SIGURNOSNI LIST Prema uredbama (EC) 1907/2006
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1 NESSLER-ov REAGENS B SIGURNOSNI LIST 1. Identifikacija supstance/priprema poduzeća ili firme 1.1. Identifikacija supstance ili priprema NESSLER-ov REAGENS B 1.2. Sinonimi: 1.3. Upotreba supstance/priprema: Za određivanje slobodnog amonijaka i amonijevih soli 1.4. Identifikacija kompanije ili firme: Semikem d.o.o. Sarajevo - Omladinska Vogošća-Sarajevo, Bi H Tel.: Fax.: web: info@semikem.ba 2. Identifikacija opasnosti Klasifikacija supstance/smjese Klasifikacijska regulativa (CE) nº 1272/2008. Korozija kože. 1B Piktogrami opasnosti Signalna riječ Opasno Izjava opasnosti H315 uzrokuje iritaciju kože. Mjere predostrožnosti P260 ne udisati prašinu/dim/gasove/paru P261 izbjeći udisanje prašine/pare/gasova/dima. P262 spriječiti kontakt s očima, kožom ili odjećom. P501 odložiti otpad u skladu sa Direktivom 94/62/CE or 2008/98/CE. klasifikacija (67/548/CEE or 1999/45/CE).
2 C korozivno R35 3. Sastav/informacije Za potpuni opis R-oznake vidjeti dio 16. Ime: Nesslerov Reagens B Natrij hidroksid pelete Formula: NaOH M.= 40,00 CAS [ ] EC broj (EINECS): EC broj indeksa: Sadržaj >= 0,1 % <= 1 % Klasifikacijska regulativa (CE) nº 1272/2008. Korozija kože 0,1A Piktogrami opasnosti Signalna riječ Opasno Izjava opasnosti H314 Izaziva teške opekotine na koži Precautionary statements
3 P260 ne udisati paru/dim/prašinu/prah/gas P264 temeljito oprati nakon korištenje. P280 Wear Zaštitna odjeća, rukavice i naočale P301+P330+P331 GUTANJE: oprati usta. Nei zazivati povraćanje. P303+P361+P353 KOŽA: Ukloniti odjeću odmah i oprati vodenim tušem. P501 odložiti otpad u skladu sa Directivom 94/62/CE or 2008/98/CE. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable UDISANJE: izvesti unesrećenog na svjež zrak P305+P351+P338 OČI: Oprati oprezno nekoliko minuta. Ukloniti kontakte leće, zatim ponovo isprati.. P310 Odmah pozvati medicinsku pomoć P321 Poseban tretman (vidjeti oznaku). P338 Ukloniti kontaktna sočiva.. P363 Oprati kontaminiranu odjeću prije ponovne upotrebe. P405 Držati zaključano Klasifikacija (67/548/CEE or 1999/45/CE). C Korozivno R35 Izaziva teške opekotine. 4.Prva pomoć 4.1 Generalna uputstva: Nikada ne piti ili izazivazi povraćanje u slučaju gubitka svijesti. 4.2 Inhalacija: Izaći na svjež vazduh ukoliko ne dođe do oporavka primijeniti vještačko disanje. Potražiti medicinsku pomoć. 4.3 Kontakt sa kožom: Isprati sa dosta vode.ukloniti kontaminiranu odjeću. 4.4 Oči: Isprati sa dosta vode(oko 15 minuta),držati oči otvorene.potražiti medicinsku pomoć. 4.5 Gutanje: Popiti mnogo vode. izavatii povraćnje.tražiti medicinsku pomoć. 5. Vatrogasni znaci 5.1. Prikladno sredstvo za gašenje požara: 5.2 Sredstvo protiv požara koje ne mora biti korišteno: 5.3 Specijalna opasnost Nezapaljivo.
4 5.4 Zaštitna oprema: 6. Mjere koje treba poduzeti u slučaju izlijevanja 6.1 Individualne mjere opreza Izbjeći kontakt s kožom očima i odjećom 6.2 Mjere opreza za zaposlene Obući zaštitnu i izbjeći doticaj sa vodoopskrbnim sistemom Metode za skupljanje/čišćenje 7. Rukovanje i čuvanje 7.1 Rukovanje Raditi u digestoru. 7.2 Čuvanje Skladištiti u zatvorenim spremnicima u atmosferskim uvjetima 8. Izloženost osoblja/zaštitne mjere 8.1 Tehničke zaštitne mjere 8.2 Kontrola izloženosti 8.3 Respiratorna zaštita Ukoliko dođe do oslobađanja gasova upotrijebiti respirator. 8.4 Zaštita ruku Koristiti odgovarajuće rukavice 8.5 Zaštita očiju Koristiti prikladne naočale 8.6 Individualne higijenske mjere Ukloniti kontaminiranu odjeću.koristiti prikladnu radnu odjeću. 8.7 Kontrola izloženosti okoliša Obezbjediti uslove propisane odgovarajućom legislativnom. 9. Fizičke i hemijske osobine Izgled: tečan Boja: bezbojan Granulometrija: Miris: odsutan ph: 13
5 Tačka topljenja/tačka mržnjenja: Početna tačka ključanja i rang ključanja: Temperature paljenja: Zapaljivost (tečnost,gas): Gornja /donja granica zapaljivosti ili eksplozivni limit: Pritisak pare: Gustoča pare: Relativna gustoća ~1,221 Rastvorljivost: rastvorljivo u vodi Koeficijent raspodjele: n-oktanol/voda Auto-paljenja temperature: Temperatura razgradnje: Viskozitet: 10.Stabilnost i reaktivnost 10.1 Uvjeti koje bi mogli izbjeći: 10.2 Materije koje bi mogli izbjeći: Metali. Laki metali. Amonijak. Formacije hidrogena 10.3 Opasnost od razgradnje produkata 10.4 Dodatne informacije: 11.Toksikološke informacije 11.1 Akutna toksičnost: LD L0 oral rbt : 500 mg/kg LD L0 oral rat : 273 mg/kg LD50 ipr mus : 40 mg/kg NaOH 11.2 Opasni efekti za zdravlje: Spojevi žive imaju toksičan efekat na ćelije in a protoplazmu. Simptomi akutnog trovanja živom: oštećenje tkiva (usta, jadenjak, želudac i crijeva), povraćanje s metalnim ukusom, opekline u digestivnom traktu, edemi pluća, aritmija, kolaps, problem s bubrezima. Infekcije bukalne sluznice, ispadanje zubi. Efekti na nervni system, halucinacije. Trdnicama nije dopušteno da budu u blizini supstance. Rizičan efekt na fetus. 12. Ekološke informacije 12.1 Mobilnost: 12.2 Ekotoksičnost EC50 test (mg/l): Bakteria (Photobacterium phosphoreum) 0,046 mg/l
6 Alge (Sc. cuadricauda) 0,07 mg/l Klasifikacija : Extr. toxic Alge (M. aeruginosa) 0,005 mg/l Ribe (Salmonidae) 0,05 mg/l Ribe (P. promelas) 0,19 mg/l Ribe (Leuciscus Idus) 0,013 mg/l Receptor medium: Rizik za vodeni okoliš Visok Rizik za kopneni okoliš Visok Observacije Ekotoksičnost zboj jona žive. Otrovno za okoliš 12.3 Razgradivost Test: klasifikacija biotičke degradacije: BOD5/COD Biodegradacija abiotička degradacija zavisi od ph: Observacije: 12.4 Akumulacija Rizik: Visok 12.5 Drugi mogući efekti na okolinu 13. Razmatranja u vezi eliminacije 13.1 Supstance ili preparati U Evropskoj Uniji nema utvrđenog homogenog standarda za eliminaciju hemijskog otpada, otpada posebne prirode,i tretman i eliminacija istog je stvar domaćeg zakodonodavstva u svakoj zemlji. U mnogim slučajevima možete kontaktirati komptentnog autora ili kompanije legalno autorizovane za eliminaciju otpada. 2001/573/EC: Odlukom vijeća 23. jula 2001 o izmjenama i dopunama provizije 2000/532/EC donijeta je lista otpada. Odlukom vijeća 91/156/EEC 18. marta 1991 o izmjenama i dopunama direktive 75/442/EEC otpada Kontaminirani kontejneri Kontaminirani kontejneri i pakovanje opasnih supstanci ili preparata mora biti tretirano na isti način kao kada je aktuelni produkt u njima. Evropski Parlament i Vijeće 91/689/EEC decembar 1994 pakovanje i pakovanje otpada. 14. Informacije o transportu
7 Drumski saobraćaj (ADR): Tehničko ime: KAUSTIČNA KOROZIVNA TEČNOST, NEORGANSKA N.O.S. UN 1719 Klasa: CONTAM. MAR PELIG.M.AMB Grupa pakovanja: II (/E) Morski saobraćaj (IMDG): Tehničko ime: KAUSTIČNA KOROZIVNA TEČNOST, NEORGANSKA N.O.S. UN 1719 Klasa: CONTAM. MAR PELIG.M.AMB Grupa pakovanja: II Vazdušni saobraćaj (ICAI-IATA): Tehničko ime: KAUSTIČNA KOROZIVNA TEČNOST, NEORGANSKA N.O.S. UN 1719 Klasa: CONTAM. MAR PELIG.M.AMB Grupa pakovanja: II Instrukcije za pakovanje: CAO 611 PAX Regulatorne informacije Druge mjere zaštite: P264 Oprati temeljito nakon korištenja. P270 Ne smije se jesti, piti, pušiti tokom upotrebe. P280 Zaštitna odjeća, rukavice i naočale. P281 Koristi ličnu radnu zaštitnu opremu.. P284 Nositi respiratornu zaštitu.. P301+P310 GUTANJE: Odmah pozvati medicinsku pomoć P301+P330+P331 GUTANJE: Oprati usta i ne izazivati povraćanje. P302+P352 KOŽA: Oprati s puno vode i sapuna. P303+P361+P353 KOŽA: Ukloniti kontaminiranu odjeću i oprati vodom.. P304+P340 UDISANJE: Izvesti unesrećenog na svjež zrak. P304+P341 UDISANJE: Ukoliko je disanje otežano izvesti unesrećenog na svjež zrak i namjestiti ga u komforan položaj za disanje. P305+P351+P338 OČI: Oprezno oprati vodom, ukloniti kontaktne leće i nastaviti sa ispiranjem.. P308+P313 ukoliko ste zabrinuti zbog izlaganja pozvati ljekara. P310 Odmah pozvati medicisnku pomoć. P312 Pozvati medicinsku pomoć ukoliko se ne osjećate dobro. P314 Pozvati ljekara ukoliko se ne osjećate dobro. P330 Oprati usta. P333+P313 Ukoliko se pojavi kožna iritacija ili svrab pozvati medicinskiu pomoć P363 Oprati kontam,iniranu odjeću prije ponovne upotrebe. P370+P378 U slučaju požara zvati vatrogasnu službu. P405 Držati zaključano Označavanje (65/548/CEE or 1999/45/CE) R-phrase(s): R35 izaziva opekotine S-phrase(s): S45 U slučaju tegobe odmah pozvati medicisnku pomoć
8 S36/37 Koristiti zaštitu. S28a Nakon dodira s kožom oprati s puno vode S13 Držati dalje od hrane i pića. S60 Ovaj materijal i njegov spremnik moraju biti odlagani kao opasan materijala Informacije uključene u ovaj sigurnosni list su bazirane na našem največem znanju, i isključivo su namjenjene za obavijest o svim aspektima sigurnosti,osobine i karakteristike navedene u ovom dokumentu nisu garantovane. U odnosu na prethodni pregled promjene su napravljene u sljedećim dijelovima: 2,3,15 Datum izdavanja: Z:\Ajlina C\REGISTRACIJA, APL, SL, AC DEZ MZ 2014\MZ grupe 2014\Pomoćni proiz.za industriju,zanatstvo i farmaciju\sigurnosni listovi po EC Pom.proizvodi za industriju,zanatstvo i farmaciju
: Antifreeze cooling liquid.
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