: Antifreeze cooling liquid.

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1 MSDS Version: E04.00 Datum izdavanja: 21/04/2015 Blend Version: 3 ODJELJAK 1: Identifikacija tvari/smjese i podaci o tvrtki/poduzeću 1.1. Identifikacija proizvoda Naziv proizvoda : Antifreeze Cooling Liquid Sifra proizvoda : W Odgovarajuće identificirane namjene tvari ili smjese i namjene koje se ne preporučuju Upotreba proizvoda Upotreba materijala / pripravka Funkcija ili kategorija uporabe : Antifreeze cooling liquid. : Sredstva protiv smrzavanja Namjene koje se ne preporučuju 1.3. Podaci o dobavljaču koji isporučuje sigurnosno-tehnički list Wynn's Belgium Industriepark-West Sint-Niklaas - Belgium T F msds@wynns.eu Broj telefona za izvanredna stanja Broj hitne pomoći : BIG: +32(0)14/ ODJELJAK 2: Identifikacija opasnosti 2.1. Razvrstavanje tvari ili smjese Razvrstavanje sukladno uredbi (EZ-a) br. 1272/2008 [CLP] Acute Tox. 4 (Oral) STOT RE 2 Cijeli tekst H-izraza: vidi odjeljak 16 H302 H373 Razvrstavanje prema Direktivi 67/548/EEZ [DSD] ili 1999/45/EZ [DPD] Xn; R22 Cijeli tekst R-fraze/upozorenja vidi pod odlomkom 16 Štetni fiziokemijski rizici te rizici za ljudsko zdravlje i okoliš 2.2. Elementi označivanja Označavanje u skladu s odredbom (EU) br. 1272/2008 [CLP] Piktogrami opasnosti (CLP) : Karakteristična riječ (CLP) Opasni sastojci Oznake upozorenja (CLP) Oznake obavijesti (CLP) GHS07 : Upozorenje : Ethanediol GHS08 : H302 - Štetno ako se proguta H373 - Može uzrokovati oštećenje organa tijekom produljene ili ponavljane izloženosti (bubrezi) (ako se proguta) : P102 - Čuvati izvan dohvata djece P260 - Ne udisati aerosol, maglu P264 - Nakon uporabe temeljito oprati ruke P301+P312 - AKO SE PROGUTA: u slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA, liječnika P330 - Isprati usta 2.3. Ostale opasnosti 23/04/2015 HR (Hrvatski) 1/7

2 ODJELJAK 3: Sastav/informacije o sastojcima 3.1. Tvar 3.2. Smjese Naziv Identifikacija proizvoda % w Klasifikacija prema Direktivi 67/548/EEZ Ethanediol (CAS br) (EZ-br) (INDEKS br) (REACH-br) sodium 2-ethylhexanoate (CAS br) (EZ-br) (REACH-br) >= 90 Xn; R Repr.Kat.3; R63 Naziv Identifikacija proizvoda % w Razvrstavanje sukladno uredbi (EZ-a) br. 1272/2008 [CLP] Ethanediol (CAS br) (EZ-br) (INDEKS br) (REACH-br) sodium 2-ethylhexanoate (CAS br) (EZ-br) (REACH-br) Puni tekst R i H oznaka dan je u Odjeljku 16 ODJELJAK 4: Mjere prve pomoći 4.1. Opis mjera prve pomoći Opće mjere prve pomoći Mjere prve pomoći nakon udisanja Mjere prve pomoći nakon dodira s kožom Mjere prve pomoći nakon dodira s očima Mjere prve pomoći nakon gutanja 4.2. Najvažniji simptomi i učinci, akutni i odgođeni Simptomi/ozljede nakon udisanja Simptomi/ozljede nakon kontakta s kožom Simptomi/ozljede nakon kontakta s očima Simptomi/ozljede nakon gutanja >= 90 Acute Tox. 4 (Oral), H302 STOT RE 2, H Repr. 2, H361d : Provjerite vitalne funkcije. Victim conscious with laboured breathing: half-seated. Žrtva nije pri svijesti: održavati odgovarajuće disanje i dotok zraka. Prestanak disanja: umjetno disanje ili kisik. Srčani zastoj: započnite s oživljavanjem. Victim in shock: on his back with legs slightly raised. Povraćanje: spriječiti gušenje/aspiracijsku upalu pluća. Nastavite pratiti žrtvu. Pružiti psihološku pomoć. Spriječiti pothlađivanje pokrivanjem žrtve (ne zagrijavanjem). Držite unesrećenog mirno, izbjegavati fizički napor. Depending on the victim's condition: doctor/hospital. : U slučaju otežanog disanja premjestiti unesrećenog na svježi zrak, umiriti ga i postaviti u položaj koji olakšava disanje. U slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA ili liječnika. : U slučaju dodira s kožom odmah skinuti natopljenu odjeću a kožu odmah oprati s puno vode i sapuna. U slučaju nadražaja ili osipa na koži: zatražiti savjet/pomoć liječnika. : U SLUČAJU DODIRA S OČIMA: oprezno ispirati vodom nekoliko minuta. Ukloniti kontaktne leće ukoliko ih nosite i ako se one lako uklanjaju. Nastaviti ispiranje. Ako nadražaj oka ne prestaje: zatražiti savjet/pomoć liječnika. : Isprati usta. NE izazivati povraćanje. Odmah nazvati CENTAR ZA KONTROLU OTROVANJA ili liječnika. Gutanje velikih količina: odmah ići u bolnicu. : Depresija središnjeg živčanog sustava, glavobolja, vrtoglavica, pospanost, gubitak koordinacije. Nadraženost grla. Mučnina. : nadraženost kože i crvenilo Hitna liječnička pomoć i posebna obrada ODJELJAK 5: Mjere gašenja požara 5.1. Sredstva za gašenje Prikladna sredstva za gašenje Neprikladna sredstva za gašenje : Može uzrokovati blagu nadraženost. : Štetno ako se proguta. Grčevi. Mučnina. Otežano disanje. Nesvijest. : Mogu se koristiti sve vrste sredstva za gašenje. : Ne da nam je poznato. Ako je u blizini požar, koristite odgovarajuća sredstva za gašenje požara. 23/04/2015 HR (Hrvatski) 2/7

3 5.2. Posebne opasnosti koje proizlaze iz tvari ili smjese Opasnost od eksplozije Reaktivnost : Proizvod nije eksplozivan. : Burno reagira s jakim oksidansima i kiselinama Savjeti za gasitelje požara Neprikladno sredstva : Ne ulaziti u požarom zahvaćeno područje bez odgovarajuće zaštitne opreme, uključujući zaštitu dišnih organa. ODJELJAK 6: Mjere kod slučajnog ispuštanja 6.1. Osobne mjere opreza, zaštitna oprema i postupci u slučaju opasnosti Za osobe koje se ne ubrajaju u interventno osoblje Zaštitna oprema Planovi za prvu pomoć : Pri radu nositi odgovarajuće zaštitne rukavice i zaštitne naočale/masku. protective clothing. : Označiti opasno područje. Take off contaminated clothing and wash before reuse Za interventno osoblje Zaštitna oprema : Opremiti tim za čišćenje prikladnom zaštitom Mjere zaštite okoliša Spriječiti ulazak u kanalizaciju i javne vode. Izbjegavati ispuštanje u okoliš Metode i materijal za sprečavanje širenja i čišćenje Za zadržavanje Postupci čišćenja 6.4. Uputa na druge odjeljke ODJELJAK 7: Rukovanje i skladištenje 7.1. Mjere opreza za sigurno rukovanje Mjere opreza za sigurno rukovanje Higijenske mjere : Sakupiti proliveno/rasuto. Sadrži tvari koje cure, crpkom isprazniti proizvod u odgovarajuće spremnike. : Male količine prolivene tekućine: sakupiti nezapaljivim upijajućim materijalom i lopatom premjestiti u spremnik radi odlaganja. Male količine prolivene tekućine: sakupiti nezapaljivim upijajućim materijalom i lopatom premjestiti u spremnik za odlaganje. Onečišćene površine: očistiti (tretirati) s velikim količinama vode. Nakon upotrebe očistiti opremu i odjeću. Ovaj materijal i njegov spremnik moraju biti disponirani na siguran način, sukladno lokalnim zakonima. : meet the legal requirements. Ne predstavlja posebnu opasnost ako se postupa sukladno praksi dobre industrijske higijene. : Observe normal hygiene standards. Oprati ruke i druga izložena područja blagim sapunom i vodom prije jela, pića ili pušenja, te prilikom završetka posla. Oprati zagađenu odjeću prije ponovne uporabe Uvjeti sigurnog skladištenja, uzimajući u obzir moguće nespojivosti Tehničke mjere i uvjeti sklaidštenja Uvjeti skladištenja Skladišna temperatura : 0-40 C Područje pohrane Posebni propisi za pakovanje 7.3. Posebna krajnja uporaba ili uporabe : Ne zahtijeva nikakve posebne ili pojedine tehničke mjere. : Meet the legal requirements. Skladištiti na suhom mjestu. Skladištiti u zatvorenom spremniku. Zaštititi od sunčevog svjetla. : Meet the legal requirements. Zaštititi od vrućine i neposredne izloženosti suncu. : correctly labelled. Skladištiti u zatvorenom spremniku. ODJELJAK 8: Nadzor nad izloženošću/osobna zaštita 8.1. Nadzorni parametri EZ IOELV TWA (mg/m³) 52 mg/m³ EZ IOELV TWA (ppm) 20 ppm EZ IOELV STEL (mg/m³) 104 mg/m³ EZ IOELV STEL (ppm) 40 ppm Belgija Granična vrijednost (mg/m³) 52 mg/m³ Belgija Granična vrijednost (ppm) 20 ppm Belgija Kratkoročna vrijednost (mg/m³) 104 mg/m³ 23/04/2015 HR (Hrvatski) 3/7

4 Belgija Kratkoročna vrijednost (ppm) 40 ppm Belgija Napomena (BE) D, M 8.2. Nadzor nad izloženošću Prikladni tehnički kontrolni uređaji Osobna zaštitna oprema : Osigurati dobro prozračivanje radnog prostora kako bi se spriječilo stvaranje pare. U neposrednoj blizini mjesta s bilo kakvom potencijalnom izloženošću bi trebali biti postavljeni sigurnosni tuševi za hitno ispiranje očiju. Ne zahtijeva nikakve posebne ili pojedine tehničke mjere. : Rukavice od neoprena ili obične gume. Sigurnosna stakla. Zaštita ruku Zaštita dišnih puteva Ostale informacije : Neopren. Nitrilna guma. PVC (Polyvinyl chloride). Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Vrijeme prodiranja određuje proizvođač rukavica. : U slučaju nedovoljnog prozračivanja nositi sredstva za zaštitu dišnog sustava. High gas/vapour concentration: gas mask with filter type A. : Vrijeme prodiranja: >30'. Thickness of the glove material >0.1 mm. ODJELJAK 9: Fizikalna i kemijska svojstva 9.1. Informacije o osnovnim fizikalnim i kemijskim svojstvima Agregatno stanje Izgled Boja Miris Prag mirisa : Tekućina : jasan. : Plavo. : Slatko. ph : 7,1-7,3 Relativna stopa isparavanja (butilacetatom=1) refraction index : 1,433 Talište Točka solidifikacije Vrelište : > 165 C Plamište : > 110 C Temperatura samozapaljenja Temperatura raspadanja Zapaljivost (kruta tvar, plin) Tlak pare Relativna gustoća pare kod 20 C Relativna gustoća C Topljivost Log Pow Log Kow Viskoznost, C Viskoznost, C Viskoznost : Viskoznost Index : Eksplozivna svojstva Oksidacijska svojstva Granice eksplozivnosti : kg/m³ : Topljivo u vodi Ostale informacije dodatne obavijesti : The physical and chemical data in this section are typical values for this product and are not intended as product specifications. 23/04/2015 HR (Hrvatski) 4/7

5 ODJELJAK 10: Stabilnost i reaktivnost Reaktivnost Burno reagira s jakim oksidansima i kiselinama Kemijska stabilnost Stabilan pod normalnim uvjetima Mogućnost opasnih reakcija Uvjeti koje treba izbjegavati Izravna sunčeva svjetlost Inkompatibilni materijali Oksidirajuće sredstvo. Snažne kiseline. Aluminija. Rubber articles Opasni proizvodi raspada On burning: release of harmful/irritant gases/vapours e.g.: carbon monoxide - carbon dioxide. ODJELJAK 11: Toksikološki podatci Informacije o toksikološkim učincima akutna toksičnost : Oralno: Štetno ako se proguta. Antifreeze Cooling Liquid ATE CLP (oralno) ATE CLP (oralno) Nagrizanje/nadraživanje kože Ozbiljno oštećenje/nadraživanje očiju Izazivanje preosjetljivosti dišnih putova ili kože Mutageni učinak na spolne stanice Kancerogenost Reproduktivna toksičnost TCO jednokratno izlaganje TCO ponavljano izlaganje opasnost od aspiracije Moguća štetna djelovanja na čovjeka i mogući simptomi 537,634 mg / kg tjelesne težine 500,000 mg / kg tjelesne težine ph: 7,1-7,3 ph: 7,1-7,3 : Može uzrokovati oštećenje organa tijekom produljene ili ponavljane izloženosti (bubrezi) (ako se proguta) : Štetno ako se proguta. ODJELJAK 12: Ekološke informacije Toksičnost Ekologija - opšte Postojanost i razgradivost Postojanost i razgradivost Bioakumulacijski potencijal Bioakumulacijski potencijal Pokretljivost u tlu Literature reports: readily degradable in water. Neodređeno Rezultati ocjenjivanja svojstava PBT i vpvb 23/04/2015 HR (Hrvatski) 5/7

6 12.6. Ostali štetni učinci ODJELJAK 13: Zbrinjavanje Metode obrade otpada Preporuke za odlaganje otpada : Uklonite u postrojenje ovlašteno za obradu otpada. Odložite na siguran način u skladu s lokalnim/državnim propisima. ODJELJAK 14: Informacije o prijevozu U skladu sa zahtjevima ADR / RID / IMDG / IATA / ADN UN broj Neopasni teret obzirom na transportne propise Ispravno otpremno ime UN ( Proper Shipping Name ) Prijevozni razred(i) opasnosti Skupina pakiranja Opasnosti za okoliš Ostale informacije : Posebne mjere opreza za korisnika Transport kopnom Prijevoz morem Zračni prijevoz Prijevoz u razlivenom stanju u skladu s Prilogom II. Konvenciji MARPOL 73/78 i Kodeksom IBC ODJELJAK 15: Informacije o propisima Propisi u području sigurnosti, zdravlja i okoliša/posebno zakonodavstvo za tvar ili smjesu EZ-propisi Ne sadrži tvari u pogledu ograničenju Priloga XVII Antifreeze Cooling Liquid nije na popisu kandidata REACH Ne sadrži tvari na popisu kandidata REACH Ne sadrži tvari iz REACH Priloga XIV Nacionalni propisi Klasa ugroženosti vode (WGK) : 2 - koji ugrožava vodu Ocjenjivanje kemijske sigurnosti ODJELJAK 16: Ostale informacije Puni tekst ili R-, H- i EUH-fraze: Acute Tox. 4 (Oral) Repr. 2 STOT RE 2 H302 Akutna toksičnost (gutanje), 4. kategorija opasnosti Reproduktivna toksičnost, 2. kategorija opasnosti Specifična toksičnost za ciljane organe ponavljano izlaganje, 2. kategorija opasnosti Štetno ako se proguta 23/04/2015 HR (Hrvatski) 6/7

7 H361d H373 R22 R63 Xn Postoji sumnja da šteti plodu Može uzrokovati oštećenje organa tijekom produljene ili ponavljane izloženosti Štetno ako se proguta Moguća opasnost štetnog djelovanja na plod Štetno Ova je informacija temeljena na našem trenutnom znanju i namjera joj je opisati proizvod samo za zdravstvene, sigurnosne i ekološke uvjete. Stoga se je treba tumačiti kao jamstvo za bilo koje specifično svojstvo proizvoda 23/04/2015 HR (Hrvatski) 7/7

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