MATERIAL SAFETY DATA SHEET

Transcription

1 DKJ MADE OUT ON: UPDATED ON REVISION 11 (dept. symbol, register no.) (year)(subsequent no. during the year) (yyyy-mm-dd) (yyyy-mm-dd) SECTION 1: Substance/mixture and company 1.1. Product identification Lead minium. CAS: EINECS Registration number: Commercial denominations of products: lead minium 1.2. Significant identified applications of substance or mixture and adverse applications Used for production of accumulators, ceramics and lead glass. Wykorzystywana w przemyśle elektronicznym, pirotechnicznym oraz jako substrat do produkcji związków organicznych Information on the party submitting the data sheet ZM SILESIA SA Oddział Huta Oława w Oława ul. Sikorskiego Oława, Poland telephone: Emergency telephone number SECTION 2: Identification of hazards 2.1. Classification of substance or mixture In accordance with the directive (EC) 1272/2008 classified as follows : Physical and chemical parameters not classified Health hazards Swallowing acute toxicity 4 (H302 Harmful if swallowed) Inhalation acute toxicity 4 (H332 Harmful if inhaled) Toxic for reproductiveness Repr. 1A (H360Df - May be harmful for a child in the womb. It is suspected it impairs reproduction.) Environmental hazards substances or mixtures implying hazards for aqueous environment severe risk, category 1. Factor M 1 (H410 - Very toxic for aqueous organisms, causing long-lasting effects) 1

2 Toxic effects on target organs recurrent exposure (STOT-RE) (H373 - May cause damage to internal organs) In accordance with the directive DSD and the order of the Ministry of Health of September 2, 2003 regarding criteria and mode of classification of chemical substances and preparations, classified as follows : Physical and chemical parameters not classified Health hazards toxic (T) Environmental hazards substance dangerous for environment (N) Kind of hazard R 61 - May be harmful for a child in the womb R 62 - Possible risk of reproduction impairment R 20/22 - Harmful effects through the respiratory system and if swallowed R 33 - Danger of accumulation in the organism R 50/53 - Very toxic for aqueous organisms; may cause long-lasting changes in the aqueous environment Description of correct safety measures S 53 Avoid exposure - read the instructions before use S 45 In case of emergency or if you feel bad, consult a doctor immediately - show the label, if possible S 60 The substance and its packaging are to be disposed as dangerous waste S 61 Avoid dumping to the environment. Proceed in accordance with the instruction or the data sheet 2.2. Symbols 2

3 GHS09: Environment GHS07: Exclamation mark Warning: danger GHS08: Health hazard Expressions indicating kind of hazard: H302 Harmful if swallowed. H332 Harmful if inhaled. H351 Suspected of causing cancer H360Df May be harmful for a child in the womb. It is suspected it impairs reproduction. H373 May cause damage to internal organs H410 Very toxic for aqueous organisms, causing long-lasting effects. 3

4 Expressions indicating measures to be taken: P202 Do not use unless you have acquainted yourself with and understood all the safety measures. P263 Avoid contact during pregnancy and lactation. P273 Avoid dumping to the environment. P281 Use personal protective equipment as required. P308+P313 In case of exposure or contact: Consult a doctor. P405 Store locked. P501 Contents/container to be disposed in accordance with the local waste management regulations. To be treated as dangerous waste Other hazards Unknown SECTION 3: Ingredients 3.1. Substances: Name Lead oxide (II, IV) Chemical formula Pb 3 O4 CAS: EINECS Molar mass g/mol Concentration of the substance 100% 3.2. Mixtures SECTION 4: First aid measures 4.1. Description of first aid measures In case of ailments caused by inhalation of dust: move the person to fresh air and consult a doctor In case of ingestion: rinse the mouth with water. Call a doctor. Proceed in accordance with the doctor s instructions. In case the substance gets in the eyes: lift the eyelid and rinse thoroughly under running water; consult a doctor in case of irritation. 4

5 In case of contact with the skin: wash the skin with water and soap. Consult a doctor in case of irritation. Remove contaminated clothes. Instructions for the doctor: lead poisoning may be detected through lead marking in the blood and/or urine. Check the level of delta-aminolevulinic acid Major acute and delayed symptoms and results of exposure See PART Indications regarding immediate medical aid and special treatment of the injured SECTION 5: Measures in case of fire 5.1. Extinguishing media Recommended extinguishing media: sprayed water, foam, carbon dioxide (CO2), dry extinguishing media, neutral powder extinguisher. Not recommended extinguishing media: do not use a pressurized water jet to extinguish fire, since the product is dusty Specific hazards related to the substance or mixture In case of fire lead oxides and lead vapours may be generated Information for the fire brigade Personal protective means for firefighters: in case of fire use oxygen respirators during firegighting. Further recommendations: Residues from fire and residues of extinguishing water must be eliminated in accordance with the national and regional regulations. SECTION 6: Proceeding in case of unintended release to the environment 6.1. Personal protective measures, protective equipment and procedures in case of emergency Personal protection: Avoid dusting. Wear dust masks. Prevent access of persons not wearing masks Measures for environmental protection Do not permit release to sewage, surface waters or soil Methods and materials for prevention of contamination spread and for elimination of contamination 5

6 Cleansing / collecting: in order to avoid dusting, collect the substance using a moist or absorbing material. Transport the collected material in tightly closed containers. Dangerous waste References to other parts Waste handling, see SECTION 13. SECTION 7: Handling and storage of substances and mixtures 7.1. Safe handling measures Always read the information in the label. Use safety measures to comply with the legally determined limit values of lead concentration in the air (NDS) in accordance with the state of technology, air-tight sealing, (extractors, wet cleansing, etc.), protection of the respiratory system Safe storage conditions, along with the information regarding any mutual inconsistencies Store in roofed premises at a room temperature. The packaging must be closed. Humidity impairs the quality. Do not store together with foods and fodders Specific target applications SECTION 8: Control of exposure / personal protective means 8.1. Control parameters Concentration at the work place, maximum limit values: NDS 0.05 mg Pb/m Exposure control Personal protective means Protection of the respiratory system: In case of presence of dusts, wear respirators with appropriate dust filters Hand protection: protective gloves Skin/body protection: wear working clothing General instructions regarding protection and hygiene: Store away from foods, beverages and fodders. Do not ever eat, drink, smoke or take snuff at the work place. Wash hands and face and rinse the mouth before breaks and after work. Do not take 6

7 contaminated working clothing home. Workers clothes may not be in contact with working clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Form: solid body, dust Colour: red Odour: odourless Decomposition point 538 o C Ignition point: non-flammable Combustion properties: non-flammable product Explosive properties: explosive safe product Oxidizing properties: above 538ºC decomposition with emission of oxygen Vapour pressure: (20oC) not applicable Density: (20 C) 9.0 g/cm3 Solubility in water: practically insoluble Value ph (at 100g/l H20) Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of dangerous reactions Conditions to be avoided Incompatible materials Dangerous decomposition products Dangerous decomposition products: Does not decompose if stored and handled in accordance with Point 7. Soluble in acids and alkalies. Water impairs the quality and may cause agglomeration. SECTION 11: Toxicological information Information on toxicological effects 7

8 Acute toxicity: Significant valuedl50/cl50 Ingredient Way Value Kind Lead oxide (II,IV) orally above 10,000 mg/kg rat Irritating limit: for the skin: not irritating for a rabbit for the eyes: not irritating for rabbit s eyes Further toxicological information: Lead compounds are harmful in case of inhaling and swallowing (T, R 20/22) Chronic toxicity: Lead pigments are hardly soluble lead compounds. However they dissolve in hydrochloric acid contained in gastric juice and may then accumulate in the organism (T, R 33). In case of a prolonged and excessive ingestion of lead compounds there is for example a risk of haemoglobin biosynthesis disturbances and irreversible damage to the nervous system. Lead compounds are classified as harmful for reproduction (Repro. Category 1; R 61) Further toxicological information SECTION 12: Ecological information Toxicity Lead compounds are dangerous for aqueous environment (N; R 50/53) Instructions for neutralization: Slightly soluble in water inorganic product. Possible to eliminate in a mechanical water treatment plant. In an acidic or basic medium it may go to the solution. Elimination of ions from water through chemical precipitation Stability and propensity for decomposition Stable in the soil, hardly soluble in water, do not decompose Capacity of bioaccumulation No data Mobility in the soil No data Results of evaluation of PBT and vpvb properties The criteria apply exclusively to organic substances Other harmful effects 8

9 SECTION 13: Handling of waste Methods of neutralization of waste Product: Product containing lead. Requires special procedures. It should be transported and handled in a special manner (dangerous product). Do not eliminate in an incinerating plant. Contaminated containers: Contaminated containers should be treated in the same way as the product itself. Empty containers contaminated externally with lead minium are not accepted for transport (ADR). SECTION 14: Transport information Road transport/adr/rid and GGVS/GGVE (abroad/domestic) UN 2291 LEAD COMPOUND, SOLUBLE, I.N.O. Class 6.1 Classification code T5 Packaging group III Hazard identification number: 60 label 6.1 fish /RID-GGVS/E: Sea transport: class 6.1 Packaging group III Air transport ICAO-TI and IATA-DGR: class 6.1 UN/ID-Nr 2291 PG III SECTION 15: Information on legal regulations Legal regulations regarding safety, health and environmental protection specific for substances or mixtures 1. Chemical Substances and Preparations Act (Law Gazette No. 11/2001 Item84) along with the subsequent amendments. 2. Directive of the Minister of Health of September 28, 2005 (Legal Gazette 201/2005 Item1674) - List of dangerous substances with their classification and marking. 9

10 3. Directive of the Minister of Health of July 3, 2002 regarding data sheet for dangerous substances and dangerous preparations, (Legal Gazette No. 140/2002 Item 1171) along with the subsequent amendments. 4. Directive of the Minister of Labour and Social Policy of November 29, 2002regarding the maximum acceptable concentrations and intensities of harmful factors in the working environment. (Law Gazette No. 217/2002 Item 1833) along with the subsequent amendments. 5. Directive modifying the directive regarding data sheet for dangerous substances and dangerous preparations, Directive of the Minister of Health of December 14, 2004 (Legal Gazette z Nr 2 Item 8). 6. DIRECTIVE (EC) NO. 1907/2006 OF THE EUROPEAN PARLIAMENT AND THE EUROPEAN COUNCIL of December 18, 2006 regarding Registration Evaluation and Authorisation of Chemicals(REACH) and creation of the European Chemicals Agency, modifying the directive 1999/45/EC and repealing the directive of the European Council (EEC) No. 793/93 and the directive of the European Commission (EC) No. 1488/94, as well as the directive of the European Council 76/769/EEC and the directives of the European Commission 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC 7. Contract ADR Directive (EC) No. 1272/2008 regarding classification, marking and packaging of substances and mixtures, modifying and repealing the directives 67/548/EEC and 1999/45/EC as well as modifying the directive (EC) No. 1907/2006 (REACH) Evaluation of chemical safety SECTION 16: Other information The information is presented in accordance with the present knowledge, which however does not constitute a full protection from the harmful effects of the substance and may not be a basis for legal claims. Source of the data: Quality Control Department Informant: Engineer Łukasz Jańczyk, M.Sc. Telephone: