This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries.
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1 This SDS adheres to the standards and regulatory requirements of the United States and may not meet the regulatory requirements in other countries. SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : MSDS Number : Product Use : Water treatment chemical, sodium chlorite for producing chlorine dioxide Manufacturer : DuPont 1007 Market Street Wilmington, DE Product Information : (outside the U.S ) Medical Emergency : (outside the U.S ) Transport Emergency : CHEMTREC: (outside the U.S ) Importer/Distributor : International Dioxcide, Inc., A DuPont Subsidiary, 40 Whitecap Drive, North Kingstown, RI Telephone : Other information : professional use SECTION 2. HAZARDS IDENTIFICATION Potential Health Effects Skin Sodium chlorite : May cause: Corrosion with pain, ulceration or blisters, cracking or peeling of skin. Eyes Sodium chlorite : Corrosive, may cause permanent eye injury if not promptly treated. May cause:, Tearing, pain, redness, swelling, ulceration, visual impairment, or blindness.. Inhalation 1 / 9
2 Sodium chlorite : Causes respiratory tract irritation. May cause:, Cough, sneezing, runny nose, sore throat, or shortness of breath.. Repeated exposure Sodium chlorite : Adverse effects from repeated ingestion may include: Gastrointestinal effects Abnormal decrease in number of red blood cells (anaemia) which could produce tiredness, rapid heartbeat, dizziness, pale skin, leg cramps, shortness of breath. altered blood chemistry Target Organ Sodium chlorite : Blood Carcinogenicity None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA, as a carcinogen. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Concentration Water % Sodium chlorite % SECTION 4. FIRST AID MEASURES Skin contact : Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. Call a poison control center or doctor for treatment advice. Eye contact : Rinse immediately with plenty of water and seek medical advice. 2 / 9
3 Inhalation Ingestion Notes to physician : Move to fresh air. If not breathing, give artificial respiration. Call a poison control center or doctor for treatment advice. : Call a poison control center or doctor for treatment advice. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. : Probable mucosal damage may contraindicate the use of gastric lavage. SECTION 5. FIREFIGHTING MEASURES Flammable Properties Flash point : not applicable Thermal decomposition : Stable under normal conditions., Decomposes on heating. Fire and Explosion Hazard : Drying of this product on clothing or combustible materials may cause fire. Suitable extinguishing media Firefighting Instructions : Water : Wear self-contained breathing apparatus (SCBA). Wear suitable protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with cleanup. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) Spill Cleanup Accidental Release Measures : Wear personal protective equipment. Avoid contact with the skin and the eyes. : Dilute with water. Pick up and transfer to properly labelled containers. After cleaning, flush away traces with water. : Prevent material from entering sewers, waterways, or low areas. Do not allow to dry. 3 / 9
4 SECTION 7. HANDLING AND STORAGE Handling (Personnel) : Use only in well-ventilated areas. Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday. Handling (Physical Aspects) Storage : Avoid letting the product become dry. : Keep tightly closed in a dry, cool and well-ventilated place. Keep away from food, drink and animal feedingstuffs. Avoid heat, freezing and ultraviolet light. Do not allow to dry. Keep away from: Strong acids and oxidizing agents SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls : Ensure adequate ventilation, especially in confined areas. Personal protective equipment Respiratory protection Hand protection Eye protection Skin and body protection Protective measures : Where there is potential for airborne exposures in excess of applicable limits, wear approved respiratory protection with dust/mist cartridge. : Additional protection: Impervious gloves : Wear coverall chemical splash goggles. Additionally wear a face shield where the possibility exists for face contact due to splashing, spraying or airborne contact with this material. : Where there is potential for skin contact, have available and wear as appropriate, impervious gloves, apron, pants, jacket, hood and boots. : Avoid exposure - obtain special instructions before use. Wear suitable gloves and eye/face protection. Exposure Guidelines Exposure Limit Values Contains no substances with occupational exposure limit values. 4 / 9
5 None established. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : liquid Color : light yellow Odor : odourless, slight chlorine ph : > 12 Freezing point : ca. -18 C (0 F) Crystallization temperature : ca. -9 C (16 F) Boiling point : ca. 106 C (223 F) Vapour Pressure : ca mm Hg at 20 C (68 F) Density : ca lb/gal Water solubility : miscible Viscosity : 2.33 mpa.s SECTION 10. STABILITY AND REACTIVITY Stability : Stable at normal temperatures and storage conditions. Decomposes on heating. Conditions to avoid Incompatibility Hazardous decomposition products Hazardous reactions : Stable under normal conditions. Decomposes on heating. : Strong acids and oxidizing agents Organic materials, chlorinated compounds, Reducing agents : Hazardous decomposition products: Chlorine, Chlorine dioxide...% : Contact with acids, organic materials, reducing agents and oxidizing agents will release toxic gases of chlorine and/or chlorine dioxide. SECTION 11. TOXICOLOGICAL INFORMATION Sodium chlorite 5 / 9
6 Dermal LD50 : 134 mg/kg, rabbit Oral LD50 : 284 mg/kg, rat Inhalation 4 h LC50 : 0.23 mg/l, rat Skin irritation : Corrosive, rabbit Eye irritation : Corrosive, rabbit Skin sensitization : Does not cause skin sensitisation., guinea pig Animal test did not cause sensitization by skin contact. Repeated dose toxicity : Oral rat 1 y Target Organs: Blood Gastrointestinal effects, Abnormal decrease in number of red blood cells, Abnormal decrease in red -blood -cell haemoglobin (hemoglobinemia) Oral rat 14 d altered hematology, altered urinalysis results Oral Monkey altered hematology, altered blood chemistry Carcinogenicity : Animal testing did not show any carcinogenic effects. Mutagenicity : Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Animal testing did not show any mutagenic effects. Reproductive toxicity : Animal testing showed effects on reproduction at levels equal to or above those causing parental toxicity. Teratogenicity : Animal testing showed effects on embryo-fetal development at levels equal to or above those causing maternal toxicity. 6 / 9
7 SECTION 12. ECOLOGICAL INFORMATION Aquatic Toxicity Sodium chlorite 96 h LC50 : Cyprinodon variegatus (sheepshead minnow) 105 mg/l 96 h ErC50 : Algae 5.33 mg/l 96 h EbC50 : Algae 1.09 mg/l 96 h NOEC : Algae 0.62 mg/l 48 h EC50 : Daphnia magna (Water flea) < 1.0 mg/l 96 h LC50 : Americamysis bahia (mysid shrimp) 0.65 mg/l Environmental Fate Sodium chlorite Biodegradability : Readily biodegradable. Additional ecological information : No data is available on the product itself. SECTION 13. DISPOSAL CONSIDERATIONS Waste Disposal : Treatment, storage, transportation, and disposal must be in accordance with applicable federal, state/provincial, and local regulations. Environmental Hazards : Empty containers should be taken to an approved waste handling site for recycling or disposal. If recycling is not practicable, dispose of in compliance with local regulations. SECTION 14. TRANSPORT INFORMATION 7 / 9
8 DOT UN number : 1908 Proper shipping name : Chlorite solution Class : 8 Packing group : II Labelling No. : 8 IATA_C UN number : 1908 Proper shipping name : Chlorite solution Class : 8 Packing group : II Labelling No. : 8 IMDG UN number : 1908 Proper shipping name : CHLORITE SOLUTION Class : 8 Packing group : II Labelling No. : 8 Marine pollutant : yes (Sodium chlorite) SECTION 15. REGULATORY INFORMATION TSCA SARA 313 Regulated Chemical(s) : On the inventory, or in compliance with the inventory : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. EPA Reg. No. : In the United States this product is regulated by the US Environmental Protection Agency (EPA) under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read and follow all label directions. This product is excluded from listing requirements under EPA/TSCA. California Prop. 65 : Chemicals known to the State of California to cause cancer, birth defects or any other harm: none known 8 / 9
9 NJ Right to Know Regulated Chemical(s) : Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): Sodium chlorite SECTION 16. OTHER INFORMATION NFPA HMIS Health : 1 1 Flammability : 1 1 Reactivity/Physical hazard : 0 0 PPE : Personal Protection rating to be supplied by user depending on use conditions. The DuPont Oval Logo is a registered trademark of E.I. du Pont de Nemours and Company. Contact person : MSDS Coordinator, DuPont Chemicals and Fluoroproducts, Wilmington, DE 19898, (800) The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Significant change from previous version is denoted with a double bar. 9 / 9
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