Safety Data Sheet 1. PRODUCT IDENTIFICATION (Outside the United States-Call Collect) address:

Transcription

1 Safety Data Sheet Safety Data Sheet (in compliance with Regulation (EC) 1907/2006, Regulation (EC) 1272/2008 and Regulation (EC) 453/2010) Date Issued: 6 June 2009 Document Number: 90000MS Date Revised: 03 April 2012 Revision Number: 4 1. PRODUCT IDENTIFICATION Trade Name (as labeled): Chemical Name/Classification: SOLO Disinfectant Wipes Mixture Product Identifier (Part/Item Number): U.N. Number: U.N. Dangerous Goods Classification: Recommended Use: Restrictions on Use: Manufacturer/Supplier Name: Manufacturer/Supplier Address: Disinfectant Cleaner For professional use only Ebiox Ltd. 822 Fountain Court, Birchwood Boulevard Birchwood, Warrington, UK WA3 7QZ Manufacturer/Supplier Telephone Number: Emergency Contact Telephone Number: (Product Information) (INFOTRAC) (Outside the United States-Call Collect) address: info@ebiox.co.uk 2. HAZARD(s) IDENTIFICATION EU Classification (1999/45/EC as amended): Not Classified as Dangerous EU Labelling: Required US Hazard Classification: Not Hazardous SOLO Disinfectant Wipes Page 1 of 8

2 3. COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Components C.A.S. # EC# Alkyl dimethyl benzyl ammonium Didecyldimethyl ammonium Poly (hexamethylenebiguanide hydro) / / / Not assigned IUPAC Name C12-C18 alkyl benzyl dimethyl ammonium Didecyldimethyl ammonium Tetrasodium ethylenediaminet etracetate Refer to Section 16 for the full text of the EU Classifications and R Phrases. Substance Classification 67/548/EEC (EC) No 1272/2008 C, N R34, R50 <=1.0 C Xn; R22, R34 <=1.0 Acute Tox. 4 ; H302 Skin Corr. 1B; H314 Xi, R41 <=1.0 WT % 4. FIRST-AID MEASURES Routes of Exposure Eye Skin Inhalation Ingestion Most important symptoms of exposure First Aid Instructions Immediately flush eyes with large quantities of water for at least 15 minutes, holding the eyelids apart. Get medical attention if irritation persists. Rinse hands with water after use. Discontinue use and get medical attention if irritation or other symptoms develop. normally needed. If symptoms develop, remove to fresh air. Get medial attention if symptoms persist. Do not induce vomiting. Rinse mouth with water and give one glass of water to drink. Never give anything by mouth to an unconscious or convulsing person. Get medical attention if symptoms persist. May cause eye irritation on direct contact. Other known. Note to Physicians (Treatment, Testing, and Monitoring): Treatment of overexposure should be directed at the control of symptoms and clinical conditions. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Fire Fighting Procedures: Specific Hazards Arising from the Chemical: Precautions for Fire Fighters: Use media appropriate for surrounding fire. Cool fire exposed containers and structures with water. known. Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing. SOLO Disinfectant Wipes Page 2 of 8

3 Recommended Protective Equipment for Fire Fighters: EYES/FACE SKIN RESPRIATORY THERMAL 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, PPE and Emergency Procedures: For large spills, wear eye protection. Small spills do not require special precautions. Environmental Precautions: Prevent spill from entering sewers and water courses. Report releases as required by local and national authorities. Methods and Materials for Containment and Clean-up: Pick up wipes. Collect liquid using an inert non-combustible absorbent material and place in appropriate containers for disposal. Recommended Personal Protective Equipment for Containment and Clean-up: EYES/FACE SKIN RESPRIATORY THERMAL 7. HANDLING AND STORAGE Precautions for Safe Handing: Avoid contact with the eyes. Use in accordance with package instructions. Conditions for Safe Storage: Store in original container in a dry, well ventilated area. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: Alkyl dimethyl benzyl ammonium United States Germany United Kingdom France Spain SOLO Disinfectant Wipes Page 3 of 8

4 Didecyldimethyl ammonium Poly (hexamethylenebiguanide hydro) Italy European Union United States Germany United Kingdom France Spain Italy European Union United States Germany United Kingdom France Spain Italy European Union Biological Exposure Limits: Appropriate Engineering Controls: No special controls normally required. Individual Protection Measures (PPE) Specific Eye/face Protection: Avoid eye contact. Follow facility requirements. Specific Skin Protection: Wear impervious gloves such as rubber for prolonged contact. Recommended glove: Rubber gloves. Consult glove supplier for thickness and breakthrough times. Specific Respiratory Protection: required under normal use conditions. Specific Thermal Hazards: Not applicable Recommended Personal Protective Equipment EYES/FACE SKIN RESPRIATORY THERMAL Environmental Exposure Controls: required for normal use. General Hygiene Considerations and Work Practices: Avoid contact with the eyes and skin. Rinse hands after use. Protective Measures During Repair and Maintenance of Contaminated Equipment: Not applicable for product use. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear liquid impregnated on a white wipe Explosive limits: Not applicable SOLO Disinfectant Wipes Page 4 of 8

5 Odor: Medicinal Vapor pressure: Not determined Odor threshold: Not available Vapor density: Not available ph: 5-6 Relative density: C Melting/freezing point: Not available Solubility: Wipe insoluble liquid soluble Initial boiling point and range: Not determined Partition coefficient: n- octanol/water: Not available Flash point: Auto-ignition temperature: Evaporation rate: Not determined Decomposition temperature: Not available Flammability: Not flammable Viscosity: Not available Explosive Properties: Oxidizing Properties: 10. STABILITY AND REACTIVITY Reactivity: Will not polymerize or react dangerously. Chemical Stability: Stable under normal use conditions. Possibility of Hazardous Reactions: known. Conditions to Avoid: known. Incompatible materials: Avoid strong oxidizing agents. Hazardous Decomposition Products: Thermal decomposition may produce carbon and nitrogen oxides and chlorine compounds. 11. TOXICOLOGICAL INFORMATION Potential Health Effects: Eyes: May cause eye irritation on direct contact. Skin: May cause minor irritation on prolonged contact. Ingestion: No adverse effects are expected. Inhalation: Not applicable to product form. SOLO Disinfectant Wipes Page 5 of 8

6 Chronic Health Effects: known. Carcinogenicity: of the components are listed as a carcinogen by IARC, NTP, OSHA, ACGIH or the EU Substances Directive. Alkyl dimethyl benzyl ammonium : No evidence of carcinogenicity in rats or mice at doses of 1,000 ppm and 500 ppm respectively. Didecyldimethyl ammonium : No evidence of carcinogenic effect in mice or rats. Mutagenicity: Alkyl dimethyl benzyl ammonium : Not mutagenic in AMES test, forward mutation assay, and unscheduled DNA synthesis assays. Didecyldimethyl ammonium : Not mutagenic an AMES test, unscheduled DNA synthesis or in-vitro cytogenic assay (CHO). Medical Conditions Aggravated by Exposure: Employees with pre-existing eye and skin disorders may be at increased risk from exposure. Acute Toxicity Data: Alkyl dimethyl benzyl ammonium : Oral rat LD mg/mg; Skin rabbit LD50> 2,000 mg/kg Didecyldimethyl ammonium : Oral Rat LD mg/kg; Skin rabbit LD ,350 mg/kg Reproductive Toxicity Data: Alkyl dimethyl benzyl ammonium : No effects were observed in reproductive and developmental toxicity studies including a two-generation study in rats. Didecyldimethyl ammonium : No developmental toxicity was observed in studies with rats. Specific Target Organ Toxicity (STOT): Single Exposure: No data available Repeated Exposure: Alkyl dimethyl benzyl ammonium : No systemic toxicity was observed in studies with mice, rats and dogs. 12. ECOLOGICAL INFORMATION Toxicity: Alkyl dimethyl benzyl ammonium : LC/EC50 values mg/l Didecyldimethyl ammonium : LC50 fish mg/l/96 hr; EC50 algae 0.11 mg/l/96 hr. EC50 daphnia 0.16 mg/l/48 hr Persistence and Degradability: No data available for product. Bio-accumulative Potential: No data available for product. Mobility in Soil: No data available for product. Other Adverse Effects: No data available for product. Results of PBT/vPvB Assessment: Not required 13. DISPOSAL CONSIDERATIONS Regulations: Dispose in accordance with local and national environmental regulations. Properties (Physical/Chemical) Affecting Disposal: known. Waste Treatment Recommendations: known. SOLO Disinfectant Wipes Page 6 of 8

7 14. TRANSPORT INFORMATION UN-Number ADR/RID: IMDG: IATA: DOT: ADR/RID: Not Regulated UN proper shipping name IMDG: Not Regulated IATA: Not Regulated DOT: Not Regulated Transport hazard class(es) ADR/RID: IMDG: IATA: DOT: Packaging group ADR/RID: IMDG: IATA: DOT: Environmental hazards ADR/RID: No Special precautions for user: Not applicable U.S. Federal Regulations IMDG Marine pollutant: No 15. REGULATORY INFORMATION IATA: No DOT: No Comprehensive Environmental Response and Liability Act of 1980 (CERCLA): This product is not subject to CERCLA release reporting. Many states have more stringent regulations. Report all spills in accordance with local, state, and federal regulations. Toxic Substances Control Act (TSCA): All of the ingredients in this product are listed on the EPA TSCA Inventory or exempt. OSHA Hazard Classification: Not Hazardous Clean Water Act (CWA): Not Listed Clean Air Act (CAA): Not Listed Superfund Amendments and Reauthorization Act (SARA) Title III Information: SARA Section 311/312 (40 CFR 370) Hazard Categories: Immediate Hazard: No Pressure Hazard: No Delayed Hazard: No Reactivity Hazard: No Fire Hazard: No This product contains the following toxic chemical(s) subject to reporting requirements of SARA Section 313 (40 CFR 372): Components C.A.S. # WT % SOLO Disinfectant Wipes Page 7 of 8

8 State Regulations California: This product contains the following chemicals(s) known to the State of California to cause cancer, birth defects or reproductive harm: known Components C.A.S. # WT % International Regulations Canadian Workplace Hazardous Materials Information System (WHMIS): Not a controlled product. EU REACH: The substances in this product comply with the EU REACH regulation as applicable. 16. OTHER INFORMATION Full text of Classification abbreviations used in Section 2 and 3: C Corrosive N Dangerous for the environment. Xi Irritant Xn Harmful R22 Harmful if swallowed. R34 Causes burns. R41 Risk of serious damage to eyes. R50 Very toxic to aquatic organisms. Acute Tox. 4 Acute Toxicity Category 4 Skin Corr 1B Skin Corrosion Category 1B H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. Date of SDS Preparation/Revision: 03 April 2012 Data Sources: US NLM ChemID Plus and HSDB, Substance SDS for components, IUCLID Dataset EU Chemical Bureau, ESIS, and Country websites for occupational exposure limits. SOLO Disinfectant Wipes Page 8 of 8