Safety Data Sheet Black Olive Exterior 0C03Z MND Revision date : 2013/05/30 Page: 1/7

Transcription

1 Revision date : 2013/05/30 Page: 1/7 1. Product and Company Identification Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) 2. Hazards Identification Emergency overview CAUTION: HARMFUL IF SWALLOWED. CAN CAUSE CENTRAL NERVOUS SYSTEM DAMAGE. CAN CAUSE LIVER DAMAGE. CAN CAUSE LUNG DAMAGE. CAN CAUSE KIDNEY DAMAGE. MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE ALLERGIC RESPIRATORY REACTION. CONTAINS MATERIAL WHICH MAY CAUSE CANCER. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. Large amounts may cause cardiovascular disturbances. Prolonged or repeated exposure effects: May cause systematic poisoning. Overexposure may cause CNS depression including headache, dizziness, nausea and loss of consciousness. May cause reproductive effects. State of matter: solid Colour: grey to black Odour: characteristic Potential health effects Chronic toxicity: Carcinogenicity: May cause cancer. The substance caused cancer in animal studies. Signs and symptoms of overexposure: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Vomiting may cause aspiration pneumonia due to the ingredients.

2 Revision date : 2013/05/30 Page: 2/7 3. Composition / Information on Ingredients CAS Number Content (W/W) Hazardous ingredients % Cobalt oxide (Co3O4) % C.I. Pigment Black % Naphtha (petroleum), heavy alkylate % Mica-group minerals 4. First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If on skin: Wash thoroughly with soap and water. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If swallowed: Rinse mouth thoroughly with water, seek medical attention. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote, administer corticosteroid dose aerosol to prevent pulmonary odema. 5. Fire-Fighting Measures Flash point: > 54 C The product does not burn self-sustainingly. Autoignition: > 300 C Information applies to the solvent. Lower explosion limit: 0.6 %(V) Information applies to the solvent. Upper explosion limit: 6 %(V) Information applies to the solvent. Flammability: not highly flammable Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire.

3 Revision date : 2013/05/30 Page: 3/7 6. Accidental release measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Cleanup: Avoid raising dust. For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. 7. Handling and Storage Handling General advice: Breathing must be protected when large quantities are decanted without local exhaust ventilation. Closed containers should only be opened in well-ventilated areas. Protection against fire and explosion: Avoid dust formation. Sources of ignition should be kept well clear. Take precautionary measures against static discharges. Storage General advice: Keep container tightly closed and dry; store in a cool place. Avoid all sources of ignition: heat, sparks, open flame. 8. Exposure Controls and Personal Protection Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Chemical resistant protective gloves Eye protection: Safety glasses with side-shields. Body protection: Impermeable protective clothing General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: Odour: powder characteristic

4 Revision date : 2013/05/30 Page: 4/7 Odour threshold: No data available. Colour: grey to black ph value: 4-8 Melting point: onset of boiling: approx. 150 C Vapour pressure: 1-2 hpa ( 20 C) Information applies to the solvent. Density: 2.78 kg/l (approx. 20 C) Relative density: 2.78 Bulk density: 278 kg/m3 Vapour density: Viscosity, dynamic: Study does not need to be conducted. Particle size: No data available. Solubility in water: insoluble Solubility in other solvents: insoluble 10. Stability and Reactivity Conditions to avoid: Avoid heat. Avoid dust formation. Avoid all sources of ignition: heat, sparks, open flame. Avoid electro-static discharge. Substances to avoid: strong acids, strong bases, strong oxidizing agents Hazardous reactions: Vapours may form explosive mixture with air. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. 11. Toxicological information Acute toxicity Information on: Odorless Mineral Spirits Assessment of acute toxicity: Virtually nontoxic after a single skin contact. Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Of moderate toxicity after short-term inhalation. Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg Inhalation: Type of value: LC50 Dermal:

5 Revision date : 2013/05/30 Page: 5/7 Type of value: LD50 Irritation / corrosion Skin: Species: rabbit Result: non-irritant Eye: Species: rabbit Result: non-irritant Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. The substance may cause sensitization of the respiratory tract. Repeated dose toxicity Information on: Mica-group minerals Assessment of repeated dose toxicity: Chronic exposures have been known to produce pneumoconiosis (chronic inflammatory and fibrotic lung disease). Genetic toxicity The substance was not mutagenic in mammalian cell culture. The substance was not mutagenic in a test with mammals. Based on the structure, there is a suspicion of a mutagenic effect. Carcinogenicity Information on: Odorless Mineral Spirits The substance caused cancer in animal studies. No data available concerning carcinogenic effects. IARC (International Agency for Research on Cancer) has classified this substance as group 2B (The agent is possibly carcinogenic to humans). Other Information: The product has not been tested. The statements on toxicology have been derived from the properties of the individual components. 12. Ecological Information Fish Acute: Fish/LC50 (96 h): Aquatic invertebrates Acute: daphnia/lc50 (48 h):

6 Revision date : 2013/05/30 Page: 6/7 Aquatic plants Toxicity to aquatic plants: algae/ec50 (72 h): Microorganisms Toxicity to microorganisms: bacteria/ec50 (0.5 h): Degradability / Persistence Biological / Abiological Degradation Evaluation: The product is virtually insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plants. Other adverse effects: The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. The product contains: cobalt The product contains heavy metals. The local waste-water limit values are to be considered for the mentioned heavy metals. 13. Disposal considerations Waste disposal of substance: Must be disposed of or incinerated in accordance with local regulations. Container disposal: The packaging must not be re-used. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. 14. Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations

7 Revision date : 2013/05/30 Page: 7/7 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released; restriction on quantity / not listed THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. 16. Other Information We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations BASF HOTLINE (800) 454 COPE (2673) SDS Prepared on: 2013/05/30 Due to the merger of Engelhard Corp. and BASFGroup all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us under the address mentioned in Section I. END OF DATA SHEET