: Stellite, ErCoCr-E (Solids)

Transcription

1 Date of issue:11/30/2015 Revision date: : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Stellite, ErCoCr-E (Solids) Type of product : Alloy 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture Function or use category : Professional use : For professional use only : Welding : Welding, cutting, heating and brazing Uses advised against 1.3. Details of the supplier of the safety data sheet The Prince & Izant Companies Plaza Drive Cleveland, Ohio - USA T F support@princeizant.com Emergency telephone number Emergency number : (CHEMTREC) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Sensitisation Respiratory, Category 1 H334 Sensitisation Skin, Category 1 H317 Hazardous to the aquatic environment Chronic Hazard, Category 4 H413 Full text of H statements : see section Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Danger : cobalt GHS08 : H317 - May cause an allergic skin reaction H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H413 - May cause long lasting harmful effects to aquatic life : P261 - Avoid breathing dust, fume P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P280 - Wear protective gloves, eye protection, face protection, protective clothing P284 - In case of inadequate ventilation wear respiratory protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P342+P311 - If experiencing respiratory symptoms: Call a doctor P362+P364 - Take off contaminated clothing and wash it before reuse P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 11/30/2015 EN (English) 1/7

2 Child-resistant fastening Tactile warning 2.3. Other hazards Adverse physicochemical, human health and environmental effects Other hazards not contributing to the classification : May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause long lasting harmful effects to aquatic life. ne under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] cobalt (CAS No) (EC no) (EC index no) Full text of H-statements: see section Resp. Sens. 1, H334 Skin Sens. 1, H317 Aquatic Chronic 4, H413 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a doctor. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. t expected to present a significant ingestion hazard under anticipated conditions of normal use. Rinse mouth. Do not induce vomiting. Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause allergy or asthma symptoms or breathing difficulties if inhaled. : May cause an allergic skin reaction. : Dust from this product may cause eye irritation. : May cause irritation to the respiratory tract and to other mucous membranes Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity in case of fire Hazardous decomposition products in case of fire : Dry powder. Use extinguishing media appropriate for surrounding fire. : The product is not flammable. : Product is not explosive. t known. : Toxic fumes may be released Advice for firefighters Precautionary measures fire Firefighting instructions Protection during firefighting special measures required. : Use extinguishing media appropriate for surrounding fire. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Avoid release to the environment. 11/30/2015 EN (English) 2/7

3 For non-emergency personnel Protective equipment Emergency procedures : Wear suitable protective clothing, gloves and eye or face protection. : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust, fume For emergency responders Protective equipment Emergency procedures : Do not attempt to take action without suitable protective equipment. Wear suitable protective clothing, gloves and eye or face protection. For further information refer to section 8: "Exposure controls/personal protection". Avoid contact with skin and eyes. Do not breathe Dust, Fumes. : Ventilate area Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections : Collect spillage. : Place in an appropriate container and dispose of the contaminated material at a licensed site. This material and its container must be disposed of in a safe way, and as per local legislation. : This material and its container must be disposed of as hazardous waste. For further information refer to section 8: "Exposure controls/personal protection". For disposal of solid materials or residues refer to section 13 : "Disposal considerations". SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible materials Storage area Packaging materials 7.3. Specific end use(s) Other hot work operations with metals. : Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust, fume. : Always wash hands after handling the product. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. : Ensure adequate ventilation, especially in confined areas. : Store in a well-ventilated place. Keep cool. : Acetylene, ammonia, ammonium nitrate, aqua regia, dioxane, ethylene oxide, chlorine trifluoride, halogens, hydrogen peroxide, hydrazine, hydrazine, mononitrate, hydrazoic acid, hydroxylamine, hydrogen sulfide, performic acid, phosphorus, selenium, sulfur, titanium plus potassium chlorate. Bromates, chlorates and iodates of alkali and alkali earth metals. : Store in a well-ventilated place. : Keep only in original container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection : Ensure good ventilation of the work station. : Gloves. Protective goggles. Face shield. Protective clothing. : Wear suitable protective clothing : Protective gloves : Wear tight fitting safety glasses or face shield : Wear suitable protective clothing : Combined gas/dust mask with filter type P3 Environmental exposure controls : Avoid release to the environment. 11/30/2015 EN (English) 3/7

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity : Solid : Silver-gray alloy. Metallic wire, rod, strip. : Silver. : odourless. n flammable : insoluble in water. : Product is not explosive. : Oxidising solids Not applicable. The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Acetylene, ammonia, ammonium nitrate, aqua regia, dioxane, ethylene oxide, chlorine trifluoride, halogens, hydrogen peroxide, hydrazine, hydrazine, mononitrate, hydrazoic acid, hydroxylamine, hydrogen sulfide, performic acid, phosphorus, selenium, sulfur, titanium plus potassium chlorate. Bromates, chlorates and iodates of alkali and alkali earth metals Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Contact dermatitis may result from direct exposure to the skin. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Long-term exposure to brazing fume, gasses, or dust may contribute to pulmonary irritation or pneumoconiosis. 11/30/2015 EN (English) 4/7

5 Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general Ecology - water : May cause long lasting harmful effects to aquatic life. : May cause long lasting harmful effects to aquatic life Persistence and degradability Stellite, ErCoCr-E (Solids) Persistence and degradability The product is not biodegradable Bioaccumulative potential Stellite, ErCoCr-E (Solids) Bioaccumulative potential Not established Mobility in soil Stellite, ErCoCr-E (Solids) Ecology - soil Not established Results of PBT and vpvb assessment Other adverse effects Other adverse effects Additional information ne known. : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Disposal must be done according to official regulations. : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Avoid release to the environment. Discharging into rivers and drains is forbidden. Dispose of contents/container to a hazardous or special waste collection point. : Avoid release to the environment UN number Not regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) 11/30/2015 EN (English) 5/7

6 ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Aquatic Chronic 4 Hazardous to the aquatic environment Chronic Hazard, Category 4 Resp. Sens. 1 Sensitisation Respiratory, Category 1 Skin Sens. 1 Sensitisation Skin, Category 1 H317 May cause an allergic skin reaction H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H413 May cause long lasting harmful effects to aquatic life SDS EU (REACH Annex II) 11/30/2015 EN (English) 6/7

7 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 11/30/2015 EN (English) 7/7