Safety Data Sheet. according to Regulation (EC) No 1907/2006. ORACAL Shampoo for Matt Car Wrapping Films

Transcription

1 Page 1 of 8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Washing and cleaning products (including solvent based products) Uses advised against Reserved for industrial and professional use Details of the supplier of the safety data sheet Company name: Street: Orafolstraße 2 Place: D Oranienburg Telephone: Telefax: msds@orafol.de Internet: Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Regulation (EC) No. 1272/2008 Hazard categories: Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements: Causes serious eye irritation Label elements Regulation (EC) No. 1272/2008 Signal word: Pictograms: Warning National Poison Information Service: In case of a medical emergency following exposure to a chemical, the public should call NHS Direct in England or Wales or NHS 24 in Scotland (UK only). Hazard statements H319 Causes serious eye irritation. Precautionary statements P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention Other hazards No information available. SECTION 3: Composition/information on ingredients 3.2. Mixtures

2 Page 2 of 8 Chemical characterization Labelling for contents according to regulation (EC) No. 648/2004: 5-15 % anionic surfactants, < 5 % non-ionic surfactants, < 5 % phosphonates, Preservative (BENZISOTHIAZOLINONE, METHYLISOTHIAZOLINONE), dyestuff, perfumes (free of allergens 2003/15 / EC). Hazardous components CAS No Chemical name EC No Index No REACH No Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity Alcohols, C12-C14 (even numbered), ethoxylated (<2,5 EO), sulfates, sodium salt 5-10 % Skin Irrit. 2, Eye Dam. 1, Aquatic Chronic 3; H315 H318 H ,2-benzisothiazol-3(2H)-one, 1,2-benzisothiazolin-3-one < 0,005 % Acute Tox. 4, Skin Irrit. 2, Eye Dam. 1, Skin Sens. 1, Aquatic Acute 1; H302 H315 H318 H317 H Methyl-(2H)-isothiazol-3-one < 0,005 % Acute Tox. 2, Acute Tox. 3, Skin Corr. 1B, Eye Dam. 1, Skin Sens. 1, Aquatic Acute 1, Aquatic Chronic 2; H330 H301 H314 H318 H317 H400 H411 Full text of H and EUH statements: see section 16. Further Information The surfactants contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. SECTION 4: First aid measures 4.1. Description of first aid measures General information Avoid contact with eyes. After inhalation Provide fresh air. If breathing is irregular or stopped, administer artificial respiration. After contact with skin After contact with skin, wash immediately with plenty of water and soap. Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. After contact with eyes After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. After ingestion Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. When in doubt or if symptoms are observed, get medical advice Most important symptoms and effects, both acute and delayed No information available Indication of any immediate medical attention and special treatment needed Treat symptomatically. Antifoaming agent (defoamer): Dimeticone SECTION 5: Firefighting measures 5.1. Extinguishing media

3 Page 3 of 8 Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. The product itself does not burn Special hazards arising from the substance or mixture No special fire protection measures are necessary Advice for firefighters No special fire protection measures are necessary. Additional information Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures No special measures are necessary Environmental precautions Dilute with plenty of water Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling No special measures are necessary. Advice on protection against fire and explosion No special fire protection measures are necessary Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Advice on storage compatibility No special measures are necessary Specific end use(s) Washing and cleaning products (including solvent based products) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective and hygiene measures Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or

4 Page 4 of 8 drink. Eye/face protection Suitable eye protection: goggles. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: liquid light green clear fruity ph-value (at 20 C): 6,5-7,5 Test method Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: Lower explosion limits: Upper explosion limits: Auto-ignition temperature Solid: Gas: Decomposition temperature: Oxidizing properties Not oxidizing. Vapour pressure: (at 20 C) Vapour pressure: (at 20 C) Density: Water solubility: Solubility in other solvents Partition coefficient: Viscosity / dynamic: (at 20 C) 101 C not applicable not applicable not applicable not applicable 23 hpa 1,04 hpa easily soluble mpa s

5 Page 5 of 8 Vapour density: Evaporation rate: 9.2. Other information Solid content: SECTION 10: Stability and reactivity Reactivity No hazardous reaction when handled and stored according to provisions Chemical stability The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions No known hazardous reactions Conditions to avoid none Incompatible materials No information available Hazardous decomposition products No known hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity CAS No Chemical name Exposure route Dose Species Alcohols, C12-C14 (even numbered), ethoxylated (<2,5 EO), sulfates, sodium salt oral dermal ,2-benzisothiazol-3(2H)-one, 1,2-benzisothiazolin-3-one oral Methyl-(2H)-isothiazol-3-one oral Source LD50 > 2000 mg/kg OECD Guideline 401 LD50 > 2000 mg/kg Rat OECD Guideline 402 ATE ATE 500 mg/kg 100 mg/kg inhalative vapour ATE 0,5 mg/l inhalative aerosol ATE 0,05 mg/l Additional information on tests This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. Practical experience Observations relevant to classification Has degreasing effect on the skin. SECTION 12: Ecological information Toxicity The product is not: Ecotoxic.

6 Page 6 of 8 CAS No Chemical name Aquatic toxicity Dose [h] [d] Species Source Alcohols, C12-C14 (even numbered), ethoxylated (<2,5 EO), sulfates, sodium salt Acute fish toxicity Acute algae toxicity Acute crustacea toxicity LC50 ErC50 EC50 7,1 mg/l 7,5 mg/l 7,2 mg/l 96 h 96 h 48 h Persistence and degradability CAS No The surfactants contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Chemical name Method Evaluation Value Alcohols, C12-C14 (even numbered), ethoxylated (<2,5 EO), sulfates, sodium salt Bioaccumulative potential OECD 301B/ ISO 9439/ EEC 92/69/V, C.4-C 100% 14 Readily biodegradable (according to OECD criteria). The product has not been tested Mobility in soil The product has not been tested Results of PBT and vpvb assessment The product has not been tested Other adverse effects No information available. Further information Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. SECTION 13: Disposal considerations Waste treatment methods d Source Advice on disposal Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to applicable legislation. Waste disposal number of waste from residues/unused products MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately collected fractions (except 15 01); detergents other than those mentioned in Waste disposal number of contaminated packaging WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); plastic packaging Contaminated packaging Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself. SECTION 14: Transport information Land transport (ADR/RID) Other applicable information (land transport) No dangerous good in sense of these transport regulations.

7 Page 7 of 8 Inland waterways transport (ADN) Other applicable information (inland waterways transport) No dangerous good in sense of these transport regulations. Marine transport (IMDG) Other applicable information (marine transport) No dangerous good in sense of these transport regulations. Air transport (ICAO) Other applicable information (air transport) No dangerous good in sense of these transport regulations Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user No special measures are necessary Transport in bulk according to Annex II of Marpol and the IBC Code not relevant SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 2004/42/EC (VOC): National regulatory information Employment restrictions: Water contaminating class (D): Skin resorption/sensitization: 0% Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC). 2 - water contaminating Causes allergic hypersensitivity reactions. Additional information This mixture contains the following substances of very high concern (SVHC) which are included in the Candidate List according to Article 59 of REACH:none This mixture contains the following substances of very high concern (SVHC) which are subject to authorisation according to Annex XIV of REACH: none Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Relevant H and EUH statements (number and full text) H301 Toxic if swallowed. H302 Harmful if swallowed.

8 Page 8 of 8 H314 H315 H317 H318 H319 H330 H400 H411 H412 Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Fatal if inhaled. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)