SECTION 1: Identification of the substance / mixture and of the company / undertaking

Transcription

1 Safety data sheet According to Regulation (EC) No. 1907/2006 (REACH) Date of issue: Supersedes edition of: --- SECTION 1: Identification of the substance / mixture and of the company / undertaking 1.1 Product identifier Product name: Grillrein 1.2 Relevant identified uses of the substance or mixture and uses advised against Basic cleaner 1.3 Details of the supplier of the safety data sheet Company: Industriestraße 20 D Allersberg Deutschland Tel info@oehme-lorito.de 1.4 Emergency telephone number Poison Control Center Nuremberg, Tel SECTION 2: Hazards identification 2.1 Classification of the substance or mixture C Corrosive R Label elements Labelling (67/548/EEC or 1999/45/EC) Symbol: C Corrosive. R-phrases: 35 Causes severe burns. S-phrases: 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible). Contains: Potassium hydroxide. 2.3 Other hazards Nor known. SECTION 3: Composition / information on ingredients Solution in water. Seite 1 von 8

2 Hazardous components Name according to EC-Directives: CAS-No. EC-No. EC-Index-No. Labelling according to EC-Directives Content Potassium hydroxide C >5 % R REACH Registration Number: Alcohols, C12-14, ethoxylated, sulfates, sodium salts Xi 10 <20 % R 36/38 REACH Registration Number: Full text of R-Phrases: see under section 16. SECTION 4: First aid measures 4.1 Description of first aid measures After inhalation: Fresh air. Call in physician if feeling unwell. After skin contact: Wash off with plenty of water. Swap with polyethylene glycol 400. Immediately remove contaminated clothing. Call a physician immediately. After eye contact: Rinse out with plenty of water with the eyelid held wide open. Call in ophthalmologist immediately. After swallowing: Make victim drink plenty of water (two glasses at most), avoid vomiting (risk of perforation). Immediately call in physician. Do not attempt to neutralise. 4.2 Most important symptoms and effects, both acute and delayed Irritation and corrosion, pain, collapse. Risk of corneal clouding. Drying-out effect resulting in rough and chapped skin. 4.3 Indication of any immediate medical attention and special treatment needed No information available. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media For this substance / mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Not Combustible. Development of hazardous combustion gases or vapours possible in the event of fire. Seite 2 von 8

3 5.3 Advice for firefighters Special protective equipment for firefighters Do not stay in dangerous zone without suitable chemical protection clothing and self-contained breathing apparatus. Further information Prevent fire-fighting water from entering surface water or groundwater. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Caution: Risk of slipping. Do not inhale vapours/aerosols. Avoid substance contact. Ensure supply of fresh air in enclosed rooms. 6.2 Environmental precautions Do not allow to enter sewerage system. 6.3 Methods and material for containment and cleaning up Take up with incombustible liquid-absorbent material. Forward for disposal. Clean up affected area. 6.4 Reference to other sections Indications about waste treatment see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Notes for prevention of fire and explosion Not required. Notes for safe handling Ensure adequate ventilation. Avoid contact with skin and eyes. Do not inhale vapours/aerosols. Avoid generation of vapours/aerosols. See section Conditions for safe storage, including any incompatibilities Store cool above 5 C. Keep away from sun and heat. Tightly closed in a well-ventilated place. 7.3 Specific end use(s) Apart fron the uses mentioned in section 1.2 no other specific uses alre stipulated. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Contains no substances with occupational limit values. Seite 3 von 8

4 8.2 Exposure controls Individual protection measures Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. Eye / face protection: Tightly fitting safety goggles (EN 166). Hand protection: Glove material: Nitrile rubber. Details on the penetration time have to be asked by the manufacturer. The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN 374. Respiratory protection: Required when vapours/aerosols are generated. Filter A2 P2 (EN 14387). Hygiene measures Change contaminated clothing. Apply skin- protective barrier cream. Wash hands and face after working with substance. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Form: liquid Colour: white Odour: characteristic ph value 14 Melting point not specified Boiling point not specified Ignition temperature not applicable Flash point not applicable Explosion limits lower not applicable upper not applicable Density (23 C) ~ 1.1 g/cm 3 Viscosity, dynamic not specified Solubility in water soluble 9.2 Other information None. SECTION 10: Stability and reactivity 10.1 Reactivity See section Chemical stability The product is chemically stable under standard ambient conditions (room temperature). Seite 4 von 8

5 10.3 Possibility of hazardous reactions Strong oxidizing agents, light metals, aluminium, strong acids Conditions to avoid No information available Incompatible materials Aluminium, light metals, various plastics Hazardous decomposition products See section 5. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute oral toxicity LD 50 rat: 1064 mg/kg (calculated; potassium hydroxide) Symptoms: If ingested, severe burns of the mouth, as well as a danger of perforation of the oesophagus and the stomach, pain, vomitting, shock, oedema, collapse, death. LD 50 rat: 4100 mg/kg (external MSDS; Fatty ether sulphate) Acute dermal toxicity LD 50 rat: >2000 mg/kg (external MSDS; Fatty ether sulphate) Acute inhalation toxicity Symptoms: Burns of mucous membranes, inhalation may lead to the formation of oedemas in the respiratory tract. Possible damages: Damage of the respiratory tract. Skin irritation Rabbit: Causes burns (IUCLID; potassium hydroxide, anhydrous). Drying-out effect resulting in rough and chapped skin. Necrosis. Mixture causes severe burns. Rabbit: No irritation (external MSDS; Fatty ether sulphate). Eye irritation Rabbit: Causes burns. Mixture causes serious eye damage (IUCLID; potassium hydroxide, anhydrous). Risk of corneal clouding. Risk of blindness! Necrosis. Rabbit: Eye irritation. (external MSDS; Fatty ether sulphate). Sensitisation Sensitisation test: Guinea pig: Negative (IUCLID; potassium hydroxide, anhydrous). Sensitisation test: Guinea pig: Negative (external MSDS; Fatty ether sulphate). Genotoxicity in vitro Ames test: Escherichia coli: Negative (IUCLID; potassium hydroxide, anhydrous). Specific target organ toxicity single exposure The substance or mixture is not classified as specific target organ toxicant, single exposure. Seite 5 von 8

6 Specific target organ toxicity repeated exposure The substance or mixture is not classified as specific target organ toxicant, repeated exposure. Aspiration hazard No aspiration toxicity classification Further information Further hazardous properties cannot be excluded. The product should be handled with the care usual when dealing with chemicals. SECTION 12: Ecological information 12.1 Toxicity Toxicity to fish Gambusia affinis LC 50 : 80 mg/l /96 h (IUCLID; potassium hydroxide, anhydrous) LC 50 : 7.1 mg/l /96 h (external MSDS; Fatty ether sulphate) Toxicity to daphnia an other aquatic invertebrates Daphnia magna: EC 50 : 7.2 mg/l /48 h (external MSDS; Fatty ether sulphate). Toxicity to algea EC 50 : 7.5 mg/l / 96h (external MSDS; Fatty ether sulphate) 12.2 Persistence and degradability Biodegradability The surfactants contained in this preparation complies with the Biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the member states and will be made available to them, at their direct request or at the request of a detergent manufacturer. Biodegradation: 100 % / 28 d (external MSDS; Fatty ether sulphate) Readily biodegradable (Fatty ether sulphate) 12.3 Bioaccumulative potential No information available Mobility in soil No information available Results of PBT and vpvb assessment PBT / vpvb assessment not available as chemical safety assessment not required / not conducted Other adverse effects Additional ecological information: Biological effects: Harmful effect due to ph-shift.caustic even in diluted form. Do not allow to enter waters, waste water, or soil! Seite 6 von 8

7 SECTION 13: Disposal considerations 13.1 Waste treatment methods Product: Chemicals must be disposed of in compliance with the respective national regulations. Code of the waste Name according to directive 2000/532/EC: * detergents containing dangerous substances * aqueous washing liquids and mother liquors. Packaging: Product packaging must be disposed of in compliance with the country-specific regulations or must be to a packaging return system. Code of the waste plastics. Name according to directive 2000/532/EC: SECTION 14: Transport information Road and rail, ADR/RID UN 1814 POTASSIUM HYDROXIDE SOLUTION, 8, II (E) Environmentally hazardous: No. Inland waterway, ADN Not tested. Sea, IMDG-Code UN 1814 POTASSIUM HYDROXIDE SOLUTION, 8, II EmS: F-A, S-B Marine pollutant: No. Air, IATA-DGR UN 1814 POTASSIUM HYDROXIDE SOLUTION, 8, II Environmentally hazardous: No. The transport regulations are cited according to international regulations and in the form applicable in Germany. Possible national deviations in other countries are not considered. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations / legislation specific for the substance or mixture EU regulations Ingredients according to Regulation (EC) on detergents No. 648/2004: Anionic surfactants: 5 % or over but less than 15 % 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out. Seite 7 von 8

8 SECTION 16: Other information Text of any R phrases referred to under section 2 and 3: 22 Harmful if swallowed. 35 Causes severe burns. 36/38 Irritating to eyes and skin. The information contained herein is based on the present state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product. Seite 8 von 8