1875-A Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/30/2017
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1 SECTION 1: Identification 1.1. Identification Product form Date of issue: 04/30/2017 : Mixture Product name : Product code : Other means of identification 1.2. Recommended use and restrictions on use 1.3. Supplier Protective Industrial Polymers 7875 Bliss Parkway North Ridgeville, Ohio USA-Ohio T Emergency telephone number : /1, /5 Emergency number : Chemtrec: (Outside USA) SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 1 H315 H319 H317 H335 H372 Full text of H statements : see section 16 Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May cause respiratory irritation Causes damage to organs (Skin) through prolonged or repeated exposure (Dermal) 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation H372 - Causes damage to organs (Skin) through prolonged or repeated exposure (Dermal) : P260 - Do not breathe vapors P261 - Avoid breathing vapors P264 - Wash hands, forearms and face thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear protective clothing P302+P352 - If on skin: Wash with plenty of soap P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing 02/08/2018 EN (English US) Page 1
2 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures P312 - Call a doctor if symptoms persist. if you feel unwell P314 - Get medical advice/attention if you feel unwell P321 - Specific treatment (see Call a doctor if symptoms persist. on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P363 - Wash contaminated clothing before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to in accordance with local regulations Name Product identifier % GHS-US classification (Phenol, 4,4'-(1-methylethylidene)bis-, polymer with (chloromethyl)oxirane) (CAS No) ,3-Epoxypropyl neodecanoate (CAS No) Full text of hazard classes and H-statements : see section 16 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Skin Irrit. 2, H315 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor/physician if you feel unwell. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : May cause respiratory irritation. : Irritation. May cause an allergic skin reaction. : Eye irritation Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : Heating may cause a fire Special protective equipment and precautions for fire-fighters Protection during firefighting : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 02/08/2018 EN (English US) 2/7
3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Do not breathe vapors. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not breathe vapors. Use only outdoors or in a well-ventilated area. Avoid contact with skin and eyes. Wear personal protective equipment. : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. : No specific data. : No known incompatible materials. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment 02/08/2018 EN (English US) 3/7
4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Melting point Freezing point Boiling point : Liquid : light yellow : characteristic : Flash point : 230 F Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Specific gravity / density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity :. : 1.13 g/cm³ : Immiscible. The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat > 2000 mg/kg (Rat; OECD 420: Acute Oral toxicity Acute Toxic Class Method; Experimental value) LD50 dermal rat > 2000 mg/kg (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) 02/08/2018 EN (English US) 4/7
5 LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact SECTION 12: Ecological information Toxicity Ecology - general > 9600 mg/kg (Rat) > 3800 mg/kg (Rabbit) : Causes skin irritation. : Causes serious eye irritation. : May cause an allergic skin reaction. : May cause respiratory irritation. : Causes damage to organs (Skin) through prolonged or repeated exposure (Dermal). : May cause respiratory irritation. : Irritation. May cause an allergic skin reaction. : Eye irritation. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. LC50 fish mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Oncorhynchus mykiss; Semi-static system; Fresh water; Experimental value) EC50 Daphnia mg/l (EC50; Equivalent or similar to OECD 202; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) LC50 fish 2 EC50 Daphnia 2 Threshold limit algae 2 5 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Salmo gairdneri) 4.8 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna) 3.5 mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 96 h; Selenastrum capricornutum) Persistence and degradability Persistence and degradability Not readily biodegradable in water. Hydrolysis in water. Low potential for adsorption in soil. Persistence and degradability Inherently biodegradable. Not readily biodegradable in water. Biodegradability in soil: no data available. Adsorbs into the soil. Photolysis in the air Bioaccumulative potential BCF other aquatic organisms (BCF) Log Pow >= (Experimental value; EU Method A.8: Partition Coefficient; 25 C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Log Pow Bioaccumulative potential 4.4 (Experimental value) Bioaccumable Mobility in soil Surface tension ,20 C Log Koc log Koc,SRC PCKOCWIN v2.0; 2.65; QSAR Surface tension 0.03 N/m (25 C) 02/08/2018 EN (English US) 5/7
6 12.5. Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Proper Shipping Name (DOT) Other information : Not Regulated : No supplementary information available. TDG Proper Shipping Name (TDG) : Not Regulated Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations National regulations US State regulations SECTION 16: Other information 02/08/2018 EN (English US) 6/7
7 Full text of H-phrases: H315 H317 H319 H335 H372 H411 NFPA health hazard NFPA fire hazard NFPA reactivity Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation May cause respiratory irritation Causes damage to organs through prolonged or repeated exposure Toxic to aquatic life with long lasting effects : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical : 2 Moderate Hazard - Temporary or minor injury may occur : 1 Slight Hazard - Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 02/08/2018 EN (English US) 7/7
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