MATERIAL SAFETY DATA SHEET

Transcription

1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Identification of the substance/preparation Use of the preparation Synonym(s) Chemical family CAS # Company identification CH128A Inkjet printing. ColorSpan (3M 5481 Light Magenta Inkjet Ink) Acrylate/Polymer/Pigment Blend Mixture HP Philippines 37th Floor Robinsons Summit Center 6783 Ayala Avenue Makati City, Philippines Telephone (632) Hewlett-Packard health effects line (Toll-free within the US) (Direct) HP Customer Care Line (Toll-free within the US) (Direct) hpcustomerinquiries@hp.com 2. COMPOSITION/INFORMATION ON INGREDIENTS Component/substance CAS number % by weight EU number EU classification Isobornyl Acrylate Xi, R43 Isooctyl Acrylate Xi, R36/37/38, 50/53 Tetrahydrofurfuryl Acrylate Xi, R36/38 Amine Modified Acrylate Oligomer Unknown ,6-Hexanediol Diacrylate Xi, R43, 36/38 Acrylic Ester Unknown 1-5 Aliphatic Urethane Acrylate Unknown 1-10 Benzophenone N, R50/53 Diphenyl (2,4,6-trimethylbenzoyl) Xn, R52/53, 62 phospineoxide 3. HAZARDS IDENTIFICATION Classification Xi, N, R36/38, R43, R51/53 Acute health effects Skin contact Eye contact Inhalation Ingestion Potential health effects Routes of exposure Physical hazards Health hazards Environmental hazards Avoid contact with skin. Prolonged or repeated skin contact may cause skin irritation or allergic skin sensitization reaction. Irritating to eyes. Avoid breathing vapours or mists of this product. Inhalation of vapours or mists of the product may be irritating to the respiratory system. Ingestion is not expected to be a primary route of exposure for this product under normal use conditions. Harmful if swallowed. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Potential routes of exposure to this product are skin and eye contact, ingestion, and inhalation. Not classified as a physical hazard. Irritating to eyes and skin. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 1 / 5

2 4. FIRST AID MEASURES Inhalation Skin contact Eye contact Ingestion Move person to fresh air immediately. Call a physician if symptoms develop or persist. In case of contact, immediately remove contaminated clothing and flush skin with copious amounts of water. Wash clothing separately before reuse. Get medical attention. In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. Rinse mouth out with water. If swallowed, do NOT induce vomiting. Drink one to two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Flash point and method Fire fighting equipment/instructions Suitable extinguishing media Extinguishing media which must not be used for safety reasons Unusual fire & explosion hazards Hazardous combustion products Special protective equipment for fire-fighters > 93.3 C (> 200 F) closed cup; Move containers from fire area if you can do it without risk. Dry chemical, carbon dioxide. Water may be ineffective. Containers may explode when heated. Carbon monoxide and carbon dioxide. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Avoid contact with skin. Avoid inhalation of vapors or mists. Do not touch or walk through spilled material. Ensure adequate ventilation. Use personal protective equipment to minimize exposure to skin and eye. Do not flush into surface water or sanitary sewer system. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. 7. HANDLING AND STORAGE Handling Storage Avoid contact with skin, eyes and clothing. Avoid breathing vapours or mists of this product. Use with adequate ventilation. Wear personal protective equipment. Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat, sparks, and flame. Keep away from oxidizers. Keep out of the reach of children. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Eye protection Skin and body protection Do not breathe dust or spray mist. Provide adequate ventilation. A NIOSH- approved air purifying respirator with an organic vapour cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Wear safety glasses with side shields (or goggles) and a face shield. Eye wash fountain and emergency showers are recommended. Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant gloves. The use of nitrile-latex gloves is recommended. When material is heated, wear gloves to protect against thermal burns. 2 / 5

3 Hygiene measures Do not get this material in contact with skin. Avoid contact with skin, eyes and clothing. When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Launder contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Form Color Odor Odour threshold ph Boiling point Flash point Flammability Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Relative density Solubility (water) Partition coefficient (n-octanol/water) Viscosity Vapor density Evaporation rate Melting point Freezing point Auto-ignition temperature VOC Liquid. Light Magenta Acrylic. > 93.3 C (> 200 F) > 93.3 C (> 200 F) closed cup; 10 20C 1.04 g/cm³ Negligible < 95 g/l 10. STABILITY AND REACTIVITY Stability Conditions to avoid Hazardous decomposition products Hazardous polymerization Stable at normal conditions. Heat, flames and sparks. This product may react with oxidizing agents. Carbon monoxide and carbon dioxide. Hazardous polymerization can occur with decreased inhibitor content. 11. TOXICOLOGICAL INFORMATION Further information Complete toxicity data are not available for this specific formulation. 12. ECOLOGICAL INFORMATION Aquatic toxicity This product has not been tested for ecological effects. 13. DISPOSAL CONSIDERATIONS Disposal instructions Do not allow this material to drain into sewers/water supplies. Dispose of in compliance with federal, state, and local regulations. 3 / 5

4 14. TRANSPORT INFORMATION ADR IMDG IATA General not regulated 15. REGULATORY INFORMATION Labeling Contains Symbol(s) 1,6-Hexanediol Diacrylate, Acrylic Ester, Aliphatic Urethane Acrylate, Amine Modified Acrylate Oligomer, Benzophenone, Diphenyl (2,4,6-trimethylbenzoyl) phospineoxide, Isobornyl Acrylate, Isooctyl Acrylate, Tetrahydrofurfuryl Acrylate Xi N Irritant R-phrase(s) S-phrase(s) Dangerous for the environment R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. S57 Use appropriate container to avoid environmental contamination. S61 Avoid release to the Refer to special instructions/ Safety data sheets. 16. OTHER INFORMATION Manufacturer information List of relevant R phrases Disclaimer Issue date Hewlett-Packard K-Tel Drive Minnetonka, MN US Product Information R36/37/38 Irritating to eyes, respiratory system and skin. R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic R62 Possible risk of impaired fertility. This Safety Data Sheet document is provided without charge to customers of Hewlett-Packard Company. Data is the most current known to Hewlett-Packard Company at the time of preparation of this document and is believed to be accurate. It should not be construed as guaranteeing specific properties of the products as described or suitability for a particular application. This document was prepared to the requirements of the jurisdiction specified in Section 1 above and may not meet regulatory requirements in other countries. 4 / 5

5 Explanation of abbreviations ACGIH CAS CERCLA CFR COC DOT EPCRA IARC NIOSH NTP OSHA PEL RCRA REC REL SARA STEL TCLP TLV TSCA VOC American Conference of Governmental Industrial Hygienists Chemical Abstracts Service Comprehensive Environmental Response Compensation and Liability Act Code of Federal Regulations Cleveland Open Cup Department of Transportation Emergency Planning and Community Right-to-Know Act (aka SARA) International Agency for Research on Cancer National Institute for Occupational Safety and Health National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Resource Conservation and Recovery Act Recommended Recommended Exposure Limit Superfund Amendments and Reauthorization Act of 1986 Short-term exposure limit Toxicity Characteristics Leaching Procedure Threshold Limit Value Toxic Substances Control Act Volatile Organic Compounds 5 / 5