Safety Data Sheet according to Regulation (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 13 TEROSON AD SP PLUS All known as Terotech SP plus All SDS No. : V002.1 Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier TEROSON AD SP PLUS All known as Terotech SP plus All Contains: Diphenylmethane diisocyanate, isomers and homologues 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Joint sealant, polyurethane 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) Fax-no.: +49 (211) ua-productsafety.de@henkel.com 1.4. Emergency telephone number The Henkel information service also provides an around-the-clock telephone service on phone no.+49-(0) for exceptional cases. Further information is available at Poison Control Centers Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Respiratory sensitizer Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger

2 Page 2 of 13 Hazard statement: H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Supplemental information Contains. May produce an allergic reaction. Precautionary statement: Prevention Precautionary statement: Response Precautionary statement: Disposal P261 Avoid breathing vapours. P284 [In case of inadequate ventilation] wear respiratory protection. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P501 Dispose of contents/container in accordance with national regulation Other hazards Information according to XVII. 56 REACH Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Mixtures SECTION 3: Composition/information on ingredients General chemical description: Joint sealant, polyurethane Base substances of preparation: Polyurethane prepolymer with free 4,4'-methylenediphenyl diisocyanate (MDI) Inorganic fillers Declaration of the ingredients according to CLP (EC) No 1272/2008: Hazardous components Diphenylmethane diisocyanate, isomers and homologues EC Number REACH-Reg No content Classification 0,1- < 1 % Carc. 2 H351 Acute Tox. 4; Inhalation H332 STOT RE 2 H373 Eye Irrit. 2 H319 STOT SE 3 H335 Skin Irrit. 2 H315 Resp. Sens. 1 H334 Skin Sens. 1 H317 0,1- < 0,25 % Skin Sens. 1; Dermal H317 Aquatic Acute 1 H400 Aquatic Chronic 1 H410 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

3 Page 3 of 13 SECTION 4: First aid measures 4.1. Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. Delayed effects possible after inhalation. Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: Rinse immediately with plenty of running water, seek medical advice if necessary. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice Most important symptoms and effects, both acute and delayed RESPIRATORY: Irritation, coughing, shortness of breath, chest tightness Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of fire, isocyanate vapors may be formed. In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Avoid contact with skin and eyes. Wear protective equipment. Danger of slipping on spilled product Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section 8

4 Page 4 of Precautions for safe handling Ensure that workrooms are adequately ventilated. Avoid skin and eye contact. Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Keep container tightly sealed. Store in a cool, dry place. Storage at 5 to 25 C is recommended. Do not store together with food or other consumables (coffee, tea, tobacco, etc.) Specific end use(s) Joint sealant, polyurethane SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure Limits Valid for Germany Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit category / Remarks Silicon dioxide 4 Exposure limit(s): If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7). 4,4'-Methylenediphenyl diisocyanate ,4'-Methylenediphenyl diisocyanate ,4'-Methylenediphenyl diisocyanate ,4'-Methylenediphenyl diisocyanate Short Term Exposure Classification: Skin designation: STEL (Short Term Exposure Limit) factor: Category I: substances for which the localized effect has an assigned OEL or for substances with a sensitizing effect in respiratory passages. Can be absorbed through the skin. 1 Substance listed with both Peak factor and STEL factor. The Peak factor is supplied with the AGW values. 0,05 Exposure limit(s): =2= If the AGW and BGW values are complied with, there should be no risk of reproductive damage (see Number 2.7). Regulatory list TRGS 900 TRGS 900 TRGS 900 TRGS 900 TRGS 900

5 Page 5 of 13 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) sewage treatment plant (STP) sediment (freshwater) sediment (marine water) soil Exposure period Value mg/l ppm mg/kg others 0,0022 mg/l 0,00022 mg/l 0,009 mg/l 1 mg/l 1,05 mg/kg 0,11 mg/kg 0,21 mg/kg Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Exposure Health Effect Workers Inhalation Long term Workers Inhalation Acute/short term Workers dermal Long term Workers dermal Acute/short term General Inhalation Long term population General population General population General population General population General population Inhalation dermal dermal oral oral Acute/short term Long term Acute/short term Long term Acute/short term Exposure Time Value 2,35 mg/m3 2,35 mg/m3 2,5 mg/kg 2,5 mg/kg 0,58 mg/m3 0,58 mg/m3 1,25 mg/kg 1,25 mg/kg 1,25 mg/kg 1,25 mg/kg Remarks

6 Page 6 of 13 Biological Exposure Indices: Ingredient [Regulated substance] 4,4'-Methylenediphenyl diisocyanate Exposure controls: Parameters 4,4- Diaminodiph enylmethane Biological specimen Creatinine in urine Sampling time Conc. Basis of biol. exposure index Remark Sampling time: End of shift. 10 µg/g DE BAT BAT values reflect the total physical load of workplace substances absorbed through inhalation, dermally, etc. With occupational exposure to MDI, parameter 4,4'- Diaminodiph enylmethane (MDA) in the urine covers all components of a complex MDI mixture, since both monomers and oligomers of the MDI are degraded independent of the exposure path of the monomerous MDI. In contrast, the MAK value for MDI takes into account only the monomer MDI portion. Additional Information Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Combination filter: ABEKP (EN 14387) This recommendation should be matched to local conditions. Hand protection: In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374. material thickness > 0.1 mm Perforation time > 480 minutes In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions. Eye protection: Goggles which can be tightly sealed. Protective eye equipment should conform to EN166.

7 Page 7 of 13 Skin protection: Suitable protective clothing Protective clothing should conform to EN for liquid splashes or to EN for dusts. Advices to personal protection equipment: The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions. Personal protective equipment should conform to the relevant EN standard. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid pasty varied, according to coloration Odor characteristic Odour threshold ph Melting point Solidification temperature Initial boiling point Flash point Evaporation rate Flammability Explosive limits Vapour pressure Relative vapour density: Density (23 C (73.4 F)) Bulk density Solubility Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Solubility (qualitative) (23 C (73.4 F); Solvent: Acetone) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity (kinematic) Explosive properties Oxidising properties > 61 C (> F) 1,35 g/cm3 low solubility Soluble 9.2. Other information max. VOC content: 80 g/l Reactivity Pressure build-up in closed containers. Reaction with water, alcohols, amines. Reaction with water, formation of CO Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity SECTION 10: Stability and reactivity

8 Page 8 of Conditions to avoid Humidity Incompatible materials See section reactivity Hazardous decomposition products Carbon dioxide is generated under contact with moisture, leading to pressure in the cans. Danger of cans bursting! SECTION 11: Toxicological information General toxicological information: Persons suffering from allergic reactions to isocyanates should avoid contact with the product. Cross-reactions with other isocyanate compounds are possible. An allergic reaction cannot be excluded after repeated skin contact Information on toxicological effects Acute oral toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Diphenylmethane diisocyanate, isomers and homologues Bis(1,2,2,6,6- pentamethyl-4-piperidyl) Value Value Species Method type LD50 > mg/kg rat OECD Guideline 401 (Acute Oral Toxicity) LD mg/kg rat Acute dermal toxicity: The mixture is classified based on calculation method referring to the classified substances present in the mixture. Diphenylmethane diisocyanate, isomers and homologues Value Value Species Method type LD50 > mg/kg rat OECD Guideline 402 (Acute Dermal Toxicity) Acute inhalative toxicity: Skin corrosion/irritation: Serious eye damage/irritation: Respiratory or skin sensitization:

9 Page 9 of 13 Germ cell mutagenicity: Carcinogenicity Reproductive toxicity: STOT-single exposure: STOT-repeated exposure:: The mixture is classified based on threshold limits referring to the classified substances present in the mixture. Diphenylmethane diisocyanate, isomers and homologues Result / Value NOAEL 0,2 mg/m³ Route of application inhalation: aerosol Exposure time / Frequency of treatment 2 y 6 h per d, 5 d per week Species Method rat OECD Guideline 453 (Combined Chronic Toxicity / Carcinogenicity Studies) Aspiration hazard:

10 Page 10 of 13 General ecological information: Do not empty into drains, soil or bodies of water. SECTION 12: Ecological information Toxicity Toxicity (Fish): The mixture is classified based on calculation method referring to the classified substances present in the mixture. Diphenylmethane diisocyanate, isomers and homologues piperidyl) Value type Value Exposure time Species Method LC50 > mg/l 96 h Danio rerio OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 0,9 mg/l 96 h Danio rerio OECD Guideline 203 (Fish, Acute Toxicity Test) Toxicity (Daphnia): Chronic toxicity to aquatic invertebrates The mixture is classified based on calculation method referring to the classified substances present in the mixture. piperidyl) Value type Value Exposure time Species Method NOEC 1 mg/l 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) Toxicity (Algae): The mixture is classified based on calculation method referring to the classified substances present in the mixture. piperidyl) piperidyl) Value type Value Exposure time Species Method NOEC 0,22 mg/l 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga, Growth Inhibition Test) EC50 1,68 mg/l 72 h Desmodesmus subspicatus OECD Guideline 201 (Alga, Growth Inhibition Test) Toxicity to microorganisms The mixture is classified based on calculation method referring to the classified substances present in the mixture. piperidyl) Value type Value Exposure time Species Method EC 50 > 100 mg/l 3 h OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test) Persistence and degradability piperidyl) Result Test type Degradability Exposure time Method aerobic 38 % 28 d OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test)

11 Page 11 of Bioaccumulative potential Mobility in soil piperidyl) LogPow Temperature Method 2,37-2,77 25 C OECD Guideline 107 (Partition Coefficient (n-octanol / water), Shake Flask Method) Results of PBT and vpvb assessment Diphenylmethane diisocyanate, isomers and homologues PBT / vpvb Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code

12 Page 12 of 13 SECTION 14: Transport information UN number Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR UN proper shipping name Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Transport hazard class(es) Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Packing group Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Environmental hazards Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Special precautions for user Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR Transport in bulk according to Annex II of Marpol and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 5,90 % (VOCV VOC regulation CH) VOC Paints and Varnishes (EU): max. VOC content: 80 g/l Chemical safety assessment A chemical safety assessment has not been carried out. National regulations/information (Germany): WGK: 1, slightly water-endangering product. (German VwVwS of May 17, 1999 ) Classification in conformity with the calculation method WGK: WGK = 1, slightly water endangering mixture. Classification according to the mixture rules in German AwSV regulation annex 1, number 5.2 from 18. April BG regulations, rules, infos: BG data sheet: BGI 524 : polyurethane production and processing / isocyanates (M 044) BG regulation: BGV B 1 Handling hazardous substances Storage class according to TRGS 510: 10

13 Page 13 of 13 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.