Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

Transcription

1 Safety Data Sheet Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name Lock-Tape Product Code ; ; ; ; Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) Repair tape 1.3 Details of the supplier of the safety data sheet Manufacturer Patch Rubber Company 100 Patch Rubber Road Weldon, NC United States Telephone (General) (252) Responsible party Christian Gimenez 1.4 Emergency telephone number Manufacturer CHEMTREC Manufacturer CHEMTREC - Outside USA & CANADA (collect calls accepted) Section 2: Hazards Identification EU/EEC According to Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP Not classified DSD/DPD Not classified 2.2 Label Elements CLP Hazard statements No label element(s) required DSD/DPD Page 1 of 24

2 United States (US) According to OSHA 29 CFR HCS Canada According to WHMIS Risk phrases No label element(s) required 2.3 Other Hazards CLP This material is exempt from CLP/REACH obligations as an article as specified in REACH (1907/2006) and related ECHA guidance. DSD/DPD Under European Directive 1999/45/EC these product(s) are exempt and considered manufactured article(s) under stated normal conditions of use. 2.1 Classification of the substance or mixture OSHA HCS 2012 Not classified 2.2 Label elements OSHA HCS 2012 Hazard statements No label elements(s) required 2.3 Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR Hazard Communication Standard) this product is exempt as an article under stated normal conditions of use. 2.1 Classification of the substance or mixture WHMIS Not classified 2.2 Label elements WHMIS No label element(s) required 2.3 Other hazards WHMIS Under Canadian regulations (Workplace Hazardous Materials Information System (WHMIS) - Hazardous Products Act (HPA), Section 11(1)), these product(s) are exempt and considered manufactured article(s) under stated normal conditions of use. See Section 12 for Ecological Information. Section 3 - Composition/Information on Ingredients 3.1 Substances 3.2 Mixtures Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. Hazardous ingredients are encapsulated in rubber matrix and are not airborne or of respirable size therefore will not be released or otherwise result in exposure to hazardous chemicals under normal conditions of use. See Section 11 for Toxicological Information. Page 2 of 24

3 Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If signs/symptoms develop, move person to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical attention. Skin First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. Wash skin with soap and water. If signs/symptoms develop, get medical attention. Eye First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If contact with material occurs flush eyes with water. If signs/symptoms develop, get medical attention. Ingestion First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If signs/symptoms develop, get medical attention. 4.2 Most important symptoms and effects, both acute and delayed Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media Water, foam, dry chemical, carbon dioxide (CO2). Unsuitable Extinguishing Media No data available. 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products 5.3 Advice for firefighters Material is non-combustible and is not expected to pose a fire or explosion hazard. No data available Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Structural firefighters' protective clothing will only provide limited protection. Section 6 - Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions No special precautions expected to be necessary if material is used under ordinary conditions and as recommended. Emergency Procedures No emergency procedures are expected to be necessary if material is used under ordinary conditions as as recommended. Use normal clean up procedures. 6.2 Environmental precautions No special precautions necessary. 6.3 Methods and material for containment and cleaning up Containment/Clean-up Measures Pick up pieces and place in container or bag for disposal. Page 3 of 24

4 6.4 Reference to other sections Section 7 - Handling and Storage Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. 7.1 Precautions for safe handling Handling Use good safety and industrial hygiene practices. 7.2 Conditions for safe storage, including any incompatibilities Storage Store in a cool, dry, well-ventilated place. 7.3 Specific end use(s) Refer to Section Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result ACGIH Canada Ontario Canada Quebec France Germany DFG TWAs 10 ppm TWA 10 ppm TWA 10 ppm TWAEV; 30 mg/m3 TWAEV 10 ppm TWA [VME] (indicative limit); 31 mg/m3 TWA [VME] (indicative limit) Propionic acid ( ) STELs 20 ppm STEL [VLCT] (indicative limit); 62 mg/m3 STEL [VLCT] (indicative limit) Ceilings MAKs 20 ppm Peak; 62 mg/m3 Peak 10 ppm TWA MAK; 31 mg/m3 TWA MAK Formaldehyde (Gas State) ( ) Ceilings 0.3 ppm Ceiling 1.5 ppm Ceiling 2 ppm Ceiling; 3 mg/m3 Ceiling 0.6 ppm Peak (no irritation should occur during mixed exposure); 0.74 mg/m3 Peak (no irritation should occur during mixed exposure) STELs 1.0 ppm STEL 1 ppm STEL [VLCT] TWAs 0.5 ppm TWA [VME] MAKs 0.3 ppm TWA MAK; 0.37 mg/m3 TWA MAK (no irritation should occur during mixed exposure) Quartz ( ) TWAs mg/m3 TWA (respirable fraction) 0.10 mg/m3 TWA (designated substances regulation, respirable, listed under Silica, crystalline) 0.1 mg/m3 TWAEV (respirable dust) 0.1 mg/m3 TWA [VME] (restrictive limit, alveolar fraction) Page 4 of 24

5 Rosin ( ) TWAs exposure by all routes should be carefully controlled to levels as low as possible 0.1 mg/m3 TWAEV (as Formaldehyde) 0.1 mg/m3 TWA [VME] (as Formaldehyde) Titanium dioxide ( ) TWAs 10 mg/m3 TWA 10 mg/m3 TWA 10 mg/m3 TWAEV (containing no Asbestos and <1% Crystalline silica, total dust) 10 mg/m3 TWA [VME] (as Ti) Carbon Black ( ) TWAs 3 mg/m3 TWA (inhalable fraction) 3 mg/m3 TWA (inhalable) 3.5 mg/m3 TWAEV 3.5 mg/m3 TWA [VME] STELs 10 mg/m3 STEL (respirable fraction) 10 mg/m3 STEL (respirable) 10 mg/m3 STEV (fume) Zinc oxide ( ) TWAs 2 mg/m3 TWA (respirable fraction) 2 mg/m3 TWA (respirable) 10 mg/m3 TWAEV (containing no Asbestos and <1% Crystalline silica, total dust); 5 mg/m3 TWAEV (fume) 5 mg/m3 TWA [VME] (fume); 10 mg/m3 TWA [VME] (dust) Ceilings MAKs 1 mg/m3 Peak (respirable fraction, fume) 1 mg/m3 TWA MAK (fume, respirable fraction) Limestone ( ) TWAs 10 mg/m3 TWAEV (Limestone, containing no Asbestos and <1% Crystalline silica, total dust) Kaolin ( ) TWAs 2 mg/m3 TWA (particulate matter containing no asbestos and <1% crystalline silica, respirable fraction) 2 mg/m3 TWA (containing no Asbestos and <1% Crystalline silica, respirable) 5 mg/m3 TWAEV (containing no Asbestos and <1% Crystalline silica, respirable dust) 10 mg/m3 TWA [VME] Exposure Limits/Guidelines (Con't.) Result Germany TRGS Italy NIOSH OSHA STELs 20 ppm STEL; 62 mg/m3 STEL 15 ppm STEL; 45 mg/m3 STEL Propionic acid ( ) TWAs 10 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2); 31 mg/m3 TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 2) 10 ppm TWA; 31 mg/m3 TWA 10 ppm TWA; 30 mg/m3 TWA Page 5 of 24

6 Formaldehyde (Gas State) ( ) Quartz ( ) Titanium dioxide ( ) Carbon Black ( ) Zinc oxide ( ) Limestone ( ) Kaolin ( ) STELs 2 ppm STEL (see 29 CFR ) TWAs ppm TWA 0.75 ppm TWA Ceilings TWAs 0.1 ppm Ceiling (15 min) 0.05 mg/m3 TWA (respirable dust) TWAs TWAs TWAs 3.5 mg/m3 TWA; 0.1 mg/m3 TWA (Carbon black in presence of Polycyclic aromatic hydrocarbons, as PAH) 5 mg/m3 TWA (dust and fume) 15 mg/m3 TWA (total dust) 3.5 mg/m3 TWA 5 mg/m3 TWA (fume); 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Ceilings 15 mg/m3 Ceiling (dust) STELs 10 mg/m3 STEL (fume) TWAs TWAs 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Exposure Control Notations Italy Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic ( ): Carcinogens: (Category 2 Carcinogen) Carcinogens: (Category 3 Carcinogen) France Formaldehyde (Gas State) ( ): Carcinogens: (Carcinogen category 3) Germany DFG Kaolin ( ): Carcinogens: (Category 3B (could be carcinogenic for man)) Carcinogens: (Category 3B (could be carcinogenic for man, inhalable fraction)) Carcinogens: (Category 3A (could be carcinogenic for man, inhalable fraction with the exception of ultra small particles)) Carcinogens: (Category 1 (causes cancer in man, alveola fraction)) Carcinogens: (Category 4 (no significant contribution to human cancer)) Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) Pregnancy: (no risk to embryo/fetus if exposure limits adhered to) Sensitizers: (skin sensitizer) Sensitizers: (skin sensitizer) Sensitizers: (skin sensitizer) 8.2 Exposure controls Engineering Under normal conditions of use, special ventilation is not required. Measures/Controls Personal Protective Equipment Respiratory No respiratory protection is required under normal conditions of use. Eye/Face Under normal conditions of use, eye protection is not required. Skin/Body No skin protection is ordinarily required under normal conditions of use. Environmental Exposure Controls Key to abbreviations Follow best practice for site management and disposal of waste. ACGIH = American Conference of Governmental Industrial Hygiene STEV = Short Term Exposure Value NIOSH = National Institute of Occupational Safety and Health Page 6 of 24 TWAEV = Time-Weighted Average Exposure Value

7 Time-Weighted Averages are based on 8h/day, 40h/week OSHA = Occupational Safety and Health Administration TWA = exposures Short Term Exposure Limits are based on 15-minute STEL = exposures Section 9 - Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Material Description Physical Form Solid Appearance/Description Color Data lacking Odor Rubber Odor Threshold Data lacking General Properties Boiling Point Data lacking Melting Point Data lacking Decomposition Temperature Data lacking ph Data lacking Specific Gravity/Relative Density Data lacking Water Solubility Data lacking Viscosity Data lacking Explosive Properties Not relevant. Oxidizing Properties: Not relevant. Volatility Vapor Pressure Data lacking Vapor Density Data lacking Evaporation Rate Data lacking Flammability Flash Point Data lacking UEL Data lacking LEL Data lacking Autoignition Data lacking Flammability (solid, gas) Not relevant. Environmental Octanol/Water Partition coefficient Data lacking A two ply vulcanized tape with a rubber odor. 9.2 Other Information No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials No dangerous reaction known under conditions of normal use. Stable under normal temperatures and pressures. Hazardous polymerization will not occur. No data available No data available Hazardous decomposition products Thermal decomposition could produce CO, CO2, and Oxides of Nitrogen. Page 7 of 24

8 Section 11 - Toxicological Information 11.1 Information on toxicological effects Other Material Information This material is an article that does not release or otherwise result in exposure to a hazardous chemical under normal use. The information provided below is for components only and is not expected to be applicable to the material as a whole. GHS Properties Acute toxicity Aspiration Hazard Carcinogenicity Germ Cell Mutagenicity Skin corrosion/irritation Skin sensitization STOT-RE STOT-SE Toxicity for Reproduction Respiratory sensitization Serious eye damage/irritation Classification EU/CLP Acute Toxicity - Not relevant; Acute Toxicity - Dermal - Not relevant; Acute Toxicity - Inhalation - Not relevant; Acute Toxicity - Oral - Not relevant OSHA HCS 2012 Acute Toxicity - Not relevant; Acute Toxicity - Dermal - Not relevant; Acute Toxicity - Inhalation - Not relevant; Acute Toxicity - Oral - Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant EU/CLP Not relevant OSHA HCS 2012 Not relevant Route(s) of entry/exposure No exposure expected to be possible Potential Health Effects Inhalation Acute (Immediate) Under normal conditions of use, no health effects are expected. Chronic (Delayed) Under normal conditions of use, no health effects are expected. Skin Acute (Immediate) Under normal conditions of use, no health effects are expected. Chronic (Delayed) Under normal conditions of use, no health effects are expected. Eye Acute (Immediate) Under normal conditions of use, no health effects are expected. Chronic (Delayed) Under normal conditions of use, no health effects are expected. Ingestion Acute (Immediate) Under normal conditions of use, no health effects are expected. Page 8 of 24

9 Chronic (Delayed) Under normal conditions of use, no health effects are expected. Carcinogenic Effects This product contains carbon black (encapsulated)( ). Accordng to IARC "No significant exposure to carbon black is thought to occur during the use of products in which carbon black is bound to other materials, such as rubber, printing ink or paint." Carcinogenic Effects CAS OSHA IARC NTP Formaldehyde (Gas State) Specifically Regulated Carcinogen Group 1-Carcinogenic Known Human Carcinogen Quartz Group 1-Carcinogenic Known Human Carcinogen Titanium dioxide Group 2B-Possible Carcinogen Carbon Black Group 2B-Possible Carcinogen Reproductive Effects No reproductive effects expected. Section 12 - Ecological Information 12.1 Toxicity Material data lacking Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in Soil Material data lacking. Material data lacking. Material data lacking Results of PBT and vpvb assessment 12.6 Other adverse effects PBT and vpvb assessment has not been carried out. Material data lacking. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 - Transport Information 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards DOT NDA Not Regulated NDA NDA NDA TDG NDA Not Regulated NDA NDA NDA IMO/IMDG NDA Not Regulated NDA NDA NDA Page 9 of 24

10 IATA/ICAO NDA Not Regulated NDA NDA NDA 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No special precautions. Not relevant. Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications None State Right To Know Component CAS MA NJ PA 1,3-Butadiene, 2- methyl-, oligomer Benzothiazole, 2,2'- dithiobis No No No No No No Carbon Black Yes Yes Yes Fatty acids, tall oil No No No Formaldehyde (Gas State) Yes Yes Yes Kaolin Yes Yes Yes Limestone Yes Yes Yes Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic No No No Propionic acid Yes Yes Yes Quartz Yes Yes Yes Rosin No No No Stearic acid No No No Styrene polymer with 1,3-butadiene (Kraton) No No No Sulfur Yes Yes Yes Titanium dioxide Yes Yes Yes White mineral oil No No No Zinc oxide Yes Yes Yes Zinc, bis (diethyldithiocarbamato) No No No Page 10 of 24

11 Inventory Component CAS Canada DSL Canada NDSL EU EINECS EU ELNICS TSCA 1,3-Butadiene, 2- methyl-, oligomer Benzothiazole, 2,2'- dithiobis Yes No No No Yes Yes No Yes No Yes Carbon Black Yes No Yes Yes Yes Fatty acids, tall oil Yes No Yes No Yes Formaldehyde (Gas State) Yes No Yes No Yes Kaolin Yes No Yes No Yes Limestone No Yes Yes No Yes Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Yes No Yes No Yes Propionic acid Yes No Yes No Yes Quartz Yes No Yes No Yes Rosin Yes No Yes No Yes Stearic acid Yes No Yes No Yes Styrene polymer with 1,3-butadiene (Kraton) Yes No No No Yes Sulfur Yes No Yes No Yes Titanium dioxide Yes No Yes No Yes White mineral oil Yes No Yes No Yes Zinc oxide Yes No Yes No Yes Zinc, bis (diethyldithiocarbamato) Yes No Yes No Yes Canada Labor Canada - WHMIS - Classifications of Substances Uncontrolled product Stearic acid according to WHMIS classification criteria Benzothiazole, 2,2'-dithiobis Uncontrolled product Styrene polymer with 1,3-butadiene (Kraton) according to WHMIS classification criteria Kaolin D2A Propionic acid B3, D1B, E Rosin D2A D2A (In certain cases, this classification does not apply. For more information, consult Carbon Black the section Substance Specific Issues - Carbon Black, non- Page 11 of 24

12 respirable on Health Canada's WHMIS Division website.) D2A (In certain cases, this classification does not apply. For more information, consult the section Substance Specific Titanium dioxide Issues - Titanium dioxide, mixture containing on Health Canada's WHMIS Division website.) Uncontrolled product Zinc oxide according to WHMIS classification criteria Limestone D2A Uncontrolled product White mineral oil according to WHMIS classification criteria Sulfur B4 Uncontrolled product Fatty acids, tall oil according to WHMIS classification criteria D2A (In certain cases, this classification does not apply. For more information, consult the section Substance Specific Quartz Issues - Silica, crystalline, encapsulated on Health Canada's WHMIS Division website.) Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic A, B1, D1A, D2A, D2B; B3, Formaldehyde (Gas State) D1A, D2A, D2B, E (regulated under Formol) Canada - WHMIS - Ingredient Disclosure List Stearic acid % Benzothiazole, 2,2'-dithiobis % Propionic acid % Rosin Carbon Black % Zinc oxide % Sulfur Quartz % Zinc, bis(diethyldithiocarbamato) % Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) % Page 12 of 24

13 Environment Canada - CEPA - Priority Substances List Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) Priority Substance List (substance considered toxic) Europe Other EU - CLP (1272/2008) - Annex VI - Table Classification Benzothiazole, 2,2'-dithiobis R31 R43 N; R50-53 Propionic acid C; R34 Rosin R43 Carbon Black Zinc oxide N; R50-53 Sulfur Xi; R38 Quartz Zinc, bis(diethyldithiocarbamato)- Xn; R22 Xi; R36/37/38 R43 N; R50-53 Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Carc.Cat.2; R45 Formaldehyde (Gas State) T; R23/24/25 C; R Carc.Cat.3; R40 R43 EU - CLP (1272/2008) - Annex VI - Table Concentration Limits Benzothiazole, 2,2'-dithiobis Page 13 of 24

14 Propionic acid 10%<=C<25%: Xi; R:36/37/ %<=C: C; R:34 Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic %<=C: R:43 25%<=C: T; Formaldehyde (Gas State) R:23/24/25 5%<=C<25%: Xn; R:20/21/22 25%<=C: C; R:34 5%<=C<25%: Xi; R:36/37/38 EU - CLP (1272/2008) - Annex VI - Table Labelling Benzothiazole, 2,2'-dithiobis- Xi N R: /53 S:(2) / Propionic acid C R:34 S:(1/2) Rosin Xi R:43 S:(2) Carbon Black Zinc oxide N R:50/53 S:60-61 Sulfur Xi R:38 S:(2)-46 Quartz Zinc, bis(diethyldithiocarbamato)- Xn N R:22-36/37/ / S:(2) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic T R:45 S:53-45 Formaldehyde (Gas State) T R:23/24/ S: (1/2)-26-36/37/ EU - CLP (1272/2008) - Annex VI - Table Notes - Substances and Preparations Benzothiazole, 2,2'-dithiobis Propionic acid B Rosin Carbon Black Page 14 of 24

15 Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic L Formaldehyde (Gas State) B, D EU - CLP (1272/2008) - Annex VI - Table Safety Phrases Benzothiazole, 2,2'-dithiobis S:(2)-36/ Propionic acid S:(1/2) Rosin S:(2) Carbon Black Zinc oxide S:60-61 Sulfur S:(2)-46 Quartz Zinc, bis(diethyldithiocarbamato) S:(2) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic S:53-45 Formaldehyde (Gas State) S:(1/2)-26-36/37/ United States Labor U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Page 15 of 24

16 Formaldehyde (Gas State) lb TQ U.S. - OSHA - Specifically Regulated Chemicals Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic ppm STEL (See 29 CFR , 15 min); 0.5 ppm Formaldehyde (Gas State) Action Level (See 29 CFR ); 0.75 ppm TWA (See 29 CFR ) Environment U.S. - CAA (Clean Air Act) Hazardous Air Pollutants Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities Benzothiazole, 2,2'-dithiobis Page 16 of 24

17 Propionic acid 5000 lb final RQ; 2270 kg final RQ Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) 100 lb final RQ; 45.4 kg final RQ U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Page 17 of 24

18 Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) lb EPCRA RQ U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) lb TPQ U.S. - CERCLA/SARA - Section Emission Reporting Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide % de minimis concentration (Chemical Category N982) Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) 0.1 % de minimis concentration U.S. - CERCLA/SARA - Section PBT Chemical Listing Benzothiazole, 2,2'-dithiobis Page 18 of 24

19 Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - RCRA (Resource Conservation & Recovery Act) - Basis for Listing - Appendix VII Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Included in waste streams: Formaldehyde (Gas State) K009, K010, K038, K040, K156, K157 U.S. - RCRA (Resource Conservation & Recovery Act) - Hazardous Constituents - Appendix VIII to 40 CFR 261 Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Page 19 of 24

20 Sulfur Quartz Zinc, bis(diethyldithiocarbamato)- hazardous constituent - no waste number Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) waste number U122 U.S. - RCRA (Resource Conservation & Recovery Act) - U Series Wastes - Acutely Toxic Wastes & Other Hazardous Characteristics Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) waste number U122 United States - California Environment U.S. - California - Proposition 65 - Carcinogens List Benzothiazole, 2,2'-dithiobis Propionic acid Rosin carcinogen, initial date 2/21/03 Carbon Black (airborne, unbound particles of respirable size) carcinogen, initial date 9/2/11 Titanium dioxide (airborne, unbound particles of respirable size) Zinc oxide Sulfur carcinogen, initial date 10/1/88 Page 20 of 24

21 Quartz (airborne particles of respirable size) Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) carcinogen, initial date 1/1/ (gas) U.S. - California - Proposition 65 - Developmental Toxicity Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL) Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL) Benzothiazole, 2,2'-dithiobis Page 21 of 24

22 Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) µg/day NSRL (gas) U.S. - California - Proposition 65 - Reproductive Toxicity - Female Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - California - Proposition 65 - Reproductive Toxicity - Male Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Page 22 of 24

23 Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) United States - Pennsylvania Labor U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide (fume) Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances Benzothiazole, 2,2'-dithiobis Propionic acid Rosin Carbon Black Zinc oxide Sulfur Quartz Zinc, bis(diethyldithiocarbamato) Mineral oil, petroleum distillates, hydrotreated (severe) heavy naphthenic Formaldehyde (Gas State) Chemical Safety Assessment 15.3 Other Information Chemical Safety Assessment is not required. Page 23 of 24

24 WARNING: This product contains a chemical known to the State of California to cause cancer. Section 16 - Other Information Last Revision Date 29/October/2013 Preparation Date 29/October/2013 Disclaimer/Statement of Liability The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current, applicable and suited to the circumstance of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as described in Section 1. Key to abbreviations NDA = No Data Available Page 24 of 24