Workplace Airborne Hazards and Air Sampling
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1 Workplace Airborne Hazards and Air Sampling Jeremy Evans SKC Sales Development Manager 13 th November 2018 Boringdon Park Golf Club, Plympton IOSH South West Branch
2 Agenda Reasons for Workplace Air Sampling Airborne Hazards & Air Sampling - Background Workplace Air Sampling Methods Active Sampling - Time Based Workplace Exposure - Particulates - Vapours Sampling Options
3 Size of the Problem? Bristol Balloon Festival Home Park Stoke-on-Trent 1 mg/m 3 one teaspoon of flour spread over a rugby/football field, to a height of one metre 1 ppm contents of a party balloon in the volume of 50 three bedroom houses
4 Size of the Problem? Safety Health ,000-13,000 Pareto s Principle - 80:20 Rule does not apply Deaths due to airborne exposure 100:1
5 Airborne Hazards (Health) Cancers Lung Cancer Mesothelioma Leukaemia Nasal Cancer etc Diseases COPD Occupational Asthma Chronic Bronchitis Emphysema Asbestosis Silicosis etc. Benzene Butadiene Chromic Acid Mist Nickel Cadmium Wood Dust Rubber Dust/Fume Asbestos Respirable Crystalline Silica Isocyanates Dust Wood, Flour, Cotton, etc. Styrene Formaldehyde Welding Fume Particulates
6 Industry Examples: Airborne Hazards (Health) Welding, Soldering, Metal Work 1 in 10 of reported breathing/lung problems caused/made worse by work Bakers 80 times more likely to develop occupational asthma Construction 40% of all reported Occupational Cancers
7 Scaffold Fall Ceiling Collapse Injures Worker Chemical Fire Worker s Crush Injury Severe Electrical Burns Forklift Crush Death Hit by Steel Girder Industrial Saw Injury Occupational Respiratory Diseases - Headlines? Asbestos Others H&S Headlines
8 Getting the Balance right 2050???? Safety Health
9 1st Century AD PLINY THE ELDER - Animal Bladders to protect against Dust & Lead 1556 AGRICOLA - De Re Metallica - Miners Diseases and Preventive Measures 1700 BERNARDINO RAMAZZINI - De Morbis Artificum Diatriba (Diseases of Workers) 1800 s MAD HATTER - Mercury Solution - Fur to Felt History - Time Line Late 1800 s MINERS CANARIES - Audible / Visual Warning (methane / carbon monoxide) 1905 BENZO (a) PYRENE - Identified as first Chemical Carcinogen 1906 WORKMAN S COMPENSATION ACT - 6 Industrial Diseases, e.g. lead, mercury, phosphorous, arsenic poisoning
10 Reasons for Workplace Air Sampling Health Protection Compliance with Government Legislation COSHH: Control of Substances Hazardous to Health EH40: Workplace Exposure Limits CLAW: Control of Lead at Work Regulations CAR: Control of Asbestos Regulations Protection from Compensation Claims Process Control
11 Airborne Exposure - Focus? CONTROLS Less Focus on ENT PURPOSE OF CONTROLS: MINIMISE PERSONAL EXPOSURE IS EXPOSURE ACTUALLY MEASURED?
12 Costs? CONTROLS AIR SAMPLING LEV, Suppression, RPE, etc Equipment, Analysis (Lab) What Does it Cost NOT to do Air Sampling?
13 UK Workplace Exposure Limits EH40:2002 MEL (Maximum Exposure Limit) OES (Occupational Exposure Standard) EH40: rd Edition: August 2018 WEL (Workplace Exposure Limit) 8 Hour (Time Weighted Average - TWA) 15 Minute (Short Term Exposure Limit - STEL)
14 Hazardous Substances without Limits WEL not specified in EH40? This does not mean it is safe! Consider Other Published Limits e.g. USA OSHA - PEL s (Permissible Exposure Limits) NIOSH - REL s (Recommended Exposure Limits) ACGIH - TLV s (Threshold Limit Values) Take advice
15 What is Air Sampling? Air is passed through a tube, filter or other collecting media Hazard Presence / Level detected by Colour Change of Media or Laboratory Analysis or Direct Reading
16 Passive Sampling Diffusion Semi-quantitative (Indicator-Surveys) Immediate results (Gastec, Dräger) Grab Sampling Types of Air Sampling Small sample volume Semi-quantitative (Gastec, Dräger) Quantitative (Bag Sampling) Not time-based exposure Active Sampling Compensating pump Quantitative - known flow rate & time Much larger sample volume
17 Personal vs Static Sampling ALL Workplace Exposure Limits are based on PERSONAL SAMPLES MUST be taken in the BREATHING ZONE
18 Sampling Train Pump Connecting tube Sampler Sampler Connecting Tube Pump Active Sampling Calibrator Setup Sampling Train Calibrate Flow Rate - Before Sampling Fit Sample Train to Operator Check Flow Rate - After Sampling Send Sample to Laboratory Review Results Actual Exposure vs 8 hr WEL 15 min STEL
19 Particulates Aerosol Dust Fume Smoke SOLID
20 General Dust Particulates Wood Dust Mills, Furniture, Workshops, Paper Fumes - Welding, Solder, Rubber, etc. Metals - Electroplating, Grinding, Cutting Fibres - Asbestos, Mineral, Ceramic, Silica Flour/Grain Dust - Mills, Bakeries Rubber Process Dust Diesel Particulates Mining - Coal, etc. Cotton, Wool Dust
21 Relative Size of Particles RESPIRABLE Respirable dust to 12 micron Inhalable dust to 100 micron INHALABLE microns
22 Inhalable Dust Size Distribution - BS EN 481:1993 Up to 100 μm AED Affects all the respiratory system Partially visible Workplace Exposure Limits (WELs) - Dust 10 mg/m 3 8 Hour TWA - Hard Wood & Soft Wood Dust 5 mg/m 3 8 Hour TWA
23 Respirable Dust Size Distribution - BS EN 481:1993 Up to 10 μm AED Penetrates deep into the lungs Invisible Workplace Exposure Limits (WELs) - Dust 4 mg/m 3 8 Hour TWA - Respirable Crystalline Silica 0.1 mg/m 3 8 Hour TWA
24 HSE Methods - Particulates MDHS - Method for the Determination of Hazardous Substances MDHS 14/4 - Dust MDHS 101/2 - Respirable Crystalline Silica
25 Active Sampling - Particulates Sampling Heads (containing filter) IOM Cyclone Cowled Mini Sampler Dust Dust Fibres Welding Fumes
26 Survey Methods - Particulates Direct Reading Dust Monitor - time-based picture of the situation Area Mapping Where (Hotspots), When, Who Inhalable or Respirable dust Cleaning Processes TIMES!
27 Vapours Aerosol Gas Vapour LIQUID
28 Vapours Organic Chemicals solvents / VOCs, etc. Benzene, Toluene, Formaldehyde, Methanol, etc. Inorganic Chemicals - mineral acids Hydrochloric Acid, Nitric Acid, etc Gases Nitrous Oxide, Chlorine, Chloroform, etc. Isocyanates
29 Vapours - Exposure Limits (WELs) Parts per Million (ppm) Wide range - Vapours - Limits Examples 8 Hour TWA 15 Minute STEL - Formaldehyde 2 ppm 2 ppm - Xylene 50 ppm 100 ppm - Dichloromethane 100 ppm 300 ppm - Propan-2-ol (IPA) 400 ppm 500 ppm
30 Passive/Grab Sampling - Vapours Passive Sampling Badges Colour Change Tubes
31 Active Sampling - Vapours Sorbent Tube - with Holder & Cover Cassette & Holder (containing treated filter)
32 HSE Methods - Vapours MDHS - Method for the Determination of Hazardous Substances Generic (VOCs) MDHS 88 Passive Sampling MDHS 104 Active Sampling
33 WHY WHAT HOW WHO? Workplace Air Sampling - Options Consultant DIY Both DIY Benefits Cost Savings Flexibility Involvement / Ownership Additional Skills / Experience
34 Measurement Requirements Equipment, Accessories Guidance/Support - Equipment Supplier - Laboratory - HSL, etc Competence (Training)
35 Air Sampling - Exposure Measurement Don t just rely on Controls Take the Guesswork Out Defuse the Exposure Time bombs Redress the Balance X Safety X Health
36 13 th November 2018 Boringdon Park Golf Club, Plympton IOSH South West Branch
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