Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/ A Page 1 of 12 SDS No. : V006.1 Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 3471A Contains: 1,3-bis(2,3-epoxypropoxy)-2,2-bis[(2,3-epoxypropoxy)methyl]propane Oxirane, mono[(c10-16-alkyloxy)methyl] derivs 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy adhesive 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Skin irritation Category 2 H315 Causes skin irritation. Serious eye irritation Category 2 H319 Causes serious eye irritation. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Chronic hazards to the aquatic environment Category 2 H411 Toxic to aquatic life with long lasting effects Label elements Label elements (CLP):

2 MSDS-No.: V A Page 2 of 12 Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Prevention Precautionary statement: Response Warning H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. P273 Avoid release to the environment. P280 Wear protective gloves. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention Other hazards None if used properly. SECTION 3: Composition/information on ingredients 3.2. Mixtures Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification % Skin Irrit. 2 H315 Skin Sens. 1 H317 Eye Irrit. 2 H319 Aquatic Chronic 2 H411 1,3-bis(2,3-epoxypropoxy)-2,2-bis[(2,3- epoxypropoxy)methyl]propane Oxirane, mono[(c10-16-alkyloxy)methyl] derivs ,5-10 % Skin Irrit. 2 H315 Skin Sens. 1 H317 Eye Irrit. 2 H <= 2,5 % Skin Irrit. 2; Dermal H315 Skin Sens. 1; Dermal H317 Eye Irrit. 2 H319 Aquatic Chronic 2 H411 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. SECTION 4: First aid measures

3 MSDS-No.: V A Page 3 of 12 Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed EYE: Irritation, conjunctivitis. SKIN: Rash, Urticaria. SKIN: Redness, inflammation Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: None known 5.2. Special hazards arising from the substance or mixture Oxides of carbon, oxides of nitrogen, irritating organic vapors Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. See advice in section Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation.

4 MSDS-No.: V A Page 4 of 12 Hygiene measures: Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place Specific end use(s) Epoxy adhesive SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain None Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) period Value mg/l ppm mg/kg others 0,006 mg/l 0,996 mg/kg 0,0996 mg/kg soil 0,196 mg/kg oral 0,0006 mg/l 0,018 mg/l 10 mg/l 11 mg/kg food Remarks

5 MSDS-No.: V A Page 5 of 12 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers Dermal Acute/short term Workers Inhalation Acute/short term Workers Dermal Long term Workers Inhalation Long term Dermal Dermal Inhalation Inhalation oral oral Acute/short term Long term Acute/short term Long term Acute/short term Long term Time Value 8,33 mg/kg bw/day 12,25 mg/m3 8,33 mg/kg bw/day 12,25 mg/m3 3,571 mg/kg bw/day 3,571 mg/kg bw/day 0,75 mg/m3 0,75 mg/m3 0,75 mg/kg bw/day 0,75 mg/kg bw/day Remarks Biological Indices: None 8.2. controls: Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.

6 MSDS-No.: V A Page 6 of 12 Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor mild Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 100 C (> 212 F) > 100 C (> 212 F) 2,3 g/cm3 Not miscible 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Stable under normal conditions of storage and use Incompatible materials No data available Hazardous decomposition products carbon oxides.

7 MSDS-No.: V A Page 7 of Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause irritation to respiratory system. Skin irritation: Causes skin irritation. Eye irritation: Causes serious eye irritation. Sensitizing: May cause an allergic skin reaction. Acute oral toxicity: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Oxirane, mono[(c alkyloxy)methyl] derivs Value type Value Route of application time Species LD50 > mg/kg oral rat LD50 > mg/kg oral rat Method Acute dermal toxicity: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Value Value Route of Species type application time LD mg/kg dermal rabbit Method Skin corrosion/irritation: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result time Species Method slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result time Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion)

8 MSDS-No.: V A Page 8 of 12 Respiratory or skin sensitization: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: Reaction product: bisphenol-a- (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time Species Method OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Do not empty into drains / surface water / ground water.

9 MSDS-No.: V A Page 9 of 12 Reaction product: bisphenol- A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) Reaction product: bisphenol- A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) Reaction product: bisphenol- A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) 1,3-bis(2,3-epoxypropoxy)- 2,2-bis[(2,3- epoxypropoxy)methyl]propan e Oxirane, mono[(c alkyloxy)methyl] derivs Oxirane, mono[(c alkyloxy)methyl] derivs Value type Value Acute Toxicity Study time Species Method LC50 1, mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 1,75 mg/l Fish 96 h Oncorhynchus mykiss (reported as Salmo gairdneri) OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 2,4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) EC50 9,4 mg/l Algae 72 h Scenedesmus capricornutum OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 0,3 mg/l chronic Daphnia 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LC mg/l Fish 96 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) LC50 > 1-10 mg/l Fish 96 h OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 1-10 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability Reaction product: bisphenol- A-(epichlorhydrin); epoxy resin (number average molecular weight <= 700) Result Route of application Degradability Method aerobic 5 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. 1,3-bis(2,3-epoxypropoxy)- 2,2-bis[(2,3- epoxypropoxy)methyl]propan e LogKow Bioconcentration factor (BCF) time Species Temperature Method < 2,6 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) Results of PBT and vpvb assessment PBT/vPvB

10 MSDS-No.: V A Page 10 of 12 (epichlorhydrin); epoxy resin (number average molecular weight <= 700) Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. SECTION 13: Disposal considerations Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Dispose of in accordance with local and national regulations. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances

11 MSDS-No.: V A Page 11 of 12 SECTION 14: Transport information UN number ADR 3082 RID 3082 ADN 3082 IMDG 3082 IATA UN proper shipping name ADR RID ADN IMDG IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bisphenol-A Epichlorhydrin resin) Environmentally hazardous substance, liquid, n.o.s. (Bisphenol-A Epichlorhydrin resin) Transport hazard class(es) ADR 9 RID 9 ADN 9 IMDG 9 IATA Packaging group ADR RID ADN IMDG IATA III III III III III Environmental hazards ADR RID ADN IMDG IATA Marine pollutant Special precautions for user ADR RID ADN IMDG IATA Tunnelcode: (E) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3,00 % Combined A/B

12 MSDS-No.: V A Page 12 of 12 (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Label elements (DPD): Xi - Irritant N - Dangerous for the environment Risk phrases: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S37 Wear suitable gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Contains epoxy constituents. See information supplied by the manufacturer. Contains:, 1,3-bis(2,3-epoxypropoxy)-2,2-bis[(2,3-epoxypropoxy)methyl]propane, Oxirane, mono[(c10-16-alkyloxy)methyl] derivs Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.

13 Safety Data Sheet according to (EC) No 1907/ B Page 1 of 13 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 3471B Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy Hardener 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Skin corrosion Category 1B H314 Causes severe skin burns and eye damage. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Chronic hazards to the aquatic environment Category 3 H412 Harmful to aquatic life with long lasting effects Label elements Label elements (CLP): Hazard pictogram:

14 MSDS-No.: Signal word: Hazard statement: 3471B Page 2 of 13 Danger H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. Precautionary statement: Prevention Precautionary statement: Response P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. P333+P313 If skin irritation or rash occurs: Get medical advice/attention Other hazards None if used properly. SECTION 3: Composition/information on ingredients 3.2. Mixtures Declaration of the ingredients according to CLP (EC) No 1272/2008: Fatty acids, tall-oil, reaction products with tetraethylenepentamine EC Number REACH-Reg No. content Classification ,5-10 % Eye Dam. 1 H318 Aquatic Chronic 2 H ,5-10 % Acute Tox. 4; Dermal H312 Acute Tox. 4; Oral H302 Skin Sens. 1 H317 Aquatic Chronic 3 H412 Skin Corr. 1B H314 <= 2,5 % Repr. 2 H361f STOT SE 3 H335 Eye Dam. 1 H318 Skin Sens. 1 H317 Aquatic Chronic 2 H411 2,2-Dimethylpropane-1,3-diamine <= 2,5 % Flam. Liq. 3 H226 Skin Corr. 1B H314 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures

15 MSDS-No.: B Page 3 of 13 Inhalation: Move to fresh air. In case of adverse health effects seek medical advice. Skin contact: Rinse with running water and soap. Seek medical advice. Eye contact: Rinse immediately with plenty of running water (for 10 minutes). Seek medical attention if necessary. Ingestion: Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting. Seek medical advice Most important symptoms and effects, both acute and delayed SKIN: Rash, Urticaria. Causes burns Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: None known 5.2. Special hazards arising from the substance or mixture None 5.3. Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Avoid skin and eye contact. Wear protective equipment. See advice in section Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up For large spills absorb onto inert absorbent material and place in sealed container for disposal. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section 8 SECTION 7: Handling and storage

16 MSDS-No.: B Page 4 of Precautions for safe handling Avoid skin and eye contact. Use only in well-ventilated areas. Gloves and safety glasses should be worn Do not inhale vapors and fumes. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed Conditions for safe storage, including any incompatibilities Store in sealed original container. Store in a cool, well-ventilated place Specific end use(s) Epoxy Hardener SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit category / Remarks 10 Time Weighted Average (TWA): [BISPHENOL A, INHALABLE DUST] [BISPHENOL A (INHALABLE DUST)] 10 Time Weighted Average (TWA): Indicative Regulatory list EH40 WEL ECTLV

17 MSDS-No.: B Page 5 of 13 Predicted No-Effect Concentration (PNEC): Name on list 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) sediment (freshwater) sediment (marine water) period Value mg/l ppm mg/kg others 0,06 mg/l 5,784 mg/kg 0,578 mg/kg soil 1,121 mg/kg STP aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) soil oral 2,2 mg/kg 0,44 mg/kg 3,7 mg/kg 0,006 mg/l 0,23 mg/l 3,18 mg/l 0,018 mg/l 0,016 mg/l 0,01 mg/l 320 mg/l 13,8 mg/kg food Remarks

18 MSDS-No.: B Page 6 of 13 Derived No-Effect Level (DNEL): Name on list 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine 3-Aminomethyl-3,5,5- trimethylcyclohexylamine Application Area Route of Health Effect Workers Inhalation Acute/short term Workers Inhalation Acute/short term local effects oral Long term Workers Dermal Acute/short term Workers Inhalation Acute/short term local effects Workers Dermal Long term Workers Inhalation Long term local effects Workers Inhalation Acute/short term Workers Inhalation Long term Dermal Inhalation oral Dermal Inhalation oral Inhalation Inhalation Acute/short term Acute/short term Acute/short term Long term Long term Long term Long term local effects Acute/short term local effects Time Value 20,1 mg/m3 20,1 mg/m3 0,526 mg/kg bw/day 1,4 mg/kg bw/day 10 mg/m3 1,4 mg/kg bw/day 10 mg/m3 10 mg/m3 10 mg/m3 0,7 mg/kg bw/day 5,0 mg/m3 0,05 mg/kg bw/day 0,7 mg/kg bw/day 0,25 mg/m3 0,05 mg/kg bw/day 5 mg/m3 5 mg/m3 Remarks Biological Indices: None 8.2. controls: Respiratory protection: Ensure adequate ventilation. Do not inhale vapors and fumes. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A

19 MSDS-No.: B Page 7 of 13 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Tightly fitting safety goggles Avoid eye contact. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor mild Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 100 C (> 212 F) > 100 C (> 212 F) 2,4 g/cm3 Not miscible 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with strong oxidants Chemical stability Stable under recommended storage conditions.

20 MSDS-No.: B Page 8 of Possibility of hazardous reactions See section reactivity Conditions to avoid Stable under normal conditions of storage and use. Avoid contact with acids and oxidizing agents. Avoid contact with water Incompatible materials No data available Hazardous decomposition products carbon oxides Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: May cause irritation to the digestive tract. Skin irritation: Causes severe skin burns and eye damage. Eye irritation: Corrosive Avoid eye contact. Sensitizing: May cause an allergic skin reaction. Acute oral toxicity: Fatty acids, tall-oil, reaction products with tetraethylenepentamine Fatty acids, tall-oil, reaction products with tetraethylenepentamine ,4'- Isopropylidenediphenol Value Value Route of type application LD50 > mg/kg oral time LD50 > mg/kg rat LD mg/kg oral rat Species Method LD mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute inhalative toxicity: Value type Value Route of application time Species Method LC50 > 5,01 mg/l Aerosol 4 h rat OECD Guideline 403 (Acute Inhalation Toxicity)

21 MSDS-No.: B Page 9 of 13 Acute dermal toxicity: Fatty acids, tall-oil, reaction products with tetraethylenepentamine ,4'- Isopropylidenediphenol Value Value Route of type application LD50 > mg/kg dermal time Species LD mg/kg dermal rabbit Method Serious eye damage/irritation: Result time Species Method corrosive rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: sensitising Result Test type Species Method Guinea pig maximisat ion test guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: 4,4'- Isopropylidenediphenol Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g negative Ames test) bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without with and without Species Method EU Method B.13/14 (Mutagenicity) Repeated dose toxicity Result LOAEL=< 160 mg/kg NOAEL=< 60 mg/kg Route of application oral: drinking water oral: drinking water time / Frequency of treatment Species Method 13 weeks rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) 13 weeks rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Harmful to aquatic life with long lasting effects. Do not empty into drains / surface water / ground water.

22 MSDS-No.: Fatty acids, tall-oil, reaction products with tetraethylenepentamine Fatty acids, tall-oil, reaction products with tetraethylenepentamine Fatty acids, tall-oil, reaction products with tetraethylenepentamine B Page 10 of 13 Value type Value Acute Toxicity Study LC mg/l Fish EC mg/l Daphnia EC mg/l Algae time Species Method LC mg/l Fish 96 h Leuciscus idus EU Method C.1 (Acute Toxicity for Fish) EC50 42 mg/l Daphnia 24 h Daphnia magna EC50 37 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) NOEC 1,5 mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus NOEC 3 mg/l chronic Daphnia EU Method C.3 (Algal Inhibition test) EU Method C.3 (Algal Inhibition subspicatus) test) 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LC50 9,9 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 16 µg/l Fish 444 d Pimephales promelas EPA OPP 72-5 (Fish Life Cycle Toxicity) EC50 3,9 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 2,5 mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) NOEC > 3,146 mg/l chronic Daphnia OECD Guideline 201 (Alga, Growth Inhibition Test) 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) Persistence and degradability Result Route of application Degradability Method aerobic 8 % OECD Guideline 301 A (new version) (Ready Biodegradability: DOC Die Away Test) readily biodegradable aerobic 89 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. LogKow Bioconcentration Species Temperature Method factor (BCF) time 5,1-13,8 42 d Cyprinus carpio 25 C 3,4 21,5 C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) Results of PBT and vpvb assessment

23 MSDS-No.: B Page 11 of 13 PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. SECTION 13: Disposal considerations Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances

24 MSDS-No.: B Page 12 of 13 SECTION 14: Transport information UN number ADR 1760 RID 1760 ADN 1760 IMDG 1760 IATA UN proper shipping name ADR RID ADN IMDG IATA CORROSIVE LIQUID, N.O.S. (Fatty acids, tall-oil, reaction products with tetraethylenepentamine,isophoronediamine) CORROSIVE LIQUID, N.O.S. (Fatty acids, tall-oil, reaction products with tetraethylenepentamine,isophoronediamine) CORROSIVE LIQUID, N.O.S. (Fatty acids, tall-oil, reaction products with tetraethylenepentamine,isophoronediamine) CORROSIVE LIQUID, N.O.S. (Fatty acids, tall-oil, reaction products with tetraethylenepentamine,isophoronediamine) Corrosive liquid, n.o.s. (Fatty acids, tall-oil, reaction products with tetraethylenepentamine,isophoronediamine) Transport hazard class(es) ADR 8 RID 8 ADN 8 IMDG 8 IATA Packaging group ADR RID ADN IMDG IATA II II II II II Environmental hazards ADR RID ADN IMDG IATA Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Special precautions for user ADR RID ADN IMDG IATA Tunnelcode: (E) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 %

25 MSDS-No.: B Page 13 of 13 (2010/75/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H226 Flammable liquid and vapor. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H361f Suspected of damaging fertility. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Label elements (DPD): C - Corrosive Risk phrases: R34 Causes burns. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and its container must be disposed of as hazardous waste. Contains:, Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.