: CISPLATIN IMPURITY B CRS
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- Jeremy Mason
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1 in accordance with Regulation (EC) No. 1907/2006, as amended. Date of issue: 27/06/2013 Revision date: 27/06/2013 Supersedes: 02/06/2009 Version: 3.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : Chemical name : Amminetrichloroplatinate (-) Product code : Y Other means of identification : RTECS No : TP (cisplatin) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Function or use category : The product is intended for research, analysis and scientific education. : For professional use only : Laboratory chemicals Uses advised against 1.3. Details of the supplier of the safety data sheet European Directorate for the Quality of Medicines & Healthcare EDQM, Council of Europe F Strasbourg T +33(0) F +33(0) Emergency telephone number Emergency number : +44(0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Carc. 1B Muta. 1B Acute Tox. 2 (Oral) Eye Dam. 1 Repr. 2 Repr. 2 Lact Skin Irrit. 2 STOT SE 3 Full text of H-phrases: see section 16 H350 H340 H300 H318 H361d H361f H362 H315 H335 Classification according to Directive 67/548/EEC or 1999/45/EC Carc.Cat.2; R45 Muta.Cat.2; R46 Repr.Cat.3; R62 Repr.Cat.3; R63 T; R25 Xi; R41 Xi; R37/38 R64 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects Impurities with unknown properties. No information available on this specific product, however by analogy, the product is considered to be: See Heading /08/2013 EN (English) 1/7
2 in accordance with Regulation (EC) No. 1907/2006, as amended Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS06 GHS05 GHS08 : H300 - Fatal if swallowed H315 - Causes skin irritation H318 - Causes serious eye damage H335 - May cause respiratory irritation H340 - May cause genetic defects H350 - May cause cancer H361d - Suspected of damaging the unborn child H361f - Suspected of damaging fertility H362 - May cause harm to breast-fed children : P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapours/spray P263 - Avoid contact during pregnancy/while nursing P264 - Wash hands and other exposed areas thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P302+P352 - IF ON SKIN: Wash with plenty of soap and water P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - IF exposed or concerned: Get medical advice/attention P310 - Immediately call a POISON CENTER or doctor/physician P312 - Call a POISON CENTER/doctor/physician if you feel unwell P330 - Rinse mouth P332+P313 - If skin irritation occurs: Get medical advice/attention P403+P233 - Store in a well-ventilated place. Keep container tightly closed P501 - Dispose of contents/container to : Hazardous waste. Comply with applicable regulations 2.3. Other hazards Other hazards not contributing to the classification : Exposure may produce an allergic reaction. SECTION 3: Composition/information on ingredients 3.1. Substances Name Product identifier % Classification according to Directive 67/548/EEC CISPLATIN IMPURITY B (Main constituent) 100 Carc.Cat.2; R45 Muta.Cat.2; R46 Repr.Cat.3; R62 Repr.Cat.3; R63 T; R25 Xi; R41 Xi; R37/38 R64 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] CISPLATIN IMPURITY B (Main constituent) 100 Carc. 1B, H350 Muta. 1B, H340 Acute Tox. 2 (Oral), H300 Eye Dam. 1, H318 Repr. 2, H361d Repr. 2, H361f Lact, H362 Skin Irrit. 2, H315 STOT SE 3, H335 Full text of R-, H- and EUH-phrases: see section 16 05/08/2013 EN (English) 2/7
3 in accordance with Regulation (EC) No. 1907/2006, as amended Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If you feel unwell, seek medical advice (show the label where possible). : Move to fresh air in case of accidental inhalation. Assure fresh air breathing. Obtain medical attention if breathing difficulty persists. : Rinse skin with water/shower. Wash with plenty of soap and water. : Rinse with water while holding the eyes wide open. Contact lenses should be removed. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth out with water. The following symptoms may occur: (see section(s) : 2). If you feel unwell, seek medical advice Most important symptoms and effects, both acute and delayed Symptoms/injuries : See Heading Indication of any immediate medical attention and special treatment needed No data available. Treat symptomatically. Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture : Small amounts: Use extinguishing media appropriate for surrounding fire. Water spray. Carbon dioxide. Dry powder. Foam. Large amounts: Not applicable Advice for firefighters Precautionary measures fire : Small amounts: Use normal individual fire protective equipment. Large amounts: Not applicable. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel Protective equipment : See Headings 7 and For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Wear suitable protective clothing, gloves and eye or face protection. Large amounts: Not applicable. : Ensure waste is collected and contained. Clean thoroughly. : Small amounts: See Heading 1. When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. Precautions for safe handling : Handle and open container with care. See Heading 8. Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products 7.3. Specific end use(s) See Heading 1. : Handle in accordance with good industrial hygiene and safety procedures. : Comply with applicable regulations. : To guarantee the quality and properties of the product, keep : dry, Keep in a cool, wellventilated place away from heat. Store in original container. : Strong oxidizing agents. 05/08/2013 EN (English) 3/7
4 in accordance with Regulation (EC) No. 1907/2006, as amended. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Material should be handled in a laboratory hood whenever possible. Personal protective equipment : Gloves. Safety glasses. Protective clothing. Dust production: dust mask with filter type P3. Hand protection Eye protection : Wear eye protection. DIN EN 166. Skin and body protection Respiratory protection SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour : Chemical resistant PVC gloves (to European standard EN 374 or equivalent). Gloves. : Wear suitable protective clothing. DIN EN Lab coat. : Wear appropriate breathing apparatus if air renewal not sufficient to maintain dust/vapour under TLV. Quarter mask (DIN EN 140). : Solid : Yellow. May be present in various forms. orange. Crystals. Powder. Odour : Not applicable. See Heading 2, 4.2, 8. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Possibility of hazardous reactions : Water: >= 1 (1-10) mg/l Small amounts: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. Large amounts: Not applicable. 05/08/2013 EN (English) 4/7
5 in accordance with Regulation (EC) No. 1907/2006, as amended Conditions to avoid Incompatible materials Small amounts: None under normal use. Large amounts: Not applicable Hazardous decomposition products When heated to decomposition, emits dangerous fumes. Large amounts: Not applicable. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Fatal if swallowed. Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Ecology - general : Causes skin irritation. : Causes serious eye damage. : Not classified : May cause genetic defects. : May cause cancer. : Suspected of damaging the unborn child. Suspected of damaging fertility. May cause harm to breast-fed children. : May cause respiratory irritation. : Not classified : Not classified : No appropriate human or animal health effects data are known to exist. : Small amounts: See Heading 2. Large amounts: Not applicable Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects : The statement is derived from products of similar structure or composition. : (No data available specific to the product) SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number UN-No : 3467 UN-No.(IATA) : 3467 UN-No. (IMDG) : 3467 : Dispose in a safe manner in accordance with local/national regulations. : Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point UN proper shipping name Proper Shipping Name Transport document description : ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S. : UN 3467 ORGANOMETALLIC COMPOUND, TOXIC, SOLID, N.O.S., 6.1, II, (D/E) 05/08/2013 EN (English) 5/7
6 in accordance with Regulation (EC) No. 1907/2006, as amended Transport hazard class(es) Class (UN) : 6.1 Class (IATA) : 6.1 Class (IMDG) : 6.1 Hazard labels (UN) : Packing group Packing group (UN) : II Packing group (IMDG) : II Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 60 Classification code (UN) : T3 Orange plates : Tunnel restriction code LQ Excepted quantities (ADR) : D/E : LQ18 : E Transport by sea Ship Safety Act : Toxic and infectious substances/toxic substances Port Regulation Law : Toxic and infectious substances/toxic substances MFAG-No : Air transport Civil Aeronautics Law : Toxic and infectious substances/toxic substances Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions National regulations Chemical safety assessment SECTION 16: Other information 05/08/2013 EN (English) 6/7
7 in accordance with Regulation (EC) No. 1907/2006, as amended. Full text of R-, H- and EUH-phrases:: Acute Tox. 2 (Oral) Acute toxicity (oral), Category 2 Carc. 1B Carcinogenicity, Category 1B Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Lact Reproductive toxicity, Additional category, Effects on or via lactation Muta. 1B Germ cell mutagenicity, Category 1B Repr. 2 Reproductive toxicity, Category 2 Repr. 2 Reproductive toxicity, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H300 Fatal if swallowed H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H340 May cause genetic defects H350 May cause cancer H361d Suspected of damaging the unborn child H361f Suspected of damaging fertility H362 May cause harm to breast-fed children R25 Toxic if swallowed R37/38 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R45 May cause cancer R46 May cause heritable genetic damage R62 Possible risk of impaired fertility R63 Possible risk of harm to the unborn child R64 May cause harm to breastfed babies T Toxic Xi Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/08/2013 EN (English) 7/7
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