Material Safety Data Sheet according to 91/155/EEC - ISO

Transcription

1 Material Safety Data Sheet according to 91/155/EEC - ISO Page 1 of 6 OMNISEAL 1K PUR WHITE SDS no. : Revision: printing date: Identification of the substance/preparation and of the company/undertaking Trade name: OMNISEAL 1K PUR WHITE Intended use: 1-Component sealant Company name: Henkel Teroson GmbH Heidelberg Phone: Fax-no.: Emergency information: In case of an emergency information will be available 24h under phone +49-(0) Information office (content SDS): Product safety / TECO, Tel: +49-(0) Fax: +49-(0) Composition / information on ingredients General chemical description: 1-Component moisture-curing sealant Base substances of preparation: PUR polymer Declaration of ingredients: < 5 % Xylene - mixture of isomeres EINECS CAS R-phrases R10, R20/21, R38 < 1 % 4,4'- methylenediphenyl diisocyanate EINECS CAS R-phrases R20, R36/37/38, R42/43

2 MSDS-No.: OMNISEAL 1K PUR WHITE Page 2 of 6 < 15 % Isoparaffins C9-12 flash point > 55 C EINECS CAS R-phrases R65, R66 3. Hazards identification R42 May cause sensitization by inhalation. Persons suffering from allergic reactions to isocyanates should avoid contact with the product. 4. First-aid measures After inhalation: Fresh air, consult doctor if complaint persist. After skin contact: Rinse with running water and soap. Skin care. Change all contaminated clothing. After eye contact: First remove splashes carefully with eye swabs Wash with plenty of water immediately and continue for several minutes, holding eyelid open. Consult a doctor. After ingestion: Seek medical advice immediately and show this container or label. 5. Fire-fighting measures Suitable extinguishing media: All common extinguishing agents are suitable. Special protection equipment for fire-fighters: Wear self-contained breathing apparatus. Wear protective equipment. Hazardous combustion products: Isocyanate vapors 6. Accidental release measures Personal precautions: Avoid contact with skin and eyes. If vapors are generated, wear suitable respiratory equipment. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not empty into drains / surface water / ground water.

3 MSDS-No.: OMNISEAL 1K PUR WHITE Page 3 of 6 Process for cleaning and take-up: Neutralise any spillages with a mixture of alcohol, water and wetting agent, if necessary adding 1% ammonia relative to the isocyanate groups. 7. Handling and storage Handling: Ensure good ventilation/suction at the workplace. Avoid skin and eye contact. Storage: Store in sealed original container protected against moisture. Store in a cool, dry place. Container must be made airtight after use. Storage at 15 to 25 C is recommended. 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis Occupational Exposure Limits Ingredient ppm mg/m 3 Type Category Remarks 0,02 EU - Time Weighted 0,07 EU - Short Term Exposure Listed. xylene EU - Time Weighted xylene EU - Short Term Exposure xylene Skin designation: Can be absorbed through the skin. xylene EU - Time Weighted xylene EU - Short Term Exposure xylene Skin designation: Can be absorbed through the skin. xylene Listed.

4 MSDS-No.: OMNISEAL 1K PUR WHITE Page 4 of 6 Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear tightly fitting goggles. Body protection: suitable protective clothing General protection and hygiene measures: S.20/21 When using do not eat, drink or smoke. S.27 Take off immediately all contaminated clothes. Wash hands with soap and water on completion of work and before breaks. 9. Physical and chemical properties General characteristics State: Odor: Color(s): pasty of solvent white Phys./chem. properties: Density (20 C) Solubility (qualitative) (Solvent: water) Solubility (qualitative) (Solvent: water) Explosion limit lower [vol%] upper [vol%] 1,17 g/cm3 insoluble Reaction with water. 0,4 %(V) 7,6 %(V) 10. Stability and reactivity Conditions to avoid: Temperatures over appr. 250 C Avoid moisture. Materials to avoid: Reacts with water: Pressure built up in closed vessel (CO2).

5 MSDS-No.: OMNISEAL 1K PUR WHITE Page 5 of 6 Dangerous decomposition products: At higher temperatures isocyanate may be released. Carbon dioxide is generated under contact with moisture, leading to pressure in the cans. Danger of cans bursting! 11. Toxicological information General toxicological information: The present product is a chemical preparation within the meaning of the chemicals act. The following evaluation has been made on the basis of the toxicological data and content by weight of the individual ingredients. Persons suffering from allergic reactions to isocyanates should avoid contact with the product. Sensitizing: May cause sensitization by inhalation. 12. Ecological information General ecological information: Do not empty into drains, soil or bodies of water. 13. Disposal considerations Waste code(ewc): (after hardening) Product disposal: The valid EWC wast code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. Small amounts of cured or dried product residues can be disposed of as household waste or as industrial waste similar to household waste. Special waste incineration or special disposal with the approval of the responsible local authority. 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.

6 MSDS-No.: OMNISEAL 1K PUR WHITE Page 6 of Regulations - classification and identification Symbols of danger: Xn - Harmful Hazard trigger: Diphenylmethane diisocyanate 4,4'- R-phrases R42 May cause sensitization by inhalation. S-phrases : S23 Do not breathe vapour. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S28 After contact with skin, wash immediately with plenty of water. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Special declaration: Contains isocyanates. Observe manufacturer's instructions! National regulations/information: VOCV VOC regulation CH 6 % 16. Other information Full text of the R-phrases indicated by codes in this safety data sheet. The product code/identification/designation is indicated in Section 15. R10 Flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R38 Irritating to skin. R42/43 May cause sensitization by inhalation and skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.

7 Material Safety Data Sheet according to 91/155/EEC - ISO Page 1 of 5 OMNISEAL 1K PUR BLACK SDS no. : Revision: printing date: Identification of the substance/preparation and of the company/undertaking Trade name: OMNISEAL 1K PUR BLACK Intended use: 1-Component sealant Company name: Henkel Teroson GmbH Heidelberg Phone: Fax-no.: Emergency information: In case of an emergency information will be available 24h under phone +49-(0) Information office (content SDS): Product safety / TECO, Tel: +49-(0) Fax: +49-(0) Composition / information on ingredients General chemical description: 1-Component moisture-curing sealant Base substances of preparation: PUR polymer Declaration of ingredients: < 5 % Xylene - mixture of isomeres EINECS CAS R-phrases R10, R20/21, R38 < 1 % 4,4'- methylenediphenyl diisocyanate EINECS CAS R-phrases R20, R36/37/38, R42/43 < 15 % Isoparaffins C9-12 flash point > 55 C EINECS CAS R-phrases R65, R66 c:\wwi\graphics\logo_techn2.bmp } { error: grafic file not found:

8 MSDS-No.: OMNISEAL 1K PUR BLACK Page 2 of 5 3. Hazards identification R42 May cause sensitization by inhalation. Persons suffering from allergic reactions to isocyanates should avoid contact with the product. 4. First-aid measures After inhalation: Fresh air, consult doctor if complaint persist. After skin contact: Rinse with running water and soap. Skin care. Change all contaminated clothing. After eye contact: First remove splashes carefully with eye swabs Wash with plenty of water immediately and continue for several minutes, holding eyelid open. Consult a doctor. After ingestion: Seek medical advice immediately and show this container or label. 5. Fire-fighting measures Suitable extinguishing media: All common extinguishing agents are suitable. Special protection equipment for fire-fighters: Wear self-contained breathing apparatus. Wear protective equipment. Hazardous combustion products: Isocyanate vapors 6. Accidental release measures Personal precautions: Avoid contact with skin and eyes. If vapors are generated, wear suitable respiratory equipment. Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not empty into drains / surface water / ground water. Process for cleaning and take-up: Neutralise any spillages with a mixture of alcohol, water and wetting agent, if necessary adding 1% ammonia relative to the isocyanate groups. 7. Handling and storage Handling: Ensure good ventilation/suction at the workplace. Avoid skin and eye contact. Storage: Store in sealed original container protected against moisture. Store in a cool, dry place. Container must be made airtight after use. Storage at 15 to 25 C is recommended. c:\wwi\graphics\logo_techn2.bmp } { error: grafic file not found:

9 MSDS-No.: OMNISEAL 1K PUR BLACK Page 3 of 5 8. Exposure controls / personal protection Components with specific control parameters for workplace: Valid for Great Britain Basis Occupational Exposure Limits Ingredient ppm mg/m 3 Type Category Remarks 0,02 EU - Time Weighted 0,07 EU - Short Term Exposure Listed. xylene EU - Time Weighted xylene EU - Short Term Exposure xylene Skin designation: Can be absorbed through the skin. xylene EU - Time Weighted xylene EU - Short Term Exposure xylene Skin designation: Can be absorbed through the skin. xylene Listed. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): Isobutylene-isoprene rubber (IIR; >= 0.7 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Wear tightly fitting goggles. Body protection: suitable protective clothing General protection and hygiene measures: S.20/21 When using do not eat, drink or smoke. S.27 Take off immediately all contaminated clothes. Wash hands with soap and water on completion of work and before breaks. 9. Physical and chemical properties General characteristics State: Odor: Color(s): pasty of solvent black Phys./chem. properties: Density (20 C) Solubility (qualitative) (Solvent: water) 1,17 g/cm3 insoluble c:\wwi\graphics\logo_techn2.bmp } { error: grafic file not found:

10 MSDS-No.: Solubility (qualitative) (Solvent: water) Explosion limit lower [vol%] upper [vol%] OMNISEAL 1K PUR BLACK Page 4 of 5 Reaction with water. 0,4 %(V) 7,6 %(V) 10. Stability and reactivity Conditions to avoid: Temperatures over appr. 250 C Avoid moisture. Materials to avoid: Reacts with water: Pressure built up in closed vessel (CO2). Dangerous decomposition products: At higher temperatures isocyanate may be released. Carbon dioxide is generated under contact with moisture, leading to pressure in the cans. Danger of cans bursting! 11. Toxicological information General toxicological information: The present product is a chemical preparation within the meaning of the chemicals act. The following evaluation has been made on the basis of the toxicological data and content by weight of the individual ingredients. Persons suffering from allergic reactions to isocyanates should avoid contact with the product. Sensitizing: May cause sensitization by inhalation. 12. Ecological information General ecological information: Do not empty into drains, soil or bodies of water. 13. Disposal considerations Waste code(ewc): (after hardening) Product disposal: The valid EWC wast code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. Small amounts of cured or dried product residues can be disposed of as household waste or as industrial waste similar to household waste. Special waste incineration or special disposal with the approval of the responsible local authority. 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. c:\wwi\graphics\logo_techn2.bmp } { error: grafic file not found:

11 MSDS-No.: OMNISEAL 1K PUR BLACK Page 5 of Regulations - classification and identification Symbols of danger: Xn - Harmful Hazard trigger: Diphenylmethane diisocyanate 4,4'- R-phrases R42 May cause sensitization by inhalation. S-phrases : S23 Do not breathe vapour. S28 After contact with skin, wash immediately with plenty of water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Special declaration: Contains isocyanates. Observe manufacturer's instructions! National regulations/information: VOCV VOC regulation CH 6 % 16. Other information Full text of the R-phrases indicated by codes in this safety data sheet. The product code/identification/designation is indicated in Section 15. R10 Flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R38 Irritating to skin. R42/43 May cause sensitization by inhalation and skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. c:\wwi\graphics\logo_techn2.bmp } { error: grafic file not found: