CFS-F FX / CP 660 Safety information for 2-Component-products

Transcription

1 CFS-F FX / CP 660 Safety information for 2-Component-products Date of issue: 18/12/2017 Revision date: 18/12/2017 Supersedes: 08/11/2017 Version: 6.0 SECTION 1: Kit identification 1.1 Product identifier Trade name CFS-F FX / CP 660 Product code BU Fire Protection 1.2 Details of the supplier of the Safety information for 2-Component-products Hilti Deutschland AG Hiltistr Kaufering - Deutschland T F de.kundenservice@hilti.com SECTION 2: General information Germany VwVwS Annex reference Storage class (LGK) Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) LGK 10 - Combustible liquids A SDS for each of these components is included. Please do not separate any component SDS from this cover page SECTION 3: Kit contents Classification of the Product Classification according to Regulation (EC). 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute Tox. 4 (Inhalation) H332 Skin Irrit. 2 Eye Irrit. 2 Resp. Sens. 1 Skin Sens. 1 Carc. 2 STOT SE 3 STOT RE 2 H315 H319 H334 H317 H351 H335 H373 Full text of hazard classes and H-statements : see section 16 Label elements Labelling according to Regulation (EC). 1272/2008 [CLP] 21/03/2018 EN (English) 1/19

2 CFS-F FX / CP 660 Kit Safety Information Sheet Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Danger GHS07 GHS08 4,4'-diphenylmethanediisocyanate, isomeres and homologues; 2-octyl-2H-isothiazol-3-one; Ethylenediamine, ethoxylated and propoxylated H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. P260 - Do not breathe vapours. P280 - Wear eye protection, protective clothing, protective gloves. P284 - [In case of inadequate ventilation] wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a doctor, a POISON CENTER. Additional information Name General description Quantity Unit Classification according to Regulation (EC). 1272/2008 [CLP] CFS-F FX, A / CP 660, A 1 pcs (pieces) Skin Sens. 1, H317 CFS-F FX, B / CP 660, B 1 pcs (pieces) Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 SECTION 4: General information General advice For professional users only SECTION 5: Safe handling advice Environmental precautions Storage conditions Precautions for safe handling Avoid release to the environment. Store in a well-ventilated place. Keep cool. Do not handle until all safety precautions have been read and understood. Wear personal protective equipment Do not breathe vapours. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes In case of inadequate ventilation wear respiratory protection. 21/03/2018 EN (English) 2/19

3 CFS-F FX / CP 660 Kit Safety Information Sheet Methods for cleaning up Take up liquid spill into absorbent material tify authorities if product enters sewers or public waters SECTION 6: First aid measures First-aid measures after eye contact First-aid measures after ingestion First-aid measures after inhalation First-aid measures after skin contact First-aid measures general Symptoms/effects after eye contact Symptoms/effects after inhalation Symptoms/effects after skin contact Other medical advice or treatment Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a poison center or a doctor if you feel unwell Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell Wash with plenty of water/ If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing. If you feel unwell, seek medical advice (show the label where possible) Eye irritation May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Irritation May cause an allergic skin reaction. Treat symptomatically SECTION 7: Fire fighting measures Protection during firefighting Hazardous decomposition products in case of fire Self-contained breathing apparatus Complete protective clothing Toxic fumes may be released Carbon dioxide Carbon monoxide SECTION 8: Other information 21/03/2018 EN (English) 3/19

4 CFS-F FX, A / CP 660, A Date of issue: 01/03/2018 Revision date: 19/12/2017 Supersedes: 08/11/2017 Version: 6.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Product code Mixture CFS-F FX, A / CP 660, A BU Fire Protection 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture For professional use only Firestop foam Uses advised against 1.3. Details of the supplier of the safety data sheet Hilti Deutschland AG Hiltistr Kaufering - Deutschland T F de.kundenservice@hilti.com Supplier Hilti Deutschland AG Hiltistr Kaufering - Deutschland T F de.kundenservice@hilti.com Department issuing data specification sheet Hilti AG Feldkircherstraße Schaan - Liechtenstein T chemicals.hse@hilti.com 1.4. Emergency telephone number Emergency number Schweizerisches Toxikologisches Informationszentrum 24h Service (international) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC). 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Skin sensitisation, Category 1 Full text of hazard classes and H-statements : see section 16 H317 Adverse physicochemical, human health and environmental effects May cause an allergic skin reaction Label elements Labelling according to Regulation (EC). 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display EN (English) 4/19

5 CFS-F FX, A / CP 660, A Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 Warning 2-octyl-2H-isothiazol-3-one; Ethylenediamine, ethoxylated and propoxylated H317 - May cause an allergic skin reaction. P280 - Wear eye protection, protective clothing, protective gloves. P302+P352 - IF ON SKIN: Wash with plenty of water Other hazards Adverse physicochemical, human health and environmental effects May cause an allergic skin reaction. SECTION 3: Composition/information on ingredients 3.1. Substances t applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC). 1272/2008 [CLP] Ethylenediamine, propoxylated (CAS-.) (EC-.) (REACH-no) ,5-5 Eye Irrit. 2, H319 Ethylenediamine, ethoxylated and propoxylated (CAS-.) (EC-.) (REACH-no) Full text of H-statements: see section 16 2,5-5 Eye Irrit. 2, H319 Skin Sens. 1, H317 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Remove person to fresh air and keep comfortable for breathing. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact May cause an allergic skin reaction Indication of any immediate medical attention and special treatment needed Treat symptomatically EN (English) 5/19

6 CFS-F FX, A / CP 660, A SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released. Carbon monoxide. Carbon dioxide Advice for firefighters Protection during firefighting Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Ventilate spillage area. Avoid contact with skin and eyes. For further information refer to section 8: "Exposure controls/personal protection". Use personal protective equipment as required Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Take up liquid spill into absorbent material. Other information Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Store in a well-ventilated place. Keep cool. Storage temperature 5-25 C 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters EN (English) 6/19

7 CFS-F FX, A / CP 660, A 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Ensure good ventilation of the work station. Safety glasses. Protective clothing. Gloves. Hand protection Protective gloves. EN 374 Type Material Permeation Thickness (mm) Standard Disposable gloves Nitrile rubber (NBR) 3 (> 60 minutes) EN 374 Eye protection Safety glasses. EN 166. EN 170 Type Use Characteristics Standard Safety glasses EN 166, EN 170 Skin and body protection Respiratory protection Wear suitable protective clothing t necessary with sufficient ventilation Environmental exposure controls Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour red. Odour Odour threshold ph t determined Relative evaporation rate (butylacetate=1) Melting point t applicable Freezing point Boiling point Flash point t applicable. Auto-ignition temperature Decomposition temperature Flammability (solid, gas) t applicable Vapour pressure Relative vapour density at 20 C Relative density Density 1,17 g/cm³ Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information EN (English) 7/19

8 CFS-F FX, A / CP 660, A SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions dangerous reactions known under normal conditions of use Conditions to avoid ne under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard ph: t determined ph: t determined May cause an allergic skin reaction. SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment Persistence and degradability EN (English) 8/19

9 CFS-F FX, A / CP 660, A Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations European List of Waste (LoW) code Dispose in a safe manner in accordance with local/national regulations * - waste adhesives and sealants containing organic solvents or other dangerous substances SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN Other information supplementary information available ADR Regulatory status: IMDG Regulatory status: IATA Regulatory status: RID Regulatory status: ADR IMDG IATA RID UN number t regulated for transport UN proper shipping name t applicable t applicable t applicable t applicable Transport hazard class(es) t applicable t applicable t applicable t applicable t applicable t applicable t applicable t applicable Packing group t applicable t applicable t applicable t applicable Environmental hazards Dangerous for the environment : Dangerous for the environment : Marine pollutant : Dangerous for the environment : supplementary information available Dangerous for the environment : Special precautions for user - Overland transport EN (English) 9/19

10 CFS-F FX, A / CP 660, A - Transport by sea - Air transport - Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code t applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference Storage class (LGK) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) LGK 10 - Combustible liquids Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Chemical safety assessment chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: Modified. Section Changed item Change Comments 2.2 Precautionary statements (CLP) Modified Full text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 H317 H319 May cause an allergic skin reaction. Causes serious eye irritation. SDS_EU_Hilti This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 10/19

11 CFS-F FX, B / CP 660, B Date of issue: 18/12/2017 Revision date: 18/12/2017 Supersedes: 08/11/2017 Version: 6.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Product code Mixture CFS-F FX, B / CP 660, B BU Fire Protection 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture Firestop foam Uses advised against 1.3. Details of the supplier of the safety data sheet Hilti Deutschland AG Hiltistr Kaufering - Deutschland T F de.kundenservice@hilti.com Supplier Hilti Deutschland AG Hiltistr Kaufering - Deutschland T F de.kundenservice@hilti.com Department issuing data specification sheet Hilti AG Feldkircherstraße Schaan - Liechtenstein T chemicals.hse@hilti.com 1.4. Emergency telephone number Emergency number Schweizerisches Toxikologisches Informationszentrum 24h Service (international) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC). 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Acute toxicity (inhal.), Category 4 Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Respiratory sensitisation, Category 1 Skin sensitisation, Category 1 Carcinogenicity, Category 2 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Specific target organ toxicity Repeated exposure, Category 2 Full text of hazard classes and H-statements : see section 16 H332 H315 H319 H334 H317 H351 H335 H373 Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled EN (English) 11/19

12 CFS-F FX, B / CP 660, B 2.2. Label elements Labelling according to Regulation (EC). 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) Danger GHS07 GHS08 4,4'-diphenylmethanediisocyanate, isomeres and homologues; 4,4'-methylenediphenyl diisocyanate, diphenylmethane-4,4'-diisocyanate H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. P260 - Do not breathe vapours. P280 - Wear eye protection, protective clothing, protective gloves. P285 - In case of inadequate ventilation wear respiratory protection. P302+P352 - IF ON SKIN: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P342+P311 - If experiencing respiratory symptoms: Call a doctor, a POISON CENTER Other hazards Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. SECTION 3: Composition/information on ingredients 3.1. Substances t applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC). 1272/2008 [CLP] 4,4'-diphenylmethanediisocyanate, isomeres and homologues (CAS-.) < 100 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H373 4,4'-methylenediphenyl diisocyanate, diphenylmethane-4,4'- diisocyanate (CAS-.) (EC-.) (EC Index-.) Carc. 2, H351 Acute Tox. 4 (Inhalation), H332 STOT RE 2, H373 Eye Irrit. 2, H EN (English) 12/19

13 CFS-F FX, B / CP 660, B Specific concentration limits: STOT SE 3, H335 Skin Irrit. 2, H315 Resp. Sens. 1, H334 Skin Sens. 1, H317 Name Product identifier Specific concentration limits 4,4'-diphenylmethanediisocyanate, isomeres and homologues (CAS-.) (C >= 0,1) Resp. Sens. 1, H334 (C >= 5) Skin Irrit. 2, H315 (C >= 5) Eye Irrit. 2, H319 (C >= 5) STOT SE 3, H335 4,4'-methylenediphenyl diisocyanate, diphenylmethane-4,4'- diisocyanate Full text of H-statements: see section 16 (CAS-.) (EC-.) (EC Index-.) (C >= 0,1) Resp. Sens. 1, H334 (C >= 5) STOT SE 3, H335 (C >= 5) Skin Irrit. 2, H315 (C >= 5) Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Irritation. May cause an allergic skin reaction. Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire Toxic fumes may be released. Carbon dioxide. Carbon monoxide Advice for firefighters Protection during firefighting Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures Ventilate spillage area. Do not breathe vapours. Avoid contact with skin and eyes EN (English) 13/19

14 CFS-F FX, B / CP 660, B For emergency responders Protective equipment Use personal protective equipment as required. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Take up liquid spill into absorbent material. Other information Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Do not handle until all safety precautions have been read and understood. Wear personal protective equipment. Do not eat, drink or smoke when using this product. Avoid contact with skin and eyes. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Store in a well-ventilated place. Keep cool. Storage temperature 5-25 C 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) Germany Local name pmdi(alsmdiberechnet) Germany TRGS 900 Occupational exposure limit value (mg/m³) 0,05 mg/m³ Germany Remark (TRGS 900) DFG,H,Sah,Y, Exposure controls Appropriate engineering controls Personal protective equipment Ensure good ventilation of the work station. Gloves. Protective clothing. Safety glasses. Hand protection Protective gloves. EN 374 Type Material Permeation Thickness (mm) Standard Disposable gloves Nitrile rubber (NBR) 3 (> 60 minutes) EN 374 Eye protection Chemical goggles or safety glasses. EN 166. EN 170 Type Use Characteristics Standard Safety glasses Droplet EN 166, EN EN (English) 14/19

15 CFS-F FX, B / CP 660, B Skin and body protection Respiratory protection Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment. t necessary with sufficient ventilation Device Filter type Condition Standard Filter AX (brown) Environmental exposure controls Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Colour amber. Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point t applicable Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) t applicable Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions EN (English) 15/19

16 CFS-F FX, B / CP 660, B Possibility of hazardous reactions dangerous reactions known under normal conditions of use Conditions to avoid ne under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Inhalation: Harmful if inhaled. ATE CLP (gases) ATE CLP (vapours) ATE CLP (dust,mist) 4500 ppmv/4h 11 mg/l/4h 1,5 mg/l/4h 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) LD50 oral rat > mg/kg (Rat, Literature study) LD50 dermal rabbit > 5000 mg/kg (Rabbit, Literature study) 4,4'-methylenediphenyl diisocyanate, diphenylmethane-4,4'-diisocyanate ( ) LD50 oral rat > 2000 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) LC50 other aquatic organisms 1 > 1000 mg/l (96 h, Literature study) Persistence and degradability EN (English) 16/19

17 CFS-F FX, B / CP 660, B 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) Persistence and degradability t readily biodegradable in water Bioaccumulative potential 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) BCF fish 1 1 (Pisces, Literature study) Log Pow 10,46 (Calculated, KOWWIN) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) Log Koc 9,078-10,597 (log Koc, SRC PCKOCWIN v2.0, Calculated value) Ecology - soil Adsorbs into the soil Results of PBT and vpvb assessment Component 4,4'-diphenylmethanediisocyanate, isomeres and homologues ( ) Other adverse effects This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Product/Packaging disposal recommendations European List of Waste (LoW) code Dispose of contents/container in accordance with licensed collector s sorting instructions. Dispose in a safe manner in accordance with local/national regulations * - waste isocyanates * - waste adhesives and sealants containing organic solvents or other dangerous substances SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN Other information supplementary information available ADR Regulatory status: IMDG Regulatory status: IATA Regulatory status: RID Regulatory status: ADR IMDG IATA RID UN number t regulated for transport UN proper shipping name t applicable t applicable t applicable t applicable Transport hazard class(es) t applicable t applicable t applicable t applicable t applicable t applicable t applicable t applicable Packing group t applicable t applicable t applicable t applicable EN (English) 17/19

18 CFS-F FX, B / CP 660, B ADR IMDG IATA RID Environmental hazards Dangerous for the environment : Dangerous for the environment : Marine pollutant : Dangerous for the environment : supplementary information available Dangerous for the environment : Special precautions for user - Overland transport - Transport by sea - Air transport - Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code t applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference Storage class (LGK) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) LGK 10 - Combustible liquids Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Chemical safety assessment chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: Composition/information on ingredients. Section Changed item Change Comments 2.1 Classification according Modified to Regulation (EC). 1272/2008 [CLP] 2.2 Hazard statements (CLP) Modified EN (English) 18/19

19 CFS-F FX, B / CP 660, B Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Resp. Sens. 1 Respiratory sensitisation, Category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT RE 2 Specific target organ toxicity Repeated exposure, Category 2 STOT SE 3 H315 H317 H319 H332 H334 H335 H351 H373 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Harmful if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. SDS_EU_Hilti This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 19/19