Curing Agent / Chemical Property

Transcription

1 Curing Agent / Chemical Property 1. General 8. Modified Aromatic Amine 2. Long Pot Life 9. Modified Aliphatic Amine 3. Quick Cure 10. Ketimine 4. Elastic 11. Imidazole 5. Mercaptane 12. Acid Anhydride 6. Modified Cycloaliphatic 13. Dicyandiamide 7. Tertiary Amine 14. Phenol Type 2012/04/13

2 1. General Cure Condition 4) ST ST12 ST13 ST14 Amine Value (mgkoh/g) ) < 5 < 5 < 5 < 400 5) phr 1) Pot Life 2) HDT 3) ( g ) (min.) ( ) Elastic version of ST12 All applications for ambient & heat cure Toughness All applications for ambient & heat cure Toughness All applications for ambient & heat cure Good heat stability, weather resistance Higher viscosity 2. Long Pot Life Cure Condition 4) DC YN100 Amine Value (mgkoh/g) phr 1) Pot Life 2) HDT 3) ( g ) (min.) ( ) < 300 5) < / 23 Low reaction heat, Good heat stability 80 or 50 /40 Reaction retarder 300/ 23 Low reaction heat, Good heat stability 75 or 50 /40 Reaction retarder/ Flooring < /23 71 Low reaction heat, Good water resistance Reaction retarder/ Lining

3 3. Quick Cure Amine Value (mgkoh/g) RC < 8 RC < 13 QC < 10 phr 1) Pot Life 2) HDT 3) Cure ( g ) (min.) ( ) Condition ) ) / 6 hr High machinery strength Adhesiveness, Flooring Low viscosity version of RC11 Adhesiveness, Flooring Does not contain phenol Adhesiveness, Lining, Putty 4. Elastic Cure Condition 4) Amine Value (mgkoh/g) phr 1) Pot Life 2) ( g ) (min.) Extension Modulus 3) (%) Remarks FL < Standard version FL11W < High reactivity version of FL11 FL < ) 32 7) 50 7) Medium Flexibility FL < ) >200 8) Higher Flexibility SA <100 9) < Low Viscosity

4 5. Mercaptane Mercaptane eq. (g/eq) phr 1) Pot Life 2) Cure ( g ) (min.) Condition QX11 QX < 1 < 200 5) ) ),12) 7 11) 23 / 15 min 23 / 1hr Good water resistance, Use with amine Adhesiveness, Lining Low viscosity, Use with tertiary amine Adhesiveness, Lining 6. Modified Cycloaliphatic Amines Purity (%) phr 1) Pot Life 2) HDT 3) Cure ( g ) (min.) ( ) Condition ) < 1 8) /1hr+ 150 /3hr Good stability for heating & light Casting, Laminate 7. Tertiary Amine (Accelerator) Amine Value phr 1) Pot Life 2) HDT 3) (mgkoh/g) ( g ) (min.) ( ) < 8 2,4,6tris(dimethylaminomethyl)phenol

5 8. Modified Aromatic Amine DX103 Amine Value (mgkoh/g) W ) Brown liquid Brown 165 8) liquid phr 1) Pot Life 2) HDT 3) Cure ( g ) (min.) ( ) Condition /4days or 0 /10days 100 /2hr+ 175 /4hr Good curability at Low Temp., for moist side Non solvent type Paints Low Toxicity, Low, High Tg Casting, Laminate

6 9. Modified Aliphatic Amines Base amine : (Polyalkylenepolyamine, Polyethylene polyamine, MXDA) Cure Condition 4) T TO < 100 5) S < 10 8) < 2 8) 40 XD < 4 40 phr 1) Pot Life 2) HDT 3) ( g ) (min.) ( ) < Amine Value (mgkoh/g) 26 U 17 DX < XD ) ) < PF < 8 < < ) < ) Low Viscosity, Quick Cure Adhesive, Casting, Laminate Low Viscosity, Low Toxicity Casting, Filament Windings, Adhesiveness Low Toxicity, Quick Cure Adhesiveness, Laminate Good curability at Low Temp., for moist side Flooring, Lining Long pot life Casting Low viscosity Lining Good stability for acid Lining Low Viscosity, High speed Cure Good Adhesiveness for moist side Quick Cure Flooring, Adhesiveness Good curability for moist side Flooring, Lining Good solubility for Mineral Spirits Painting

7 10. Ketimine H3 H30 Amine Value phr 1) Pot Life 2) Cure (mgkoh/g) ( g ) (hr) Condition ) < / 7 days < / 7 days Amine blush Proof High solid paint Long Pot life of H3 Good stability for one package system 11. Imidazole Amine Value Purity 15) Pot life 16) Water content Melting Point Chemical name mgkoh/g (%) (hr) (%) ( ) EMI < 8 98< 14 < ),18) BMI < 8 92< 30 <0.5 18) 23 8) IBMI < 23 <0.5 < ) P ) < P200H ) <0.5 2Ethyl4(5)Methyl Imidazole 1Benzyl2Methyl Imidazole 1Isobutyl2Methyl Imidazole Modified Imidazole Modified Imidazole / Propylene glycol monomethylether

8 12. Acid Anhydride YH307 Neutralization (g/eq) YH ) ) 13. Dicyandiamide 14. Phenol type YH DICY7 DICY15 DICY Grain size / µm 14) 50% average Maximum < 6 < < 30 5) 110 Appearance White fine powder phr 1) Pot Life 2) HDT 3) Cure ( g ) (hr) ( ) Condition 120 phr 1) ( g ) 3 6 Softening point 22) ( o C) Cure Condition 160 / 1 2 hr 4 30 White fine powder / 1 2 hr White fine powder / 1 2 hr PhenolOH (m eq/g) ) (GardnerH) 171N G K N Q Appearance White Powder White Powder Cure Condition 150 / 15 min 150 / 15 min 80 /3hr+ 80 /3hr+ 120 /6hr 150 /6hr 100 /3hr+ 150 /6hr Remarks Lower Dielectric constant, Lower water absorption Good stability for PCT / Casting, Laminate, Potting, filament winding Anticaking agent : include Powder coating, FRP, Adhesiveness Anticaking agent : include Powder coating, FRP, Adhesiveness Anticaking agent : include Powder coating, FRP, Adhesiveness Good reactivity, flexibility Powder coating Good reactivity, flexibility Powder coating

9 1) phr : per hundred resin / Feeding quantity (g) of Curing Agent for 100g of 828(WPE:190g/eq) 2) Pot Life : Mixing with 100g of 828 and stay it at 23 3) HDT (Heat Distortion Temperature), Extension Modulus are Analyzed by cured products. The test piece is made by standard cure condition as above. 4) Cure condition : Cured with 828 / 23 for 7 days or 23 for 24 hrs and 80 for 3 hrs 5) APHA 6) Analysis condition : at 50 7) The test piece is made of 801N and FL51 8) Representative Value 9) Analysis condition : at 20 10) Amine Value (mgkoh/g) 11) Depends on the type of amine and quantity used, pot life varies greatly. 12) Pot Life : Mixing with 50g of 828 and stay it at 23 13) N (nitrogen) content (%) 14) phr : per hundred resin / Feeding quantity (g) of Curing Agent for 100g of 168V70(WPE:420480g/eq : as solid) 15) Purity : Analyzed by Gas Chromatography 16) Pot Life : Mixing with 200g of 828 and stay it at 23 17) Amine Equivalent (meq/g) 18) Easily crystallized 19) Nonvolatile matter 20) Melting point ( ) 21) Analyzed by solution of Diethyleneglycolbutylacetate ( Resin Content : 40%) 22) Softening point : Ring and ball method

10 Safety and Handling These products and the auxiliary materials normally combined with them are capable of producing adverse health effects ranging from minor skin irritation to serious effects. Exposure to these materials should be minimized and avoided if feasible through the observance of proper precautions, use of appropriate engineering controls and proper personal protective clothing and equipment, and adherence to proper handling procedures. Each of these preventive measures depends upon responsible action by adequately informed persons. None of these materials should be used, stored or transported until the handling precautions and recommendations as stated in the Material Safety Data Sheet (MSDS) for these and all other products being used are understood by all persons who will word with them. Questions and requests for information on Mitsubishi Chemical Corporation (MCC) products should be directed to MCC. Information and MSDSs on nonmcc products should be obtained from the respective manufacturer or vender. Warranty All products purchased from or supplied by MCC are subject to terms and conditions set out in the contract, order acknowledgement and/or bill of lading. MCC warrants only that its product will meet those specifications designated as such herein or in other publications. All other information supplied by MCC is considered accurate but is furnished upon the express condition the customer shall make its own assessment to determine the product s stability for a particular purpose. MCC makes no other warranty, either express or implied, including those regarding such other information, the data upon which the same is based, or the results to be obtained from the use thereof; that any product shall be merchantable or fit for any particular purpose; or that the use of such other information or product will not infringe any patent. Mitsubishi Chemical Corporation Specialty Chemicals Department Performance Products Division 11 Marunouchi 1Chome, Chiyodaku, Tokyo Phone : Facsimile: