TECHNOMELT PUR 3460 MSDS-No. : V001.0 Revision: printing date:

Transcription

1 Safety Data Sheet Page 1 of 6 TECHNOMELT PUR 3460 MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: TECHNOMELT PUR 3460 Identification of manufacturer, importer or distributor Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, Kuala Lumpur, Malaysia. Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients General chemical description: 1-Component PU adhesive Declaration of ingredients: Cyclohexane, 5-isocyanato-1- (isocyanatomethyl)-1,3,3-trimethyl-, homopolymer o-(p-isocyanatobenzyl)phenyl isocyanate EINECS content Classification % carcinogenic, category 3; R40 Xn - Harmful; R20, R48/20 Xi - Irritant; R36/37/38 R42/43 0,1-1 % Xi - Irritant; R37, R ,1-1 % carcinogenic, category 3; R40 Xi - Irritant; R36/37/38 Xn - Harmful; R20, R48/20 R42/43 Section 3. Hazards identification Hazard classification: Risk phrases: Xn - Harmful R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. Section 4. First aid measures Inhalation: Fresh air, oxygen supply, warmth; seek specialist medical attention. Delayed effects possible after inhalation.

2 Skin contact: Eye contact: Ingestion: TECHNOMELT PUR 3460 Page 2 of 6 Molten product. After skin contact cool down immediately with cold water. Do not remove adherent product. Seek medical advice. Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. If necessary, see a dermatologist. After contact with the hot melt: cool with water, seek medical attention. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: All common extinguishing agents are suitable. Wear self-contained breathing apparatus. Wear protective equipment. In case of fire toxic gases can be released. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Wear protective equipment. Avoid contact with skin and eyes. Keep unprotected persons away. Do not empty into drains / surface water / ground water. Remove mechanically. Dispose of contaminated material as waste according to Chapter 13. Section 7. Handling and storage Handling: Storage: Always be careful around molten material. Avoid skin contact with molten resins. Follow suggested application temperature. Do not wear contact lenses. At elevated temperatures, irritating fumes may be emitted. Provide adequate ventilation. Wash hands before breaks and immediately after handling the product. Ensure good ventilation/extraction. Store in a cool place in closed original container. Keep away from heat and direct sunlight. Section 8. controls / personal protection Ingredient Type ppm mg/m 3 Remarks METHYLENE BISPHENYL ISOCYANATE (MDI) Time Weighted Average (TWA): 0,005 ACGIH METHYLENE BISPHENYL ISOCYANATE (MDI) Time Weighted Average (TWA): 0,005 0,051 MY OEL

3 Respiratory protection: Hand protection: TECHNOMELT PUR 3460 Page 3 of 6 Suitable breathing mask when there is inadequate ventilation. Wear refractive gloves while working with the hot melt. Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Goggles which can be tightly sealed. Protective clothing that covers arms and legs. Wear protective equipment. Use only in well ventilated areas. Draw off vapors and fumes directly at the point of generation or release. In the case of regular work use bench-mounted extraction equipment. Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. Section 9. Physical and chemical properties Appearance: Ivory solid, crystalline, solid material Odor: characteristic Specific gravity: 1,18 Flash point: No flash point up to 200 C (no method) Density: 1,13-1,23 g/cm3 Solubility: Solvent: Water, Insoluble Viscosity (dynamic) mpa.s (Brookfield; 130 C (266 F); speed of rotation: 10 min-1; Spindle No: 27; Method: ;; TIA- PD-PD/HM PA10-049; viscosity Brookfield (Purmelt)) VOC content (2004/42/EC) 0 % (VOCV VOC regulation CH) Section 10. Stability and reactivity Conditions to avoid: Materials to avoid: Stable under recommended storage conditions. None if used for intended purpose. Humidity Reaction with water, alcohols, amines. Reacts with water: Pressure built up in closed vessel (CO2). Hazardous decomposition products: At higher temperatures isocyanate may be released. Carbon dioxide is generated under contact with moisture, leading to pressure in the cans. Danger of cans bursting!

4 TECHNOMELT PUR 3460 Page 4 of 6 Section 11. Toxicological information General toxicological information: Persons suffering from allergic reactions to isocyanates should avoid contact with the product. Sensitizing: May cause sensitization by inhalation. May cause sensitization by skin contact. Acute toxicity: Cyclohexane, 5- isocyanato-1- (isocyanatomethyl)-1,3,3- trimethyl-, homopolymer type LD50 Acute toxicity estimate (ATE) LC50 > mg/kg 2,24 mg/l > 2,24 mg/l Route of application oral inhalation inhalation oralinhalationder mal Species rat rat Method Expert judgement OECD Guideline 403 (Acute Inhalation Toxicity) Skin corrosion/irritation: Result Species Method irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Respiratory or skin sensitization: sensitising sensitising Result Test type Species Method Buehler test guinea pig guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / with and without Species Method EU Method B.13/14 (Mutagenicity) Section 12. Ecological information General ecological information: Do not empty into drains, soil or bodies of water.

5 TECHNOMELT PUR 3460 Page 5 of 6 Toxicity: type Acute Toxicity Study Species Method LC0 > mg/l Fish 96 h Oryzias latipes OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 129,7 mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: Cyclohexane, 5-isocyanato-1- (isocyanatomethyl)-1,3,3- trimethyl-, homopolymer Result Route of application Degradability Method aerobic 0 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) aerobic 0 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) Bioaccumulative potential / Mobility in soil: o-(p-isocyanatobenzyl)phenyl isocyanate LogKow Bioconcentration factor (BCF) Species Temperature Method d Cyprinus carpio OECD Guideline 305 E (Bioaccumulation: Flowthrough Fish Test) 5,22 5,22 Section 13. Disposal considerations Product Method of disposal: Packaging Disposal for uncleaned package: In consultation with the responsible local authority, must be subjected to special treatment. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Section 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Xn - Harmful R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact.

6 Safety phrases: TECHNOMELT PUR 3460 Page 6 of 6 S22 Do not breathe dust. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Global inventory status: Regulatory list EINECS TSCA Notification yes yes Section 16. Other information Issue date: Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.