Safety Data Sheet. according to Regulation (EC) No 1907/2006. cat for compact lab putty
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1 Page 1 of 9 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Putty for use in dental technology Details of the supplier of the safety data sheet Company name: Street: Place: Carl-Zeiss-Strasse D Ettlingen Telephone: /510-0 Telefax: / Internet: Responsible Department: 1.4. Emergency telephone number: SECTION 2: Hazards identification post@detax.de Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Emergency number: /510-0 This number is only obtainable during office hours (Monday - Thursday 8.00 a.m p.m., Friday 8.00 a.m p.m.) /510-0 This number is only obtainable during office hours (Monday - Thursday 8.00 a.m p.m., Friday p.m.) Indications of danger: T - Toxic, Xn - Harmful, Xi - Irritant R phrases: May impair fertility. May cause harm to the unborn child. Harmful by inhalation and if swallowed. Risk of serious damage to eyes. Toxic: danger of serious damage to health by prolonged exposure if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Possible risks of irreversible effects. Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard categories: Acute toxicity: Acute Tox. 4 Serious eye damage/eye irritation: Eye Irrit. 2 Germ cell mutagenicity: Muta. 2 Specific target organ toxicity - repeated exposure: STOT RE 1 Hazardous to the aquatic environment: Aquatic Chronic 3 Hazard Statements: Harmful if swallowed or if inhaled. Causes serious eye irritation. Suspected of causing genetic defects. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects Label elements Hazardous components which must be listed on the label alkylstannosiloxane
2 Page 2 of 9 Signal word: Pictograms: Danger GHS07-GHS08 Hazard statements H302+H332 H319 H341 H372 H412 Harmful if swallowed or if inhaled. Causes serious eye irritation. Suspected of causing genetic defects. Causes damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects. Precautionary statements P201 Obtain special instructions before use. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER/doctor. Special labelling of certain mixtures EUH208 Contains Menthone, Isomenthone. May produce an allergic reaction Other hazards No information available. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical characterization Silicon-tin-compound with auxilliary matters.
3 Page 3 of 9 Hazardous components EC No CAS No Index No REACH No Chemical name Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity alkylstannosiloxane % Muta. Cat. 3, Repr. Cat. 1, T - Toxic, Xn - Harmful, Xi - Irritant R / / Flam. Liq. 3, Muta. 2, Repr. 1, Acute Tox. 4, Acute Tox. 4, Eye Dam. 1, STOT RE 1, Aquatic Chronic 3; H226 H341 H360D H302 H332 H318 H372 H Menthone < 1 % Xi - Irritant R38-43 Skin Irrit. 2, Skin Sens. 1B; H315 H l-menthyl acetate < 1 % N - Dangerous for the environment R51-53 Aquatic Chronic 2; H Isomenthone < 1 % Xi - Irritant R38-43 Skin Irrit. 2, Skin Sens. 1B; H315 H317 Full text of R-, H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General information First aider: Pay attention to self-protection! Remove affected person from the danger area and lay down. After inhalation Provide fresh air. If breathing is irregular or stopped, administer artificial respiration. Medical treatment necessary. After contact with skin After contact with skin, wash immediately with polyethylene glycol, followed by plenty of water. Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. After contact with eyes In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart and consult an ophthalmologist. After ingestion Rinse mouth immediately and drink plenty of water. Let water be drunken in little sips ( dilution effect). Seek immediately medical advice. Do not induce vomiting. In case of spontaneous vomiting take care of an unhindered flow out of the vomit (danger of suffocation) Most important symptoms and effects, both acute and delayed No information available Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures
4 Page 4 of Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings Special hazards arising from the substance or mixture Non-flammable Advice for firefighters Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit. Additional information Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use personal protection equipment Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe gas/fumes/vapour/spray. Advice on protection against fire and explosion No special fire protection measures are necessary Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Keep locked up. Store in a place accessible by authorized persons only. Provide adequate ventilation as well as local exhaustion at critical locations. Advice on storage compatibility Do not store with strong oxidising materials. Further information on storage conditions Keep only in the original container in a cool, dry and well-ventilated place, away from foodstuffs Specific end use(s) Component A of a silicone based epithesis repair material for use in dentistry. / Putty for use in detal laboratories. For use by trained specialist staff. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls
5 Page 5 of 9 Appropriate engineering controls If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe gas/fumes/vapour/spray. Protective and hygiene measures Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink. Eye/face protection Suitable eye protection: goggles. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Suitable are gloves of the following material: NBR (Nitrile rubber), Butyl caoutchouc (butyl rubber), FKM (fluoro rubber), CR (polychloroprene, chloroprene rubber) Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: liquid: light blue like peppermint Test method >200 C DIN >100 C DIN not applicable not applicable Lower explosion limits: Upper explosion limits: Ignition temperature: Auto-ignition temperature Solid: Gas: >300 C not applicable not applicable Decomposition temperature: >250 C Oxidizing properties Not oxidizing. Vapour pressure: (at 20 C) <1 hpa DIN 51794
6 Page 6 of 9 Density (at 20 C): 1,0 g/cm³ DIN Water solubility: Solubility in other solvents Partition coefficient: Viscosity / dynamic: (at 23 C) Vapour density: Evaporation rate: 9.2. Other information Solid content: insoluble <80 mpa s BROOKFIELD SECTION 10: Stability and reactivity Reactivity No hazardous reaction when handled and stored according to provisions Chemical stability The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions Reacts with : strong oxidising agents Conditions to avoid Higher temperatures advance the formation of flammable vapours, therefore don't expose the product to increased temperatures Incompatible materials No information available Hazardous decomposition products No known hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Harmful if swallowed or if inhaled. For the product itself no toxicological data are available. In products with a comparable composition a LD50 (orally, species rat) of >2000 mg/kg has been found. ATEmix calculated ATE (oral) 509,0 mg/kg; ATE (inhalative vapour) 11,20 mg/l; ATE (inhalative aerosol) 1,527 mg/l CAS No Chemical name Exposure routes Method Dose Species Source alkylstannosiloxane oral ATE 500 mg/kg inhalative vapour ATE 11 mg/l inhalative aerosol ATE 1,5 mg/l Irritation and corrosivity Causes serious eye irritation.
7 Page 7 of 9 Sensitising effects Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. Severe effects after repeated or prolonged exposure Causes damage to organs through prolonged or repeated exposure. (alkylstannosiloxane) Carcinogenic/mutagenic/toxic effects for reproduction Suspected of causing genetic defects. (alkylstannosiloxane) Aspiration hazard Based on available data, the classification criteria are not met. Additional information on tests This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. Special hazards arising from the substance or mixture! SECTION 12: Ecological information Toxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Persistence and degradability The product has not been tested Bioaccumulative potential The product has not been tested Mobility in soil The product has not been tested Results of PBT and vpvb assessment The product has not been tested Other adverse effects No information available. Further information Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to applicable legislation. Contaminated packaging This material and its container must be disposed of as hazardous waste. Handle contaminated packages in the same way as the substance itself. SECTION 14: Transport information Land transport (ADR/RID) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Inland waterways transport (ADN) UN number:
8 Page 8 of UN proper shipping name: Transport hazard class(es): Packing group: Marine transport (IMDG) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Air transport (ICAO) UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulatory information 2010/75/EU (VOC): 2004/42/EC (VOC): Additional information 0,044 % (0,438 g/l) 0,044 % (0,438 g/l) To follow: 850/2004/EC, 79/117/EEC, 689/2008/EC National regulatory information Employment restrictions: Water contaminating class (D): Skin resorption/sensitization: Chemical safety assessment Observe employment restrictions for young people. Observe employment restrictions for child bearing mothers and nursing. 3 - highly water contaminating Causes allergic hypersensitivity reactions. Chemical safety assessments for substances in this mixture were not carried out. SECTION 16: Other information Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50%
9 Page 9 of 9 LD50: Lethal dose, 50% Relevant R-phrases (Number and full text) 10 Flammable. 20/22 Harmful by inhalation and if swallowed. 38 Irritating to skin. 41 Risk of serious damage to eyes. 43 May cause sensitisation by skin contact. 48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed. 51 Toxic to aquatic organisms. 52 Harmful to aquatic organisms. 53 May cause long-term adverse effects in the aquatic environment. 60 May impair fertility. 61 May cause harm to the unborn child. 68 Possible risks of irreversible effects. Relevant H- and EUH-phrases (Number and full text) H226 Flammable liquid and vapour. H302 Harmful if swallowed. H302+H332 Harmful if swallowed or if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H360D May damage the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH208 Contains Menthone, Isomenthone. May produce an allergic reaction. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)
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