxidizing agents. Keep away from heat, ignition sources and incompatible materials. Page 3 of 5

8 11. TOXICOLOGICAL INFORMATION Acute oral product toxicity: Acute dermal product toxicity: LD50 (rat) > 10,000 mg/kg LD50 (rabbit) > 4,000 mg/kg Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Tetrahydrofurfuryl methacrylate Chlorosulphonated polyethylene Methacrylic acid 2-Ethylhexyl methacrylate Epichlorohydrin-4,4'-isopropylidene diphenol resin Talc Hazardous components Tetrahydrofurfuryl methacrylate Chlorosulphonated polyethylene Methacrylic acid 2-Ethylhexyl methacrylate Epichlorohydrin-4,4'-isopropylidene diphenol resin Talc Health Effects/Target Organs Irritant, Allergen No Target Organs Corrosive, Irritant, Allergen Irritant, Allergen Allergen, Irritant Irritant, Lung, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. D019: Carbon tetrachloride. 14. TRANSPORT INFORMATION The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR) Not regulated Hazard class or division: Identification number: International Air Transportation (ICAO/IATA) Hazard class or division: Identification number: Water Transportation (IMO/IMDG) Hazard class or division: Identification number: Not regulated Not regulated Page 4 of 5

9 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimus Immediate Health, Delayed Health, Fire above reporting de minimus This product contains a chemical known in the State of California to cause cancer.this product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. B.3, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. 2,3,4,5,8,9,11, and 15 Prepared by: Jennifer Glieco, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5