Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 1 of 10 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Silicone sealant 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): The substance or mixture is not hazardous according to Regulation (EC) No 1272/2008 (CLP) Label elements Label elements (CLP): The substance or mixture is not hazardous according to Regulation (EC) No 1272/2008 (CLP). Supplemental information EUH210 Safety data sheet available on request Other hazards None if used properly.

2 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 2 of 10 SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: Silicone sealant Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification >= 0,1- < 0,5 % Repr. 1B H360FD ===== EU. REACH Candidate List of Substances of Very High Concern for Authorization (SVHC) 0,1- < 0,5 % Flam. Liq. 2 H225 Repr. 2 H361d Asp. Tox. 1 H304 STOT RE 2 H373 Skin Irrit. 2 H315 STOT SE 3 H336 Aquatic Chronic 3 H412 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed Prolonged or repeated contact may cause skin irritation. Prolonged or repeated contact may cause eye irritation Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures

3 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 3 of Extinguishing media Suitable extinguishing media: water, carbon dioxide, foam, powder Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released. In case of fire, keep containers cool with water spray. carbon oxides Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in section Precautions for safe handling Avoid skin and eye contact. See advice in section 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Keep container tightly sealed. Store at room temperature Specific end use(s) Silicone sealant

4 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 4 of 10 SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 type Short term exposure limit category / Remarks Silicon dioxide 6 Time Weighted Average (TWA): [SILICA, AMORPHOUS, INHALABLE DUST] Silicon dioxide [SILICA, AMORPHOUS, RESPIRABLE DUST] [TOLUENE] [TOLUENE] [TOLUENE] [TOLUENE] [TOLUENE] 2,4 Time Weighted Average (TWA): Time Weighted Average (TWA): Short Term Limit (STEL): Skin designation: Time Weighted Average (TWA): Short Term Limit (STEL): Can be absorbed through the skin. Indicative Indicative Regulatory list EH40 WEL EH40 WEL EH40 WEL EH40 WEL EH40 WEL ECTLV ECTLV Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) sediment (freshwater) sediment (marine water) soil STP aqua (marine water) aqua (intermittent releases) period mg/l ppm mg/kg others 0,68 mg/l 16,39 mg/kg 16,39 mg/kg 2,89 mg/kg 13,61 mg/l 0,68 mg/l 0,68 mg/l Remarks

5 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 5 of 10 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers Inhalation Acute/short term local effects Workers Inhalation Acute/short term Workers Inhalation Long term local effects Workers Inhalation Long term Workers Dermal Long term general Inhalation Acute/short term population local effects general population general population general population general population Inhalation Inhalation Dermal oral Acute/short term Long term Long term Long term Time 343 mg/m3 384 mg/m3 192 mg/m3 192 mg/m3 384 mg/kg bw/day 226 mg/m3 226 mg/m3 56,5 mg/m3 226 mg/kg bw/day 8,13 mg/kg bw/day Remarks Biological Indices: None 8.2. controls: Engineering controls: Ensure good ventilation/extraction. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing.

6 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 6 of 10 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste pink Odor None Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 99 C (> F) Not applicable 1 g/cm Other information SECTION 10: Stability and reactivity Reactivity None if used for intended purpose Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if stored and applied as directed Incompatible materials See section reactivity Hazardous decomposition products None if used for intended purpose Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.

7 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 7 of 10 Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause irritation to respiratory system. Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: May cause mild irritation to the eyes. Acute oral toxicity: type Route of application time Species LD50 > mg/kg oral rat LD mg/kg oral rat Method Acute inhalative toxicity: Acute dermal toxicity: type Route of application time Species LC50 28,1 mg/l Vapor. 4 h rat Route of Species type application time LD50 > mg/kg dermal rabbit Method Method Skin corrosion/irritation: Result time Species Method irritating rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Respiratory or skin sensitization: not sensitising Result Test type Species Method Buehler test guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without Species Method SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following.

8 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 8 of Toxicity Ecotoxicity: Do not empty into drains / surface water / ground water. type Acute Toxicity Study time Species Method LC mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 3,2 mg/l Fish 28 d Cyprinodon variegatus OECD Guideline 204 (Fish, Prolonged Toxicity Test: 14-day Study) EC50 11,5 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) IC50 12 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Result Route of application Degradability Method readily biodegradable aerobic 80 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available Results of PBT and vpvb assessment No data available Other adverse effects No data available Waste treatment methods SECTION 13: Disposal considerations

9 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 9 of 10 Product disposal: Do not empty into drains / surface water / ground water. Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packaging group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

10 LOCTITE MR 122S E&C known as MOLD RELEASE 122 S 450 G Page 10 of 10 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H360FD May damage fertility. May damage the unborn child. H361d Suspected of damaging the unborn child. H373 May cause damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Label elements (DPD): The product is not subject to classification according to the calculation methods of the "General Classification Guideline for Preparations of the EC" as issued in the last version. Additional labeling: Safety data sheet available for professional user on request. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.