: Scratch-off UV Cure Varnish

Transcription

1 Date of issue: 2017/04/19 Revision date: 2017/06/26 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : Scratch-off UV Cure Varnish : D493-A Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture : Professional use : PRINTING INK Uses advised against 1.3. Details of the supplier of the safety data sheet GL Specialized Inks (Pty) Ltd 8 Hawthorne Place Mahogany Ridge Westmead Durban Telephone: +27 (0) Fax: +27 (0) After hours: (Jay) (Julie) jay@gl-inks.com 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category H319 2 Skin sensitisation, Category 1 H317 Specific target organ toxicity Single H335 exposure, Category 3, Respiratory tract irritation Hazardous to the aquatic environment H411 Chronic Hazard, Category 2 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : GHS07 GHS /06/28 EN (English) 1/8

2 Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Warning : 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, esters with acrylic acid; SR306 (TPGDA) (DISPENSER); 2,2-bis(acryloyloxymethyl)butyl acrylate, trimethylolpropane triacrylate : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation H411 - Toxic to aquatic life with long lasting effects : P261 - Avoid breathing fume, mist, spray, vapours P280 - Wear eye protection, protective clothing, protective gloves P302+P352 - IF ON SKIN: Wash with plenty of Wash with plenty of soap and water P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTRE or doctor if you feel unwell P362+P364 - Take off contaminated clothing and wash it before reuse P501 - Dispose of contents to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, esters with acrylic acid (CAS-No.) (EC-No.) SR306 (TPGDA) (DISPENSER) (CAS-No.) (EC-No.) (REACH-no) ,2-bis(acryloyloxymethyl)butyl acrylate, trimethylolpropane triacrylate (CAS-No.) (EC-No.) (EC Index-No.) Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 STOT SE 3, H335 Aquatic Chronic 2, H Eye Irrit. 2, H319 Skin Irrit. 2, H315 Skin Sens. 1, H317 CELLULOSE ACETATE BUTYRATE (CAS-No.) Acute Tox. 4 (Dermal), H312 Triethanolamine (CAS-No.) (EC-No.) (REACH-no) Full text of H-statements: see section Skin Irrit. 2, H315 Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. 2017/06/28 EN (English) 2/8

3 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Do not breathe fume, mist, spray, vapours. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not breathe fume, mist, spray, vapours. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Wear personal protective equipment. : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Personal protective equipment: Avoid all unnecessary exposure. Safety glasses. Gloves. Protective clothing. Materials for protective clothing: Wear suitable protective clothing Hand protection: In case of repeated or prolonged contact wear gloves Eye protection: Eye protection should only be necessary where liquid could be splashed or sprayed Skin and body protection: 2017/06/28 EN (English) 3/8

4 Wear suitable protective clothing Respiratory protection: Where exposure through inhalation may occur from use, respiratory protection equipment is recommended Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : Not applicable Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Not applicable Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. 2017/06/28 EN (English) 4/8

5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Triethanolamine ( ) LD50 oral LD50 dermal LC50 inhalation rat (Dust/Mist - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity 8000 mg/kg bodyweight > mg/kg bodyweight > 1,8 mg/l : Causes skin irritation. : Causes serious eye irritation. : May cause an allergic skin reaction. STOT-single exposure STOT-repeated exposure Aspiration hazard : May cause respiratory irritation. SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity Triethanolamine ( ) LC50 fish 1 EC50 other aquatic organisms 1 EC50 other aquatic organisms 2 : Toxic to aquatic life with long lasting effects. : Toxic to aquatic life with long lasting effects mg/l 2038 mg/l waterflea 216 mg/l Persistence and degradability Bioaccumulative potential Triethanolamine ( ) Log Pow -1, Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Avoid release to the environment. ADR IMDG IATA ADN RID UN number UN proper shipping name ENVIRONMENTALLY ENVIRONMENTALLY Environmentally ENVIRONMENTALLY ENVIRONMENTALLY 2017/06/28 EN (English) 5/8

6 ADR IMDG IATA ADN RID (DISPENSER)) (DISPENSER)) Transport document description UN 3082 UN 3082 ENVIRONMENTALLY ENVIRONMENTALLY (DISPENSER)), 9, III, (E) (DISPENSER)), 9, III, MARINE POLLUTANT hazardous substance, liquid, n.o.s. (SR306 (TPGDA) (DISPENSER)) UN 3082 Environmentally hazardous substance, liquid, n.o.s. (SR306 (TPGDA) (DISPENSER)), 9, III (DISPENSER)) UN 3082 ENVIRONMENTALLY (DISPENSER)), 9, III (DISPENSER)) UN 3082 ENVIRONMENTALLY (DISPENSER)), 9, III Transport hazard class(es) Packing group III III III III III Environmental hazards Special precautions for user Marine pollutant : Yes No supplementary information available - Overland transport Classification code (ADR) : M6 Special provisions (ADR) : 274, 335, 601, 375 Limited quantities (ADR) : 5l Excepted quantities (ADR) Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions : T4 (ADR) Portable tank and bulk container special : TP1, TP29 provisions (ADR) Tank code (ADR) : LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages : V12 (ADR) Special provisions for carriage - Loading, : CV13 unloading and handling (ADR) Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : E - Transport by sea Special provisions (IMDG) : 274, 335, 969 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) Packing instructions (IMDG) : P001, LP01 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 2017/06/28 EN (English) 6/8

7 Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) : TP2, TP29 : F-A : S-F : A - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : Y964 : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) : 450L : A97, A158, A197 : 9L : M6 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) : 5 L : T : PP Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : M6 Special provisions (RID) : 274, 335, 375, 601 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 5L : P001, IBC03, LP01, R001 : PP1 : MP19 : T4 Transport category (RID) : 3 Special provisions for carriage Packages (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) : TP1, TP29 : LGBV : W12 : CW13, CW31 : CE8 Hazard identification number (RID) : Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 3(b) Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10 SR306 (TPGDA) (DISPENSER) - 2,2- bis(acryloyloxymethyl)butyl acrylate, trimethylolpropane triacrylate - Triethanolamine Scratch-off UV Cure Varnish - 4,4'- Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane, esters with acrylic acid - SR306 (TPGDA) (DISPENSER) - 2,2-bis(acryloyloxymethyl)butyl acrylate, trimethylolpropane triacrylate - Triethanolamine 2017/06/28 EN (English) 7/8

8 3(c) Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1 Scratch-off UV Cure Varnish - SR306 (TPGDA) (DISPENSER) Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Recommendations Danish Regulation : Water hazard class (WGK) 3, severe hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H312 Harmful in contact with skin H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H335 May cause respiratory irritation H411 Toxic to aquatic life with long lasting effects SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2017/06/28 EN (English) 8/8