DuPont Pool Care Multifunctional Shock
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1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : MSDS Number : Manufacturer : Bluegrass Water Products 1400 Bluegrass Lakes Parkway Alpharetta, GA Product Information : (877) Medical Emergency : ACEAN SECTION 2. HAZARDS IDENTIFICATION Potential Health Effects Skin : Causes skin irritation. May cause:, Burns, Ulceration. Eyes : May cause: Severe irritation, Burns, Ulceration, May cause permanent eye injury if not promptly treated.. Inhalation : May cause irritation of respiratory tract. Other effects may include:, Nose bleeding, Cough, Difficulty in breathing, Shortness of breath. Ingestion : May cause: inflammation of the stomach (gastritis), Other effects may include:, Necrosis, Internal bleeding. Aggravated Medical Condition : Skin disorders Gastrointestinal tract Carcinogenicity None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA, as a carcinogen. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No. Concentration Potassium monopersulfate compound Sodium dichloro-s-triazinetrione % Sodium carbonate SECTION 4. FIRST AID MEASURES Skin contact : Immediately flush skin with large amounts of water. Wash contaminated clothing before reuse. Consult a physician. Eye contact : Rinse immediately with plenty of water and seek medical advice. 1 / 7
2 Inhalation Ingestion : Move to fresh air. Artificial respiration and/or oxygen may be necessary. Consult a physician. : Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or poison control centre immediately. SECTION 5. FIRE-FIGHTING MEASURES Flammable Properties Thermal decomposition Fire and Explosion Hazard : Decomposes on heating. : The product itself does not burn. Heating will release oxygen, chlorine, and increase the intensity of the fire. Suitable extinguishing media : Water Unsuitable extinguishing media Firefighting Instructions : Do not use carbon dioxide or other gas-filled fire extinguishers. : Wear self-contained breathing apparatus and protective suit. Evacuate personnel to safe areas. Flood with water. SECTION 6. ACCIDENTAL RELEASE MEASURES NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Safeguards (Personnel) : Wear self-contained breathing apparatus and protective suit. Spill Cleanup : Shovel or sweep up. Flush with plenty of water. Accidental Release Measures : All flushing and clean-up residuals should be collected for proper disposal to prevent soil and surface, ground and sewer water contamination. Prevent material from entering sewers, waterways, or low areas. SECTION 7. HANDLING AND STORAGE Handling (Personnel) : Avoid inhalation. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. Wash hands before eating, drinking, or smoking. Storage : Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from: Combustible material Oxidizing agents Keep away from oxidising agents and strongly acid or alkaline materials. Do not store together with acids and ammonium salts. 2 / 7
3 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls : Use only with adequate ventilation. Personal protective equipment Respiratory protection Hand protection Eye protection Skin and body protection : Wear NIOSH approved respiratory protection as appropriate. : Material: Impervious gloves : Wear safety glasses or coverall chemical splash goggles. Additionally wear a face shield where the possibility exists for face contact due to splashing, spraying or airborne contact with this material. : Where there is potential for skin contact, have available and wear as appropriate, impervious gloves, apron, pants, jacket, hood and boots. Exposure Guidelines Exposure Limit Values Potassium monopersulfate compound AEL * (DUPONT) 1 mg/m3 8 & 12 hr. TWA Total dust. Sodium carbonate AEL * (DUPONT) 5 mg/m3 8 & 12 hr. TWA Total dust. AEL * (DUPONT) 2.5 mg/m3 8 & 12 hr. TWA Respirable dust. * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form : granular Color : white Odor : Chlorine ph : (1% solution in water) % Volatile : < 1 % Specific Gravity : Water solubility : at 20 C (68 F)25 g 100 cc water SECTION 10. STABILITY AND REACTIVITY Stability : Stable under recommended storage conditions. Conditions to avoid Incompatibility Hazardous decomposition : Exposure to moisture. Avoid extreme heat. : oxidizers Halides halogens Heavy metal salts : Decomposition can cause large release of heat., Oxygen, Carbon dioxide 3 / 7
4 products Hazardous reactions (CO2), Chlorine : Polymerization will not occur. SECTION 11. TOXICOLOGICAL INFORMATION Dermal LD50 : > 5,000 mg/kg, rat Oral LD50 : 1,750 mg/kg female, rat Skin irritation : Species: rabbit, Severe skin irritation Sensitisation : Species: mouse, Causes sensitization. Potassium monopersulfate compound Inhalation 4 h LC50 : > 5 mg/l, rat Eye irritation : Corrosive Repeated dose toxicity : Inhalation Eyes, corneal damage, Reversible Oral Stomach, Pathologic changes Mutagenicity : Did not cause genetic damage in cultured bacterial cells., Tests on mammalian cell cultures showed mutagenic effects., Evidence suggests this substance does not cause genetic damage in animals. Teratogenicity : Animal testing showed effects on embryo-foetal development at levels equal to or above those causing maternal toxicity. Sodium dichloro-s-triazinetrione Inhalation 4 h LC50 : mg/l, rat Eye irritation : Species: rabbit irritant Repeated dose toxicity : Oral - drinking water, rat Carcinogenicity : Animal testing did not show any carcinogenic effects. Mutagenicity : Did not cause genetic damage in cultured bacterial cells. Did not cause genetic damage in cultured mammalian cells., Did not cause genetic damage in animals., Information given is based on data obtained from similar product. Reproductive toxicity : Evidence suggests the substance is not a reproductive toxin in 4 / 7
5 animals. Teratogenicity : Evidence suggests the substance is not a developmental toxin in animals. Sodium carbonate Inhalation 4 h LC50 : 0.4 mg/l, guinea pig Eye irritation : Species: rabbit irritant Repeated dose toxicity : Inhalation lung effects Mutagenicity : Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Teratogenicity : Animal testing showed no developmental toxicity. SECTION 12. ECOLOGICAL INFORMATION Aquatic Toxicity Potassium monopersulfate compound 96 h LC50 : Oncorhynchus mykiss (rainbow trout) 53 mg/l 72 h ErC50 : Algae > 1 mg/l 48 h EC50 : Daphnia 3.5 mg/l Sodium dichloro-s-triazinetrione 96 h LC50 : Lepomis macrochirus (Bluegill sunfish) 0.43 mg/l 48 h EC50 : Daphnia magna (Water flea) mg/l Sodium carbonate 96 h LC50 : Lepomis macrochirus (Bluegill sunfish) 300 mg/l 96 h LC50 : Gambusia affinis (Mosquito fish) 1,200 mg/l Additional ecological information : No data is available on the product itself. SECTION 13. DISPOSAL CONSIDERATIONS Waste Disposal : Treatment, storage, transportation, and disposal must be in accordance with applicable federal, state/provincial, and local regulations. 5 / 7
6 SECTION 14. TRANSPORT INFORMATION Not Regulated as a hazardous material by DOT, IMO, or IATA. SECTION 15. REGULATORY INFORMATION TSCA Status : Listed. SARA 313 Regulated Chemical(s) Title III hazard classification : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. : Acute Health Hazard: Yes Chronic Health Hazard: No Fire: No Reactivity/Physical hazard: No Pressure: No EPA Reg. No. : In the United States this product is regulated by the US Environmental Protection Agency (EPA) under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read and follow all label directions. This product is excluded from listing requirements under EPA/TSCA. California Prop. 65 PA Right to Know Regulated Chemical(s) NJ Right to Know Regulated Chemical(s) : This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. : Substances on the Pennsylvania Hazardous Substances List present at a concentration of 1% or more (0.01% for Special Hazardous Substances): Troclosene sodium : Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): Troclosene sodium SECTION 16. OTHER INFORMATION HMIS Health : 3 Flammability : 0 Reactivity/Physi : 2 cal hazard PPE : Personal Protection 6 / 7
7 MSDS preparation date rating to be supplied by user depending on use conditions. : 10/20/2009 The DuPont Oval Logo and DuPont are registered trademarks or trademarks of E. I. du Pont de Nemours and Company or its affiliates. Contact person : MSDS Coordinator, DuPont Chemical Solutions Enterprise, Wilmington, DE 19898, (800) The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Significant change from previous version is denoted with a double bar. 7 / 7
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