Material Safety Data Sheet. Gypsum Rock, Anhydrite Rock. Calcium Sulfate Dihydrate Chemical Formula CaSO4 2H2O
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1 Harrison Gypsum, LLC MAIN OFFICE: 1550 DOUBLE DRIVE, NORMAN, OK PHONE: FAX: Material Safety Data Sheet Phone Number: (405) Preparation Date: 1/1/2012 Products : Common Name: Chemical Name: Gypsum Rock, Anhydrite Rock Gypsum & Anhydrite Calcium Sulfate Dihydrate Chemical Formula CaSO4 2H2O CAS OSHA PEL* ACGIH TLV* Concentration Ingredients Number (mg/m3) (mg/m3) (%) Calcium Sulfate Dihydrate /15 10 Calcium Sulfate /15 10 Limestone (CaCO3) /15 10 <5 Crystalline Silica / - 0.1/ - <1 * Respirable dust/total dust. PEL and TLV limits are based on an 8 hour TWA. Note: Ground calcium sulfate dihydrate, calcium sulfate and calcium carbonate are classified as nuisance dusts. OSHA believes that nuisance dust may cause safety problems among exposed workers because it can be a source of distraction and physical irritation which can cause accidents or safety mishaps in the workplace. Appearance Odor Solubility (in water) Specific Gravity White to off-white powder None Slight 2.32 to 2.41
2 Page 1 of 5 Flash Point Flammable Limits Fire Extinguishing Media Special Fire-Fighting Procedures Toxic Gases Produced Not Combustible N/A Not Combustible None Decomposes to Sulfur C Section V - Health Hazard Data Effects of Overexposure Acute: Persons exposed to large amounts of dust may be forced to leave the area because of nuisance conditions, including coughing, sneezing, and nasal irritation. Other temporary effects may include drying of the skin and eye irritation. Gypsum is considered non-toxic. Chronic: None known for gypsum. Prolonged and repeated exposure to crystalline silica by inhalation may cause silicosis and lung cancer. Medical Conditions Generally Aggravated by Exposure: Bronchitis, Emphysema and Asthma Target Organs: Lungs, eyes Routes of Entry: Inhalation
3 Page 2 of 5 Carcinogenicity: IARC NTP Crystalline silica Carcinogen (Group 1) Anticipated Carcinogen In 1997, IARC classified inhaled crystalline silica as carcinogenic to humans categorizing it as a Group 1 agent. In this evaluation, IARC noted that carcinogenicity was not detected in all industrial circumstances studied, and may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs. In 1992, NTP listed respirable crystalline silica among the substances reasonably anticipated to be carcinogens. Ingestion: If swallowed and the person is conscious, immediately give large amounts of water. Get medical attention. Inhalation: If person breathes in large amounts, move the exposed person to fresh air. Get medical attention if irritation persists. Eye Contact: Remove contact lenses and immediately flush with water for at least 15 minutes, including under eyelids. Seek medical advice if irritation persists. Skin Contact: Wash with soap and water. If irritation occurs, contact physician. Precautionary Labeling: HMIS NFPA Health 0 0 Flammability 0 0 Reactivity 0 0 Other - N/A Rating Scale: 0 = Minimal Hazard, 1 = Slight Hazard, 3 = Serious Hazard, 4 = Extreme Hazard Precautionary Label Statements: Caution, may cause irritation during use. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. When not in uses keep in tightly closed container. Page 3 of 5
4 Stability: Stable Hazardous Polymerization: Will not occur Conditions to Avoid: None Incompatibles: Aluminum, Strong Acids Decomposition Products: Oxides of Sulfur Section VII - Spill and Disposal Procedures Steps to be taken in the event of a spill or discharge: Remove by dry-sweeping or vacuum. Do not wash down drains since it could plug drains. Disposal Procedure: For disposal of this material as a waste, act in accordance with all applicable federal, state and local environmental regulations. Ventilation: Respiratory Protection: Eye Protection: Skin Protection: Section VIII Special Protection Information Use adequate general or local exhaust ventilation to keep dust levels as low as possible. None required where adequate ventilation conditions exist. A dust mask can be used for nuisance dust. If airborne concentrations of any hazardous ingredients exceed the TLV or PEL, use a NIOSH approved respirator. Safety glasses or goggles, as needed. Gloves are not required, but may be desirable under certain working conditions or to protect against drying of hands. Page 4 of 5
5 Page 5 of 5
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