1. Identification of the Substance and of the Company :
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1 1. Identification of the Substance and of the Company : Product Description : Pharma Glycerine 99.5 % Product Code No : Synonyms : E 422 1,2,3 Propanetriol Glycerol Trihydroxypropane Intended Uses of the Substance: Pharma grade glycerine for application in cosmetics, pharmaceuticals Manufacturer/supplier identification: Company Address :Evyap Sabun,Yağ Gliserin San. Tic. A.Ş :Ayazağa Mah. Kemerburgaz Cad. No: Sisli - ISTANBUL TURKEY Emergency Phone Number/ Contacts Pbx : (0212) (LINE 40) Fax : (0212) Tlx : EVYA TR EVEX TR 2. Hazards Identification : Health hazards inhalation : Not applicable at ambient temperature Vapour from heated product can cause irritation. Skin contact : Not irritating. Eye contact : Can cause irritation. Ingestion : Unlikely to be harmful.can cause diarrhoe if big amounts are swallowed ( > 50 g/day for children, > 100 g/day for adults) Physical / Chemical hazards : At incomplete combustion can acrolein be formed Environmental hazards : None identified 1/5
2 3. Composition / Information on Ingredients : CAS registry number : EINECS Number : EINECS name : 1,2,3-propanetriol Bruta Formula : C 3 H 5 (OH) 3 Molecular weight : 92,09 Concentration : Min % Additivites : None Known impurities causing risks : None 4. First aid measures : Inhalation Skin contact Eye contact Ingestion : Remove to fresh air : Wash off with plenty of water and soap. : Wash out with water without delay and obtain medical attention if any sensation persist. : Remove material from mouth.drink plenty of water.if large amount of swallowed or symptoms develop obtain medical attention. 5. Fire fighting measures : General Information : Glycerin has a high flash point ( 350ºF or 177ºC) and ( 400ºF or 204ºC). Extinguishing Media : Use water spray to cool fire-exposed containers.use agent most appropriate to extinguish fire.use water spray,dry chemical,carbondioxide,or appropriate foam. Specific Hazards: Formation of acrolein,see point 2 above. 6. Accidental release measures : Personal Precautions : No special precautions required. Environmental precautions : No specific protective measures are required Methods for Cleaning Up : Transfer product to suitably labelled containers for disposal at an approved site.absorb liquid spillage inert material,for example sand.residues and small spillages may be washed away with water and detergent. 2/5
3 7. Handling and storage : Handling : No special protective measures are required. Prevent formation of mist. Storage : Since glycerin is hygroscopic,preserve in tightly closed containers at 20 ºC. The container should also be of a design to permit easy cleaning and maintanence Other information : For quality reasons, avoid elevated temperatures 8.Exposure controls / personal protection : Hygiene measures Engineering measures Occupational exposure limits Personal Protective Equipment : Good industrial hygiene should be followed. : Provide ventilation to meet exposure limits. : TWA : 10 mg/m _(mist) : Normal precautions should be observed as for handling all chemicals. 9. Physical data and chemical properties : Appearance : Colourless viscous, liquid Odour : Odourless Spesific Gravity (25ºC) : Min Colour : According to USP Residue On Ignition : Max % Chloride : Max % Sulfate : Max % Heavy Metals : Max. 5 ppm Sugars : Negative Chlorinated Compounds: % of Cl Fatty Acids and Esters : Max. 1.0 ml of 0.5 N NaOH is consumed Water : Max. 0.5 % Glycerin : Min % Identification [B ] (Limit of diethylene glycol and ethylene glycol) : Max. 0,1% Related Compounds: Max %0,1; Max %1 TOTAL 3/5
4 Physical form at room temperature : syrup liquid Boiling point : 290 ºC Melting point : 17.8 ºC Vapor pressure : mm Hg Solubility : Soluble in water, insoluble in ether /chloroform. Evaporation rate : not found Reactivity in water : not found % Volatile by volume : not found 10. Stability and Reactivity : Stability : Stable under normal conditions. Conditions to avoid : None Materials to avoid : Oxidizing agents. Hazardous decomposition products : Thermal decomposition may release acrolein, Hazardous polymerization : Will not occur. 11. Toxicological information : Oral Rat : LD50 : mg / kg ( Pratically non toxic) Oral Mouse : LD50 : 4900 mg / kg ( Pratically non toxic) Irritancy Organ(s) : Eyes,Skin, Lungs and Kidneys Listed as a Carcinogen : NTP : No ; IARC : No ; Osha : No ; Other : not found Routes of Exposure : Ingestion. Toxicological effects due to exposure to the substance /mixture : According to our knowledge, if used correctly,this product is not dangerous. 12.Ecological Information : Degradability Ecotoxicity LC 50,fish : Completely biodegradable BOD 5 / COD : 0,75 / 1,00 ( g O 2 /g) : >5000 mg 4/5
5 EC 50,algae EC 50,Pseudomonas Putida : >2900 mg/l : >10000 mg/ l 13.Disposal considerations : Waste Disposal Method : Waste incineration or special in complience with local Contaminated packaging : Observe local regulations Transport Information : Not classified in RID / ADR ADNR IMDG ICAO /IATA-DGR 15. Regulatory Information : EU classification : Not dangerous within the meaning of Directive 67 / 548 /EEC-88/379 EEC and Regulation 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL Reach Status : Exempt from Reach according to Regulation (EC) No 1907/ Annex V 16. Other Information : The components of the product are described in EINECS 5/5
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