MATERIAL SAFETY DATA SHEET PRODUCT: Magellan XPA Universal

Transcription

1 Product: Chemical Family: Product Use: Manufacturer: SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Magellan XPA Universal Aromatic isocyanate Adhesive Magellan XPA P.O. Box Cambridge, MA Telephone Number: (617) In Emergency Only: CANUTEC Collect: (613) (24-hour hotline) Information: (613) Emergency Overview: Potential Health Effects: SECTION 2: HAZARDS IDENTIFICATION Beige coloured, thick liquid. Combustible. Harmful by inhalation. Harmful if swallowed. May cause eye, skin, and/or respiratory tract irritation. May cause skin and/or respiratory sensitization. Eyes Irritant. Skin Irritant. Sensitizer. Prolonged or repeated contact can lead to severe irritation. Inhalation Irritant. Sensitizer. Harmful by inhalation of isocyanate vapours. May cause breathlessness, chest discomfort and reduced pulmonary function. Ingestion Will cause adverse health effects. Chronic Effects Prolonged or repeated inhalation of isocyanate vapours can cause lung damage. Heating of the product can release additional vapours. This product should not be used without adequate ventilation. SECTION 3: HAZARDOUS INGREDIENT INFORMATION Ingredient % (W/W) CAS Number Polylmeric diphenylmethane diisocyanate Methylenediphenyl diisocyanate Diphenylmethane-4,4 -diisocyanate Benzenesulfonyl Isocyanate,4-methyl Naphtha, heavy alkylate Eyes: SECTION 4: FIRST AID MEASURES Flush open eyes with water for 15 minutes. Seek immediate medical attention. Page 1 of 5

2 Skin: Inhalation: Ingestion: Flammable Properties: Extinguishing Media: Hazardous Combustion Products: Protection of Fire Fighters: Remove affected clothing. Wash skin with soap and water immediately. Wash contaminated clothing before re-use. Seek medical attention if irritation occurs. Move to fresh air. Administer oxygen if necessary. Seek immediate medical attention. Do not induce vomiting. Give at least two glasses of milk or water. Never give anything by mouth to an unconscious person. Seek medical attention immediately. SECTION 5: FIRE FIGHTING MEASURES Material is combustible: isolate from heat, open flame and sparks. CO 2, chemical foam, dry chemical, water spray. Do not use water jet. CO, CO2 Self contained breathing apparatus and full protective clothing should be worn by fire fighters. SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protective equipment as recommended in Section 8. Environmental Do not empty into drains or discharge into the soil/subsoil. Precautions: Methods for Containment: Eliminate all ignition sources. Absorb with an inert material. Place in an opentop container and remove to a ventilated area. Allow to sit in an open container for 24 hours. Methods for Clean-Up: Flush area with water to remove trace residue. General Warning to Prevent Exposure: General Storage Information: SECTION 7: HANDLING AND STORAGE Do not breathe fumes or vapours. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Keep containers tightly closed when not in use. Combustible. Handle and open containers with care. Store in tightly-sealed containers in a cool, dry area. Do not handle near open flames, heat or other ignition sources. Do not open containers until ready to use. Page 2 of 5

3 SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Ingredient Exposure Limit Unit Polymeric diphenylmethane diisocyanate 0.05 (TLV ACGIH) mg/m3 Methylenediphenyl diisocyanate Not established --- Diphenylmethane-4,4 -diisocyanate (TWA ACGIH) ppm Benzenesulfonyl Isocyanate,4-methyl Not established --- Naphtha, heavy alkylate 525 (TLV ACGIH) mg/m3 Engineering Controls: Personal Protective Equipment: Appearance: Odour: Melting Point: Boiling Point: Flash Point and Method: Evaporation Rate (Butyl acetate = 1) Upper/Lower Flammable Limits: Vapour 25 C: Vapour Density: Specific 25 C: Solubility: Use local exhaust ventilation or other engineering controls to keep airborne levels below recommended exposure limits. Eyes: Safety glasses, chemical goggles. Skin: Chemical-resistant clothing, gloves and footwear. Inhalation: NIOSH-approved organic respirator if TLV is exceeded. Other: Eye bath and safety shower. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Beige coloured liquid. >65 C (149 F) CC 1.55 g/ml SECTION 10: STABILITY AND REACTIVITY Page 3 of 5

4 PRODUCT: Magellan XPA Univeral Chemical Stability: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Possibility of Hazardous Reactions: Stable Moisture, heat, sparks, ignition sources, vapour accumulation. Strong oxidizers, acids, bases. CO. CO Will not occur. SECTION 11: TOXICOLOGICAL INFORMATION Acute Dose Toxicity: Naphtha, heavy alkylate Oral LD 50 > 8000 mg/kg (rat) Dermal LD 50 > 4000 mg/kg (rabbit) Polymeric diphenylmethane Dermal LD 50 > 5000 mg/kg (rabbit) diisocyanate Benzenesulfonyl Isocyanate,4-methyl Oral LD mg/kg (rat) Repeated Dose Toxicity: Sensitization: May cause sensitization by skin contact or by inhalation. Carcinogenicity: Not listed Neurological Effects: Genetic Effects: Reproductive Effects: Developmental Effects: Target Organ Effects: Lungs chronic inhalation can cause respiratory distress and respiratory impairments SECTION 12: ECOLOGICAL INFORMATION Biodegradability SECTION 13: DISPOSAL CONSIDERATIONS Recover or recycle if possible. Uncured product is hazardous waste. Incinerate in accordance with federal, state, and local environmental controls/regulations. All provided information only applies to the material as supplied to the user. The characteristics outlined may not apply if the material has been used or otherwise contaminated. It is the responsibility of the user to determine the proper waste identification and disposal methods in compliance with applicable regulations. Page 4 of 5

5 US Regulations: Canadian Regulations: SECTION 14: TRANSPORT INFORMATION NOT REGULATED FOR TRANSPORTATION SECTION 15: REGULATORY INFORMATION All of the components of this material appear on the Toxic Substances Control Act (TSCA) inventory. As per WHMIS, this material is classified: B3, D2A, D2B All of the components of this material appear on the Domestic Substances List (DSL). This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required in the Controlled Products Regulations. SECTION 16: Other Information Abbreviations: Not established The conditions of your use and application of our products, technical assistance and information (whether verbal, written or by way of production evaluations), including any suggested method of application and recommendations, are beyond our control. Therefore, it is imperative that you test our products, technical assistance and information to determine to your own satisfaction whether they are suitable for your intended uses and applications. This application-specific analysis must at least include testing to determine suitability from a technical as well as health, safety, and environmental standpoint. Such testing has not necessarily been done at Magellan XPA. All technical assistance and information provided with respect to Magellan XPA's products is subject to Magellan s Terms and Conditions, including the limited warranty therein. Magellan XPA s Terms and Conditions appear on the reverse side of Magellan XPA s credit applications and invoices and are available upon your request. Except as expressly provided in the Terms and Conditions, Magellan XPA's excludes all express and implied warranties, representations, conditions and objections, whether statutory or otherwise, concerning the quality of the products of Magellan XPA's or their fitness for any particular purpose. It is expressly understood and agreed that the customer assumes and hereby expressly releases Magellan XPA's from all liability, in tort, contract, or otherwise, incurred in connection with the use of our products, technical assistance and information. Any statement or recommendation not contained herein is unauthorized and shall not bind Magellan XPA. Nothing herein shall be construed as a recommendation to use any product in conflict with patents covering any material or its use. No license is implied or in fact granted under the claims of any patent. Page 5 of 5