Section 1 Identification of the substance/preparation and the company

Transcription

1 Date: 31/01/2013 Donaghys INSEC 480 Page 1 of 6 Section 1 Identification of the substance/preparation and the company Product Name: Donaghys INSEC 480 Company: Donaghys Ltd. Address: 16 Sheffield Crescent PO Box Christchurch. Telephone Number: Manufacturer Product Code: Recommended Use: Emergency Contact: Broad-Spectrum Organophosphate Insecticide (National Poisons Centre). Section 2 Hazard Identification Classified as hazardous according to criteria in the Hazardous Substances Regulations 2001 EPA NZ Approval Code HSR Hazard Classes HSNO Classification N/A 3.1D Flammable liquid. 6.1C Acute toxicant. 6.1D Acutely toxic- Harmful. 6.4A Irritating to eye. N/A 6.1E (asp) Acutely toxic-aspiration hazard. N/A 6.3B Irritating to skin. 6.8B Reproductive/ Developmental toxicant. 6.9A Target organ systemic toxicant. 9.1A Aquatic ecotoxicant. 9.2B Soil ecotoxicant. 9.3A Vertebrate ecotoxicant. 9.4A Invertebrate ecotoxicant. Hazard Statements H227 Combustible liquid. H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H302 Harmful if swallowed. H304 May be fatal if swallowed. H305 May be harmful if swallowed and enters airways. H312 Harmful in contact with skin. H316 Causes mild skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H400/410 Very toxic to aquatic life with long lasting effects.

2 Date: 31/01/2013 Donaghys INSEC 480 Page 2 of 6 H422 H431 H441 Toxic to the soil environment. Very toxic to terrestrial vertebrates.. Very toxic to terrestrial invertebrates Prevention Statements (For more information refer to Section 7) P102 Keep out of reach of children. P103 Read the label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P260 Do not breathe dust/fume/gas/mist/vapour/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. Response Statements (For more information refer to Section 4) P101 If medical advice is needed, have product container or label at hand. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307+P311 IF EXPOSED: Call a POISON CENTER or doctor/ physician. P308+P313 If exposed or concerned: Get medical advice/attention. P311/312 Call a POISON CENTER or doctor/ physician if you feel unwell. P321 Specific First Aid- Refer to Section 4. P330 Rinse mouth. P331 Do NOT induce vomiting. PP332+P313 Is skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Refer to Section 5 for fire-fighting measures. P391 Collect spillage

3 Date: 31/01/2013 Donaghys INSEC 480 Page 3 of 6 Section 3 Composition Information Chemical Entity CAS No. Content Chlorpyrifos g/L Aromatic hydrocarbon solvents >500g/L Calcium alkyl aryl sulphonate <100g/L Section 4 First Aid Measures If Swallowed If in eyes If on skin If inhaled Do NOT induce vomiting. Rinse mouth thoroughly. Seek medical advice immediately and show container or label or contact POISON CENTER. Make every effort to prevent vomit from entering the lungs by careful placement of the patient. Rinse eyes cautiously for 15 minutes. Remove contact lenses if present and easy to do so. Continue rinsing. If irritation persists get medical advice or attention. Remove and wash contaminated clothing. Wash affected areas thoroughly with soap and water. If skin irritation persists, get medical advice or attention. Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical advice. Advice to doctor Vomiting may cause pulmonary aspiration. The stomach should be emptied as soon as possible by careful gastric lavage (using a cuffed endotracheal tube already in place). Artificial respiration should be started at the first sign of respiratory failure. Cautious administration of fluids is advised, as well as general supportive and symptomatic pharmacological treatment and absolute rest. As early as possible, administer 2mg of Atropine sulphate i.v. and mg of Pralidoxime chloride or 250mg of Obidoxime chloride (adult dose) i.v. to patients suffering from severe respiratory difficulties, convulsions, and unconsciousness. Repeated doses of 2mg of Atropine sulphate should be given, as required, based on respiration, blood pressure, pulse frequency, salivation, and convulsion conditions. The dose and the frequency of Atropine varies with each patient, but the patient should remain fully atropinised (signs include dilated pupils, dry mouth, skin flushing). Diazepam should be given in all but mildest cases in doses of 10mg, s.c. or i. v., which may be repeated as required. For children, the doses are mg of Atropine/kg bodyweight, 250mg of Pralidoximechloride per child, or 4-8mg of Obidoxime chloride/kg bodyweight. Morphine, barbiturates, phenothiazine derivatives, tranquillizers, and all kinds of central stimulants are contraindicated.

4 Date: 31/01/2013 Donaghys INSEC 480 Page 4 of 6 Section 5 Fire-fighting Measures Flashpoint Combustion Products HAZCHEM Code Protective Equipment Extinguishing Media Location Certificate Fire Extinguishers >60 o C If involved in fire or exposed to extreme heat may evolve toxic and irritating fumes of hydrogen chloride or phosgene 2X Full protective clothing and self contained breathing apparatus Foam, fog, carbon dioxide or dry chemical Required REQUIRED. 2 for 500L or more, with 30Brating Spills and Disposal Protective Equipment Refer to Section 8. Environmental Precautions Section 6 Accidental Release Measures Contain spillage and absorb with clay, soil, sand or proprietary absorbent (such as vermiculite). Collect spilled material and waste in sealable containers for disposal. Dispose of at a landfill in accordance with local regulations. Avoid entry into waterways or streams. Prevent washings from entering waterways. Section 7 Handling and Storage Storage Handling Other information Tracking regulations Store locked up in a cool, well-ventilated place with container tightly closed. Do not store for prolonged periods in direct sunlight. Keep out of reach of children. Do not handle until all safety instructions have been read and understood. In case of inadequate ventilation wear respiratory protection. Contaminated work clothing should not be allowed out of the workplace. Avoid unintended release to the environment. This product must be under control of approved handler at all times. For more information see Regulations 4-6 Hazardous Substances (Personnel Qualifications) Regulations Required

5 Date: 31/01/2013 Donaghys INSEC 480 Page 5 of 6 Section 8 Exposure Controls/Personal Protection These precautions are suggested for conditions where the potential for exposure to the product exists. Emergency conditions may require additional precautions. Exposure Limits No exposure limits have been assigned for this product by OSHA. Handle in well ventilated areas, generally natural ventilation is adequate. Protective Equipment If exposure to vapour or spray is expected, a half face respirator with cartridge type A should be worn. When opening a container, preparing spray and using the prepared spray wear elbow-length PVC gloves and face shield or goggles, cotton overalls buttoned to the neck and wrist and washable hat. Wear impervious footwear such as plastic or rubber boots. Re-Entry period: Do not enter treated area until spray has dried. Hygiene Precautions Do not eat, drink or smoke when using this product. After using the product wash hands, arms and face thoroughly with soap and water. After each day s use, wash contaminated clothing and safety equipment. Engineering Controls Not applicable Section 9 Physical and Chemical Properties Appearance Brown liquid Specific Gravity ph N/A Flash Point >60 o C Solubility Emulsifiable with water Section 10 Stability and Reactivity Stability Conditions to Avoid Materials to Avoid Hazardous Decomposition Products Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Avoid direct sunlight. Avoid contact with oxidizing agents, strong acids or alkali/ alkaline materials. None. Section 11 Toxicological Information No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Oral LD50 Rat = mg/kg Inhalation LC50 Rat > 2.75 mg/l/4hrs (no death) Dermal Slight irritation, not a skin sensitizer Ocular Mild irritation Carcinogenicity Product has no known carcinogenic properties.

6 Date: 31/01/2013 Donaghys INSEC 480 Page 6 of 6 Section 12 - Ecological Information EPA Classification Ecotoxicity 9.1A, 9.2B, 9.3A, 9.4A. Very toxic to the aquatic environment. Section 13 Disposal Considerations Product Disposal When empty, triple rinse container and add residues to spray tank. Dispose of empty container at an approved landfill or other approved facility. Avoid contamination of any water supply with product or empty container. Do not re-use container. Section 14 Transport Information Proper Shipping Name Organophosphorous Pesticide, LIQUID, TOXIC (chlropyrifos 48%). UN Number DG Class 6.1. Subsidiary Risk Class N/A. Packing Group III. HAZCHEM Code 2XE. EPA NZ Registration Code HSR ACVM Approval Number P8369. Approved Handler Yes. Tracking required Yes. Section 15 Regulatory Information Section 16 Other Information The information in this SDS is provided in good faith, but no warranty, expressed or implied is made. For more information please contact Donaghys ltd. DONAGHYS NZ : DONAGHYS AUSTRALIA : POLICE, AMBULANCE & FIRE SERVICE : 111 NATION POISON INFORMATION CENTRE : 0800 POSION ( ) HAZARDOUS SUBSTANCES EMERGENCY : 0800 CHEMCALL ( )