EN 1 EN. Detergents Ingredients Database. Part A. List of ingredients. Appendix I DID LIST
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1 Appendix I DID LIST For ingredients that are included in the part-a of DID list, the values for toxicity and degradability in the list must be used for the assessment of compliance with the ecological criteria. For ingredients that are not in the part-a of DID list, the procedure described in the part-b shall be used for establishing toxicity and degradability values. Part A. List of ingredients. Detergents Ingredients Database Version January 2007 Acute toxicity Chronic toxicity Degradation DIDno Ingredient name LC50/EC50 SF(acute) TF(acute) NOEC (*) SF (chronic) (*) TF (chronic) DF Aerobic Anaerobic Anionic surfactants 1 Linear alkyl benzene sulphonates 11,5-11,8 (LAS) 4, ,0041 0, ,069 0,05 R N 2 LAS (C10-13 alkyl) triethanolamine salt 4, ,0042 3, ,034 0,05 R O 3 C 14/17 Alkyl sulphonate 6, , , ,044 0,05 R N 4 C 8/10 Alkyl sulphate ,0264 0,0264 0,05 R Y EN 1 EN
2 5 C 12/14 Alkyl sulphate (AS) 2, , ,02 0,05 R Y 6 C 12/18 Alkyl sulphate (AS) (#) 0,0149 0,027 0,05 R Y 7 C 16/18 Fatty alcohol sulphate (FAS) ,027 1,7 50 0,034 0,05 R Y 8 C 12/15 A 1-3 EO sulphate 4, ,0046 0,1 10 0,01 0,05 R Y 9 C 16/18 A 3-4 EO sulphate 0, , , ,05 R Y 10 Dialkyl sulpho succinate 15, ,0157 0,0157 0,5 I N 11 C 12/14 Sulpho- fatty acid methylester ,0009 0, ,0046 0,05 R N 12 C 16/18 Sulpho- fatty acid methylester 0, , ,2 50 0,004 0,05 R N 13 C 14/16 alfa Olefin sulphonate 3, , , ,05 R N 14 C 14/18 alfa Olefin sulphonate 0, ,0001 0,0001 0,05 R N 15 Soap C> , ,1 0,05 R Y 16 Lauroyl Sarcosinate ,0056 0,0056 0,05 R Y 17 C9/ EO Carboxymethylated, sodium salt or acid ,01 0,01 0,05 R O 18 C12/ EO Carboxymethylated, sodium salt or acid 8,8 8, , ,05 0,05 R 19 C 12/18 Alkyl phosphate esters ,038 0,038 0,05 R Non-ionic surfactants 20 C8 A 1-5 EO 7, ,0078 0,0078 0,05 R Y 21 C 9/11 A, >3-6 EO predominantly linear 5, ,0056 0,0056 0,05 R Y EN 2 EN
3 22 C 9/11 A, >6-10 EO predominantly linear ,005 0,005 0,05 R Y 23 C 9/11 A, 5-11 EO multibranched ,001 0,001 0,05 R O 24 C10 A, 5-11 EO multibr.(trimer-propen-oxo-alcohol) ,01 0,01 0,05 R Y 25 C 12/15 A, 2-6 EO predominantly linear 0, , , ,0036 0,05 R Y 26 C12/ EO 1 t-buo (endcapped) 0, , , ,0018 0,05 R O 27 C 12/15 A, 3-12 EO multibranched ,001 3, ,032 0,05 R O 28 C 12/15 (mean value C<14) A, >6-9 EO 0, , , ,024 0,05 R Y 29 C 12/15 (mean value C>14) A, >6-9 EO 0, ,0004 0, ,017 0,05 R Y 30 C 12/15 A, >9-12 EO 1, ,0011 0,017 0,05 R Y 31 C 12/15 A >12-20 EO 0, ,0007 0,0007 0,05 R O 32 C 12/15 A >20-30 EO , ,1 0,05 R O 33 C 12/15 A, >30 EO ,13 0,13 0,5 I O 34 C 12/18 A, 0-3 EO 0, ,0003 0,0003 0,05 R Y 35 C 12/18 A, 5-10 EO ,001 0, ,0035 0,05 R O 36 C 12/18 A, >10-20 EO ,001 0,0035 0,05 R O 37 C 16/18 A, 2-8 EO 3, ,0032 0, ,004 0,05 R Y 38 C 16/18 A, >9-18 EO 0, , , ,032 0,05 R Y 39 C 16/18 A, EO 4, ,0041 0,0041 0,05 R Y 40 C 16/18 A, >30 EO ,03 0,03 0,5 I Y EN 3 EN
4 41 C12-15 A 2-6 EO 2-6 PO 0, , , ,0036 0,05 R O 42 C10-16 A 0-3 PO 6-7 EO 3, , ,01 0,05 R O 43 Glycerin (1-5 EO) cocoate ,016 6, ,063 0,05 R Y 44 Glycerin (6-17 EO) cocoate ,1 0,1 0,05 R Y 45 C 12/14 Glucose amide ,013 4,3 50 0,086 0,05 R Y 46 C 16/18 Glucose amide ,001 0, ,0066 0,05 R Y 47 C 8/10 Alkyl polyglycoside ,028 5, ,057 0,05 R Y 48 C8/12 Alkyl polyglycoside, branched , ,05 R N 49 C 8/16 or C12-14 Alkyl polyglycoside 5, , ,1 0,05 R Y 50 Coconut fatty acid monoethanolamide 9, , ,01 0,05 R Y 51 Coconut fatty acid monoethanolamide 4-5 EO ,0017 0,0017 0,05 R Y 52 Coconut fatty acid diethanolamide ,002 0, ,003 0,05 R O 53 PEG-4 Rapeseed amide ,007 0,007 0,05 R Y Amphoteric surfactants 60 C12/15 Alkyl dimethylbetaine 1, ,0017 0, ,001 0,05 R O EN 4 EN
5 61 Alkyl C12/18 amidopropylbetaine 1, ,0018 0, ,0009 0,05 R Y 62 C12/18 Alkyl amine oxide 0, ,0003 0,0003 0,05 R Y Cationic surfactants 70 Alkyl trimethyl ammonium salts 0, ,0001 0, , ,5 I O 71 Alkyl ester ammonium salts 2, , ,1 0,05 R Y Preservatives 80 1,2-Benzisothiazol-3-one 0, , , ,5 I N 81 Benzyl alcohol ,36 0,36 0,05 R Y 82 5-bromo-5-nitro-1,3-dioxane 0, , , P O 83 2-bromo-2-nitropropane-1,3-diol 0, , , ,002 0,5 I O 84 Chloroacetamide 55, , , O O 85 Diazolinidylurea ,007 0,007 1 P O 86 Formaldehyde ,002 0,002 0,05 R O 87 Glutaraldehyde 0, , , ,05 R O 88 Guanidine, hexamethylene-, homopolymer 0, , , , P O 89 CMI + MIT in mixture 3:1 ( ) 0, , , , ,5 I O EN 5 EN
6 90 2-Methyl-2H-isothiazol-3-one (MIT) 0, , , ,5 I O 91 Methyldibromoglutaronitrile 0, , , ,05 R O 92 e-phtaloimidoperoxyhexanoic acid 0, , , P O 93 Methyl-, Ethyl- and Propylparaben 15, , , ,05 R N 94 o-phenylphenol 0, , , ,05 R O 95 Sodium benzoate ,128 0,128 0,05 R Y 96 Sodium hydroxy methyl glycinate 36, ,0073 0, O O 97 Sodium Nitrite ,0087 0, NA NA 98 Triclosan 0, , , , ,5 I O 99 Phenoxy-ethanol , ,05 R O Other ingredients 110 Silicon ,25 0,25 1 P N 111 Paraffin ,1 0,1 1 P O 112 Glycerol ,88 0,88 0,05 R Y 113 Phosphate, as STPP ,15 NA NA 114 Zeolite (Insoluble Inorganic) ,5 1 NA NA 115 Citrate and citric acid , ,6 0,05 R Y EN 6 EN
7 116 Polycarboxylates , ,6 1 P N 117 Nitrilotriacetat (NTA) , ,28 0,05 R O 118 EDTA , ,44 0,5 I N 119 Phosphonates , ,5 1 P N 120 EDDS , ,64 0,05 R N 121 Clay (Insoluble Inorganic) NA NA 122 Carbonates ,25 0,25 0,15 NA NA 123 Fatty acids C>=14 3, , , ,05 R Y 124 Silicates ,25 0,25 1 NA NA 125 Polyasparaginic acid, Na-salt ,41 0,41 0,05 R N 126 Perborates (as Boron) ,014 0,014 1 NA NA 127 Percarbonate (See carbonate) ,25 0,25 0,15 NA NA 128 Tetraacetylethylenediamine (TAED) , ,05 R O 129 C1-C4 alcohols ,05 R Y 130 Mono-, di- and triethanol amine ,09 0, ,0078 0,05 R Y 131 Polyvinylpyrrolidon (PVP) ,5 I N 132 Carboxymethylcellulose (CMC) ,05 0,05 0,5 I N 133 Sodium and magnesium sulphate NA NA 134 Calcium- and sodiumchloride NA NA EN 7 EN
8 135 Urea ,2 0,2 1 NA NA 136 Silicon dioxide, quartz (Insoluble inorganic) NA NA 137 Polyethylene glycol, MW> ,1 0,1 1 P N 138 Polyethylene glycol, MW< ,1 0,1 0,05 R O 139 Cumene sulphonates ,45 0,45 0,5 I N 140 Na-/Mg-/KOH ,03 0,03 0,05 NA NA 141 Enzymes/proteins ,005 0,005 0,05 R Y 142 Perfume, if not other specified (**) ,002 0,002 0,5 I N 143 Dyes, if not other specified (**) ,01 0,01 1 P N 144 Starch ,1 0,1 0,05 R Y 145 Anionic polyester ,655 0,655 1 P N 146 PVNO/PVPI ,53 0,53 1 P N 147 Zn Ftalocyanin sulphonate 0, ,0002 0, , P N 148 Iminodisuccinat , ,17 0,05 R N 149 FWA , ,1 1 P N 150 FWA , ,1 1 P N decanol 2, , , ,05 R O 152 Methyl laurate ,136 0,136 0,05 R O 153 Formic acid (Ca salt) ,1 0,1 0,05 R Y EN 8 EN
9 154 Adipic acid ,031 0,031 0,05 R O 155 Maleic acid ,106 0,106 0,05 R Y 156 Malic acid ,106 0,106 0,05 R O 157 Tartaric acid ,02 0,02 0,05 R O 158 Phosphoric acid ,138 0,138 0,15 NA NA 159 Oxalic acid ,0256 0,0256 0,05 R O 160 Acetic acid ,03 0,03 0,05 R Y 161 Lactic acid ,13 0,13 0,05 R Y 162 Sulphamic acid ,075 0,075 1 NA NA 163 Salicylic acid ,046 0,046 0,15 R O 164 Glycollic acid ,0282 0,0282 0,05 R O 165 Glutaric acid ,0416 0,0416 0,05 R O 166 Malonic acid ,019 0,019 0,05 R O 167 Ethylene glycol ,5 6,5 0,05 R Y 168 Ethylene glycol monobutyl ether ,1494 0,1494 0,05 R O 169 Diethylene glycol ,44 0,44 0,05 R Y 170 Diethylene glycol monomethyl ether ,5 0,5 0,15 R O 171 Diethylene glycol monoethyl ether ,788 0,788 0,05 R O 172 Diethylene glycol monobutyl ether ,254 1,254 0,05 R O EN 9 EN
10 173 Diethylene glycol dimethylether ,2 0,2 0,5 I O 174 Propylene glycol ,15 R Y 175 Propylene glycol monomethyl ether ,54 2,54 0,05 R O 176 Propylene glycol monobutylether ,1496 0,1496 0,05 R O 177 Dipropylene glycol ,1625 0,1625 0,05 R O 178 Dipropylene glycol monomethyl ether ,3838 0,3838 0,05 R O 179 Dipropylene glycol monobutylether ,1682 0,1682 0,05 R O 180 Dipropylene glycol dimethylether ,2 0,2 0,5 I O 181 Triethylene glycol ,4 4,4 0,5 I O 182 Tall oil 1, ,0018 0,0018 0,5 I O 183 Ethylenebisstearamides ,028 0,028 0,5 I O 184 Sodium gluconate ,05 R O 185 Glycol distearate ,02 0,02 0,05 R Y 186 Hydroxyl ethyl cellulose ,0418 0, P O 187 Hydroxy propyl methyl cellulose ,0376 0, P O methyl-2-pyrrolidone ,5 0,5 0,05 R O 189 Xanthan gum ,49 0,49 0,05 R O 190 Trimethyl Pentanediol mono-isobutyrate ,018 3, ,033 0,05 R O 191 Benzotriazole ,029 0,029 1 P O EN 10 EN
11 192 Piperidinol-propanetricarboxylate salt , ,2 0,5 I O 193 Diethylaminopropyl-DAS , ,2 1 P O 194 Methylbenzamide-DAS , ,2 0,5 I O 195 Pentaerythritol-tetrakis-phenol-propionate ,038 0,038 1 P O 196 Block polymers (***) ,02 0,02 1 P N 197 Denatonium benzoate ,0026 0, O O 198 Succinate ,0374 0,0374 0,05 R O 199 Polyaspartic acid ,528 0,528 0,05 R N 200 Xylene Sulphonate , ,31 0,5 I N 201 Proteinhydrolizates, wheatgluten ,023 0,023 0,05 R O 202 Fatty acid, C 6-12 methyl ester ,0021 0,0021 0,05 R O 203 Mn-Saltren (CAS ) ,039 4, ,043 0,5 I O 204 Tri-Sodium methylglycine diacetat ,1 16,7 50 0,334 0,05 R O Insoluble inorganic Inorganic ingredient with very low, or no ability to dissolve in water. (*) If no acceptable chronic toxicity data was found, these columns are empty. In that case TF(chronic) is defined as equal to TF(acute) (**) As a general rule licence applicants must use the data on the list. Perfumes and dyes are exceptions. If toxicity data is submitted by the licence applicant the submitted data shall be used to calculate the TF and determine the degradability. If not, the values on the list shall be used. (***) The applicants data on aerobic degradability of DID no. 196 Block polymers will be accepted after presentation of test-report. EN 11 EN
12 (#) Due to a lack of toxicity results the TF has been calculated as an average of the values of C 12/14 Alkyl sulphate (AS) and C 16/18 Alkyl sulphate (AS). ( ) 5-Chloro-2-Methyl-4-isothiazolin-3-one and 2-Methyl-4-isothiazolin-3-one in mixture 3:1 List of abbreviations: SF(acute) Safety factor for acute toxicity. TF(acute) Toxicity factor based on acute toxicity on aquatic organisms. SF(chronic) Safety factor for chronic toxicity. TF(chronic) Toxicity factor based on chronic toxicity on aquatic organisms. DF Degradation factor Aerobic degradation: R Readily biodegradable according to OECD guidelines. I Inherently biodegradable according to OECD guidelines. P Persistent. The ingredient has failed the test for inherent biodegradability. O The ingredient has not been tested. NA Not applicable Anaerobic degradation: EN 12 EN
13 Y Biodegradable under anaerobic conditions. N Not biodegradable under anaerobic conditions. O The ingredient has not been tested. NA Not applicable EN 13 EN
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