Section 1: Identification of the Substance/Mixture and of the Company/Undertaking

Transcription

1 Safety Data Sheet Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier SBS Polyester FR Series: SBS FR, SBS FR Torch, SBS Premium Product Name FR, SBS Premium FR Torch Product Description Black mat with sand and/or ceramic and/or thin plastic film covered surface and an asphalt odor. 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) Construction 1.3 Details of the supplier of the safety data sheet Manufacturer Firestone Building Products Company 250 West 96th Street Indianapolis, IN United States Telephone (General) Emergency telephone number Manufacturer (800) CHEMTREC Manufacturer (703) CHEMTREC - International Section 2: Hazards Identification EU/EEC According to EU Directive 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP Specific Target Organ Toxicity Repeated Exposure 1 - H372 DSD/DPD Harmful (Xn) 2.2 Label Elements CLP R20 DANGER Hazard statements H372 - Causes damage to organs through prolonged or repeated exposure. Precautionary statements 흾힏힕힓흎흟흎힝힔흎흟흣

2 Prevention P260 - Do not breathe dust, fume, gas, mist, vapours and/or spray. P264 - Wash thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. Response P314 - Get medical advice/attention if you feel unwell. DSD/DPD Storage/Disposal P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Risk phrases R20 - Harmful by inhalation. 2.3 Other Hazards CLP According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD According to European Directive 1999/45/EC this preparation is considered dangerous. United States (US) According to OSHA 29 CFR HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 Specific Target Organ Toxicity Repeated Exposure 1 - H Label elements OSHA HCS 2012 DANGER Hazard statements Causes damage to organs through prolonged or repeated exposure. - H372 Precautionary statements Prevention Do not breathe dust, fume, gas, mist, vapours and/or spray. - P260 Wash thoroughly after handling. - P264 Do not eat, drink or smoke when using this product. - P270 Response Get medical advice/attention if you feel unwell. - P314 Storage/Disposal Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P Other hazards OSHA HCS 2012 Under United States Regulations (29 CFR Hazard Communication Standard), this product is considered hazardous. Canada According to WHMIS 2.1 Classification of the substance or mixture WHMIS Other Toxic Effects - D2B 2.2 Label elements 흾힏힕힓흎흠흎힝힔흎흟흣

3 WHMIS Other Toxic Effects - D2B 2.3 Other hazards WHMIS In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). 2.4 Other information The calcium carbonate is bound in an asphalt matrix, neither of which is expected to be released. The sand and granules are applied to the asphalt surface in such a manner that nominal release from the surface is anticipated. See Section 12 for Ecological Information. Section 3 - Composition/Information on Ingredients 3.1 Substances 3.2 Mixtures Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. Chemical Name Asphalt Colemanite Limestone Quartz Identifiers % LD50/LC50 CAS: EINECS: CAS: CAS: EC Number: CAS: EC Number: % TO 60% 20% TO 30% 5% TO 10% Composition Inhalation-Rat LC50 >94.4 mg/m³ NDA NDA < 10% NDA Classifications According to Regulation/Directive EU DSD/DPD: Self Classified: Carc. 3 R40 EU CLP: Self Classified: Carc. 2, H351 OSHA HCS 2012: Carc. 2 EU DSD/DPD: Data Lacking EU CLP: Data Lacking OSHA HCS 2012: Data Lacking EU DSD/DPD: Self Classified: Xn, R48/20 EU CLP: Self Classified: STOT RE 1 (Lungs), H372 OSHA HCS 2012: STOT RE 1 (Lungs) EU DSD/DPD: Self Classified: Carc. 1; R45 EU CLP: Self Classified: Carc 1A, H350 OSHA HCS 2012: Carc. 1A Comments NDA NDA NDA NDA See Section 11 for Toxicological Information. Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation Remove to fresh air, apply artificial respiration and/or oxygen if necessary and get medical attention. Skin Remove contaminated clothing and wash exposed skin with soap and water. If irritation develops or persists, seek medical attention. Eye If foreign matter enters eyes, immediately flush with large amounts of water for at least 흾힏힕힓흎흡흎힝힔흎흟흣

4 15 minutes or until irritation subsides. If irritation develops, or persists, seek medical attention. Ingestion Consult a physician if unusual reaction is noted. Product is not intended nor is it likely to be ingested or eaten. 4.2 Most important symptoms and effects, both acute and delayed Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. See Section 2 for Potential Health Effects. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media Use water, foam, CO2 or dry chemical extinguishers to contain fire. Unsuitable Extinguishing No data available. Media Firefighting Procedures Fire fighters should avoid inhaling any combustion products. 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products 5.3 Advice for firefighters Burning of this product will produce thick black smoke. Carbon dioxide, carbon monoxide and partially burned carbon. Firefighters should wear full-face, self contained breathing apparatus and impervious protective clothing to avoid smoke inhalation and lack of oxygen. Section 6 - Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions No special precautions expected to be necessary if material is used under ordinary conditions and as recommended. Emergency Procedures No emergency procedures are expected to be necessary if material is used under ordinary conditions as as recommended. 6.2 Environmental precautions Avoid run off to waterways and sewers. 6.3 Methods and material for containment and cleaning up Containment/Clean-up Measures 6.4 Reference to other sections Section 7 - Handling and Storage Pick up large pieces. Vacuum dust. If sweeping is necessary, use a dust suppressant such as water. These procedures will help to minimize potential exposures. Scoop up material and put into a suitable container for disposal as a non-hazardous waste. Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. 7.1 Precautions for safe handling Handling Do not breathe dusts or fumes generated from cutting or heating this material. Use this product with adequate ventilation. Always wash work clothes seperately from 흾힏힕힓흎흢흎힝힔흎흟흣

5 other clothing. Wash thoroughly after handling. Use personal protective equipment as described in Section Conditions for safe storage, including any incompatibilities Storage Store indoors in a cool, dry, well-ventilated area. Do not handle or store near an open flame, heat or other sources of ignition. Special Packaging Materials No data available. Incompatible Materials or Ignition Sources 7.3 Specific end use(s) This product will react with strong oxidizing agents, reducing agents, strong acids and alkalis. Refer to Section Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Limestone ( ) Quartz ( ) Asphalt ( ) Limestone ( ) Quartz ( ) Asphalt ( ) Result ACGIH Exposure Limits/Guidelines Canada British Canada Manitoba Columbia Canada New Brunswick Canada Northwest Territories STELs 20 mg/m3 STEL mg/m3 TWA (respirable fraction) 0.5 mg/m3 TWA (fume, inhalable fraction, as benzene soluble aerosol) 10 mg/m3 TWA (total dust); 3 mg/m3 TWA (respirable fraction) mg/m3 TWA (respirable) 0.5 mg/m3 TWA (inhalable fume, as Benzene-soluble aerosol) mg/m3 TWA (respirable fraction) 0.5 mg/m3 TWA (fume, inhalable fraction, as Benzene soluble aerosol) 10 mg/m3 TWA (particulate matter containing no Asbestos and <1% Crystalline silica) 0.1 mg/m3 TWA (respirable fraction) 5 mg/m3 TWA (petroleum fumes) STELs 5 mg/m3 TWA (respirable mass); 10 mg/m3 TWA (total mass) 0.1 mg/m3 TWA (respirable mass); 0.3 mg/m3 TWA (total mass) 5 mg/m3 TWA (Petroleum fumes) 10 mg/m3 STEL (Petroleum fumes) Exposure Limits/Guidelines (Con't.) Result Canada Nova Scotia Canada Nunavut Canada Ontario Canada Quebec Canada Yukon 5 mg/m3 TWA (respirable mass); 10 mg/m3 TWA (total mass) 10 mg/m3 TWAEV (Limestone, containing no Asbestos and <1% Crystalline silica, total dust) 30 mppcf TWA; 10 mg/m3 TWA STELs 20 mg/m3 STEL mg/m3 TWA (respirable fraction) 0.5 mg/m3 TWA (fume, inhalable fraction, as Benzene soluble aerosol) 0.1 mg/m3 TWA (respirable mass); 0.3 mg/m3 TWA (total mass) 5 mg/m3 TWA (Petroleum fumes) 0.10 mg/m3 TWA (designated substance regulation, respirable) 0.5 mg/m3 TWA (fume, inhalable, as Benzene-soluble aerosol) 0.1 mg/m3 TWAEV (respirable dust) 5 mg/m3 TWAEV (fume) 300 particle/ml TWA (listed under Silica) 5 mg/m3 TWA (fume) 흾힏힕힓흎흣흎힝힔흎흟흣

6 STELs 10 mg/m3 STEL (Petroleum fumes) 10 mg/m3 STEL (fume) Exposure Limits/Guidelines (Con't.) Result China NIOSH OSHA Limestone ( ) STELs 16 mg/m3 STEL (total dust); 8 mg/m3 STEL (respirable dust) 8 mg/m3 TWA (total dust); 4 mg/m3 TWA (respirable dust) 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) STELs 2 mg/m3 STEL (10%- 50% free SiO2, total dust); 1.4 mg/m3 STEL (50%-80% free SiO2, total dust); 1 mg/m3 STEL (containing >80% free SiO2, total dust); 1.4 mg/m3 STEL (10%- 50% free SiO2, respirable dust); 0.6 mg/m3 STEL (50%- 80% free SiO2, respirable dust); 0.4 mg/m3 STEL (containing >80% free SiO2, respirable dust) Quartz ( ) 0.7 mg/m3 TWA (containing 50-80% free SiO2, total dust); 0.3 mg/m3 TWA (containing 50-80% free SiO2, respirable dust); 1 mg/m3 TWA (containing 10-50% free SiO2, total dust); 0.7 mg/m3 TWA (containing 10-50% free SiO2, respirable dust); 0.5 mg/m3 TWA (containing >80% free SiO2, total dust); 0.2 mg/m3 TWA (containing >80% free SiO2, respirable dust) 0.05 mg/m3 TWA (respirable dust) STELs 12.5 mg/m3 STEL (fume, as Benzene soluble matter) Asphalt ( ) 5 mg/m3 TWA (fume, as Benzene soluble matter) Ceilings 5 mg/m3 Ceiling (fume, 15 min) Exposure Limits Supplemental OSHA Quartz ( ): Mineral Dusts: ((30)/(%SiO2 + 2) mg/m3 TWA, total dust; (250)/(%SiO2 + 5) mppcf TWA, respirable fraction; (10)/(%SiO2 흾힏힕힓흎흤흎힝힔흎흟흣

7 + 2) mg/m3 TWA, respirable fraction) 8.2 Exposure controls Engineering Adequate ventilation systems as needed to control concentrations of airborne Measures/Controls contaminants below applicable threshold limit values. Personal Protective Equipment Respiratory Respiratory protection is not normally required. Use a NIOSH approved/certified respiratory when the exposure limits are exceeded. Use a particulate filter respirator for particulate concentrations exceeding the Occupational Exposure Limit. Eye/Face Safety glasses with side shields should be worn at a minimum. Hands Leather or cotton gloves may be worn to prevent skin contact and irritation. Skin/Body Normal work clothing (long sleeved shirts and long pants) is recommended. General Industrial Hygiene Considerations Environmental Exposure Controls Key to abbreviations Use good industrial hygiene practices in handling this material. Availability of eye wash fountains are recommended. Follow best practice for site management and disposal of waste. Short Term Exposure Limits are based on 15- ACGIH = American Conference of Governmental Industrial Hygiene STEL = minute exposures. Time-Weighted Averages are based on 8h/day, NIOSH = National Institute of Occupational Safety and Health TWA = 40h/week exposures OSHA = Occupational Safety and Health Administration PEL Permissible Exposure Level determined by the Occupational Safety and = Health Administration (OSHA) TWAEV = Time-Weighted Average Exposure Value Section 9 - Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Material Description Physical Form Solid Appearance/Description Color Black Odor Asphalt odor. Odor Threshold Data lacking General Properties Boiling Point Data lacking Melting Point Data lacking Decomposition Temperature Data lacking ph Data lacking Specific Gravity/Relative Density Data lacking Water Solubility Insoluble Viscosity Data lacking Explosive Properties Data lacking Oxidizing Properties: Data lacking Volatility Vapor Pressure Data lacking Vapor Density Data lacking Evaporation Rate Data lacking Flammability Flash Point Data lacking UEL Data lacking LEL Data lacking Autoignition Data lacking Flammability (solid, gas) Data lacking Environmental Octanol/Water Partition coefficient Data lacking 9.2 Other Information Black mat with sand and/ or ceramic covered surface and an asphalt odor. 흾힏힕힓흎흥흎힝힔흎흟흣

8 No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials No dangerous reaction known under conditions of normal use. Stable under normal conditions of use. Hazardous polymerization will not occur. Strong oxidizing agents. This product will react with strong oxidizing agents, reducing agents, strong acids and alkalis Hazardous decomposition products Burning will produce smoke, carbon monoxide, and carbon dioxide. Section 11 - Toxicological Information 11.1 Information on toxicological effects Component Name CAS Data Asphalt (50% TO 60%) Acute Toxicity: orl-rat LD50:>5000 mg/kg; ihl-rat LC50:>94.4 mg/m3; Mutagen: dna-mus-skn 600 mg/kg Quartz (< 10%) GHS Properties Acute toxicity Aspiration Hazard Carcinogenicity Germ Cell Mutagenicity Skin corrosion/irritation Skin sensitization STOT-RE STOT-SE Toxicity for Reproduction Tumorigen/Carcinogen: ihl-rat TCLo:50 mg/m3/6h/71w-i Classification EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Specific Target Organ Toxicity Repeated Exposure 1 OSHA HCS 2012 Specific Target Organ Toxicity Repeated Exposure 1 EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met 흾힏힕힓흎흦흎힝힔흎흟흣

9 Respiratory sensitization Serious eye damage/irritation EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met EU/CLP Classification criteria not met OSHA HCS 2012 Classification criteria not met Medical Conditions Pre-existing lung conditions which may be aggravated if fumes/dusts are inhaled. Aggravated by Exposure Potential Health Effects Inhalation Acute (Immediate) Temporary irritation of nose and throat may occur. Chronic (Delayed) This product contains crystalline silica which is listed by IARC as a suspect carcinogen. Silicosis (pulmonary fibrosis or severe lung scarring) may occur if exposed to high levels or repeated encounters with dust. Exposure to airborne particles that exceed the limits listed may cause lung cancer. This product also contains petroleum asphalt. If heated, there is limited evidence that derivatives of asphalt fumes may cause carcinogenic effects in animals. There is inadequate evidence to support that asphalt fumes alone are carcinogenic to humans. Skin Acute (Immediate) Mechanical irritation of the skin/skin abrasion may occur characterized by itching or redness. Chronic (Delayed) No data available Eye Acute (Immediate) Mechanical irritation of the eye may occur characterized by itching or redness. Chronic (Delayed) No data available. Ingestion Acute (Immediate) Ingestion of this product unlikely. Chronic (Delayed) No data available. Carcinogenic Effects When used under normal conditions, this product is not considered a carcinogen. Based upon the newly published IARC classifications for bitumen/asphalt fumes, it has been determined that the IARC carcinogen designation does not apply to this material as it does not contain material identified by IARC. This product contains crystalline silica. IARC Monographs on Evaluation of Carcinogenic Risk of Chemicals to Humans (Monograph 68, 1997) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to humans, IARC (Group I). Crystalline Silica is classified as a Known Carcinogen according to the NTP. Carcinogenic Effects CAS IARC NTP Quartz Group 1-Carcinogenic Known Human Carcinogen Asphalt Group 2B-Possible Carcinogen Not Listed Key to abbreviations LC = Lethal Concentration LD = Lethal Dose TC= Toxic Concentration Section 12 - Ecological Information 12.1 Toxicity 12.2 Persistence and degradability No information available for the product. 흾힏힕힓흎흧흎힝힔흎흟흣

10 12.3 Bioaccumulative potential 12.4 Mobility in Soil No information available for the product. No information available for the product. No information available for the product Results of PBT and vpvb assessment No PBT and vpvb assessment has been conducted Other adverse effects Ecological Fate No information available for the product Other Information This product has not been tested. Based on information related to all raw materials in the finished product it is not expected to harm ecosystems through its applied use. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 - Transport Information 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards DOT NDA Not Regulated NDA NDA NDA TDG NDA Not Regulated NDA NDA NDA IMO/IMDG NDA Not Regulated NDA NDA NDA ADN NDA Not Regulated NDA NDA NDA ADR/RID NDA Not Regulated NDA NDA NDA IATA/ICAO NDA Not Regulated NDA NDA NDA 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code None known. Not relevant. Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications Chronic 흾힏힕힓흎흟흞흎힝힔흎흟흣

11 State Right To Know Component CAS MA MN NJ PA Limestone Yes Yes Yes Yes Asphalt Yes Yes Yes Yes Quartz Yes Yes Yes Yes Colemanite No No No No Inventory Component CAS Canada DSL Canada NDSL China EU EINECS EU ELNICS Limestone No Yes Yes Yes No Asphalt Yes No Yes Yes No Quartz Yes No Yes Yes No Colemanite No No No No No Inventory (Con't.) Component CAS TSCA Limestone Yes Asphalt Yes Quartz Yes Colemanite No Australia Labor Australia - Work Health and Safety Regulations - Hazardous Substances Requiring Health Monitoring Demographic, medical and occupational history; Records of personal exposure; Standardised respiratory Quartz questionnaire to be completed; Standardised respiratory function test, for example, FEV1, FVC and FEV1/FVC; Chest X-ray full size PA view Australia - High Volume Industrial Chemicals List Asphalt Limestone Quartz Colemanite Not Listed Not Listed Australia - List of Designated Hazardous Substances - Classification Asphalt Self classification required (petroleum fumes) Quartz Self classification required Environment Australia - National Pollutant Inventory (NPI) Substance List 흾힏힕힓흎흟흟흎힝힔흎흟흣

12 Australia - Ozone Protection Act - Scheduled Substances Australia - Priority Existing Chemical Program Canada Labor Canada - WHMIS - Classifications of Substances Limestone D2A D2A (In certain cases, this classification does not apply. For more information, consult the section Substance Quartz Specific Issues - Silica, crystalline, encapsulated on Health Canada's WHMIS Division website.) Canada - WHMIS - Ingredient Disclosure List Quartz % Europe Other EU - CLP (1272/2008) - Annex VI - Table Classification EU - CLP (1272/2008) - Annex VI - Table Concentration Limits EU - CLP (1272/2008) - Annex VI - Table Labelling EU - CLP (1272/2008) - Annex VI - Table Notes - Substances and Preparations 흾힏힕힓흎흟흠흎힝힔흎흟흣

13 EU - CLP (1272/2008) - Annex VI - Table Safety Phrases Mexico Other Mexico - Hazard Classifications Mexico - Regulated Substances United States Environment U.S. - CAA (Clean Air Act) Hazardous Air Pollutants U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs U.S. - CERCLA/SARA - Section Emission Reporting U.S. - CERCLA/SARA - Section PBT Chemical Listing 흾힏힕힓흎흟흡흎힝힔흎흟흣

14 U.S. - CWA (Clean Water Act) - Hazardous Substances U.S. - CWA (Clean Water Act) - Priority Pollutants U.S. - RCRA (Resource Conservation & Recovery Act) - List for Hazardous Constituents United States - California Environment U.S. - California - Proposition 65 - Carcinogens List Quartz carcinogen, initial date 10/1/88 (airborne particles of respirable size) United States - New Jersey Environment U.S. - New Jersey - Special Health Hazards Substances List Asphalt flammable - third degree Quartz carcinogen United States - Pennsylvania Labor U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List United States - Rhode Island Labor U.S. - Rhode Island - Hazardous Substance List Asphalt Toxic; Flammable Limestone Toxic 흾힏힕힓흎흟흢흎힝힔흎흟흣

15 Quartz Toxic (dust and fiber) 15.2 Chemical Safety Assessment No Chemical Safety Assessment has been carried out. Section 16 - Other Information Last Revision Date 03/October/2013 Preparation Date 03/January/2012 Disclaimer/Statement of Liability The information contained herein is based on data considered accurate which has been obtained from other companies and organizations. However, no warranty or representation is expressed or implied that the information, is accurate, complete or representative. Firestone Building Products Company, LLC assumes no responsibility for injury to the buyer, the buyer's employees, or any third persons, if reasonable safety procedures are not followed. Additionally, Firestone Building Products Company assumes no responsibility for injury to buyer, the buyer's employees, or any third persons caused by abnormal use of this material, even if reasonable safety procedures are followed. Key to abbreviations NDA = No Data Available 흾힏힕힓흎흟흣흎힝힔흎흟흣