Report No April A private report by the PROCESS ECONOMICS PROGRAM PARK, CALIFORNIA STANFORD RESEARCH INSTITUTE I

Transcription

1 Report No. 113 ORGANIC PHOSPHORUS COMPOUNDS by GRANT E. RUSSELL April 1977 A private report by the PROCESS ECONOMICS PROGRAM STANFORD RESEARCH INSTITUTE I MENLO PARK, CALIFORNIA

2 For detailed marketing data and information, the reader is referred to one of the SRI programs specializing in marketing research. The CHEMICAL ECONOMICS HANDBOOK Program covers most major chemicals and chemical products produced in the United States and the WORLD HYDROCARBONS Program covers major hydrocarbons and their derivatives on a worldwide basis. In addition, the SRI DIRECTORY OF CHEMICAL PRODUCERS services provide detailed lists of chemical producers by company, product, and plant for the United States and Western Europe. ii

3 CONTENTS 1 INTRODUCTION SUMMARY... Methyl Parathion Zinc Dialkyl Phosphorodithioates... Tris(nonylpheny1) Phosphite... 3 INDUSTRY STATUS Methyl Parathion Zinc Dialkyl Phosphorodithioates Tris(nonylpheny1) Phosphite (TNPP) Premises for Waste Treatment METHYL PARATHION... Chemistry... Review of Processes... Process Description... Process Discussion... Cost Estimates... 5 MALATHION... Chemistry... Review of Processes... Process Description... Process Discussion... Cost Estimates... 6 ZINC DIALKYL PHOSPHORODITHIOATE... Chemistry... Review of Processes... Process Description... Process Discussion... Cost Estimates... 7 TRIS(MIXED NONYLPHENYL) PHOSPHITE Chemistry... Review of Processes... Process Description... Process Discussion... Cost Estimates vii

4 CONTENTS APPENDIX A APPENDIX B APPENDIX C APPENDIX D APPENDIX E APPENDIX F APPENDIX G APPENDIX H APPENDIX I APPENDIX J DESIGN AND COST BASIS PHYSICAL PROPERTIES OF METHYL PARATHION TOXICITY AND HANDLING PRECAUTIONS FOR METHYL PARATHION PHYSICAL PROPERTIES OF MALATHION TOXICITY AND HANDLING PRECAUTIONS FOR MALATHION.. PHYSICAL PROPERTIES OF ZINC DIALKYL PHOSPHORODITHIOATES TOXICITY AND HANDLING PRECAUTIONS FOR ZINC DIALKYL PHOSPHORODITHIOATES PHYSICAL PROPERTIES OF TRIS(NONYLPHENYL) PHOSPHITE TOXICITY AND HANDLING PRECAUTIONS FOR TRIS(NONYLPHENYL) PHOSPHITE PHYSICAL PROPERTIES OF RAW MATERIALS AND INTERMEDIATES., CITED REFERENCES... PATENT REFERENCES BY COMPANY Vlll

5 ILLUSTRATIONS 4.1 Manufacture of Methyl Parathion Flow Diagram Manufacture of Methyl Parathion Effect of Plant Capacity on Total Fixed Capital Manufacture of Methyl Parathion Effect of Operating Level and Plant Capacity on Production Cost Manufacture of Flow Diagram Manufacture of Effect of Plant Capacity on Total Fixed Capital Manufacture of Effect of Operating Level and Plant Capacity on Production Cost Manufacture of Zinc Dialkyl Phosphorodithioate Flow Diagram Manufacture of Zinc Dialkyl Phosphorodithioate Effect of Plant Capacity on Total Fixed Capital Manufacture of Zinc Di(Isopropyl-Hexyl) Phosphorodithioate Effect of Operating Level and Plant Capacity on Production Cost Manufacture of Tris(Mixed Nonylphenyl) Phosphite Flow Diagram Manufacture of Tris(Mixed Nonylphenyl) Phosphite Effect of Plant Capacity on Total Fixed Capital Manufacture of Tris(Mixed Nonylphenyl) Phosphite Effect of Operating Level and Plant Capacity on Production Cost ix

6 TABLES 2.1 Manufacture of Methyl Parathion (80% Solution) Summary of Economics Manufacture of Summary of Economics Manufacture of Zinc Di(Isopropyl-Hexyl) Phosphorodithioate Summary of Economics Manufacture of Tris(Mixed Nonylphenyl) Phosphite Summary of Economics U.S. Production of Methyl Parathion U.S. Plant Capacities for Parathion and Methyl Parathion U.S. Production of Acyclic Organophosphorus Insecticides U.S. Production of Lubricating Oil Additives Manufacture of Methyl Parathion Patent Summary Chlorination of 0,0-Dialkylphosphorodithioic Acid Patent Summary Condensation of 0,0-Dialkyl Phosphorochloridothioate with Sodium p-nitrophenate Patent Summary Methyl Parathion Bases and Assumptions Methyl Parathion Major Equipment and Utilities Summary Methyl Parathion Stream Flows Methyl Parathion Summary of Waste Products Methyl Parathion Total Capital Investment Methyl Parathion Production Costs xi

7 TABLES Manufacture of Patent Summary Bases and Assumptions Major Equipment and Utilities Summary Stream Flows Summary of Waste Products Total Capital Investment Production Costs Manufacture of Zinc Dialkyl Phosphorodithioates Patent Summary Zinc Di(Isopropyl-Hexyl) Phosphorodithioate Bases and Assumptions Zinc Dialkyl Phosphorodithioate Major Equipment and Utilities Summary Zinc Di(Isopropyl-Hexyl) Phosphorodithioate Stream Flows.., Zinc Di(Isopropyl-Hexyl) Phosphorodithioate Summary of Waste Products., Zinc Dialkyl Phosphorodithioate Total Capital Investment Zinc Di(Isopropyl-Hexyl) Phosphorodithioate Production Cost Manufacture of TNPP and Similar Compounds Patent Summary Tris(Mixed Nonylphenyl) Phosphite Bases and Assumptions Tris(Mixed Nonylphenyl) Phosphite Major Equipment and Utilities Summary xii

8 TABLES 7.4 Tris(Mixed Nonylphenyl) Phosphite Stream Flows Tris(Mixed Nonylphenyl) Phosphite Summary of Waste Products Tris(Mixed Nonylphcnyl) Phosphite Total Capital Investment Tris(Mixed Nonylphenyl) Phosphite Production Cost xiii