MATERIAL SAFETY DATA SHEET

Transcription

1 Page: 1 of 12 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT INFORMATION Product Name: GM VehicleCare Lacquer Touch-Up Paint External Keys: TOUCH-UP Distributable Material (Part #) PAINT TOUCH-UP Primary Tradename - Distributable Material PAINT - 5 OZ AEROSOL MANUFACTURER INFORMATION Address: 101 PROSPECT AVENUE USA OHIO CLEVELAND MAILING N.W. Communication Lines: Phone EMERGENCY Phone Information Phone Information - Duplicolor Products Group Phone Information - Diversified Brands Phone Information - Krylon Products Group Phone Information - Consumer Group Industrial Manufacturer name change. Formerly manufactured by Dupli-Color Prod. Co. 2 INGREDIENT INFORMATION FORMULATION Ingredients: Chemical Name CAS Number Prefix Value Unit Limits ACETONE Range %Wt Yes PROPANE Range %Wt Yes BUTANE Range %Wt Yes TOLUENE = 12 %Wt Yes 2-BUTANONE = 14 %Wt Yes PROPIONIC ACID, 3-ETHOXY-, Range 7-8 %Wt No ETHYL ESTER TITANIUM OXIDE =< 4 %Wt Yes ACETIC ACID, ETHYL ESTER =< 3 %Wt Yes ISOPROPYL ALCOHOL =< 3 %Wt Yes TALC (powder), containing no =< 6 %Wt Yes asbestos fibers CARBONIC ACID, CALCIUM =< 2 %Wt Yes SALT (1:1) ACETIC ACID, BUTYL ESTER =< 1 %Wt Yes ALUMINUM OXIDE (2:3) =< 1 %Wt Yes ACETIC ACID, PROPYL ESTER =< 1 %Wt Yes CARBON BLACK =< 0.3 %Wt Yes ETHYL ALCOHOL =< 4 %Wt Yes COATED MICA =< 2 %Wt No 3 HAZARDS IDENTIFICATION Specific Hazards: ROUTES OF EXPOSURE: INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. Specific Hazards (Routes Of ): Routes Duration Observation Eye Contact General Irritation. Skin Contact General Prolonged or repeated exposure may cause irritation. Inhalation General Irritation of the upper respiratory system. May cause nervous system depression. Extreme overexposure

2 Page: 2 of 12 Routes Duration Observation may result in unconsciousness and possibly death. Effects Of Overexposure: SIGNS AND SYMPTOMS OF OVEREXPOSURE: Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and skin exposure. Medical Conditions Aggravated By : None generally recognized. Additional Health Hazard Data: OTHER PRECAUTIONS: Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. CHRONIC HEALTH EFFECTS: Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects liver, urinary, blood forming, cardiovascular systems. Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. 4 FIRST AID MEASURES First Aid By:: Inhalation If affected, remove from exposure. Restore breathing. Keep warm and quiet. Skin Contact SH AFFECTED AREA THROUGHLY WITH SOAP AND TER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. Eye Contact Flush eyes with large amounts of water for 15 minutes. Get medical attention. Ingestion Do not induce vomiting. Get medical attention immediately. 5 FIRE FIGHTING MEASURES Flash Point: < 0 F PROPELLANT Explosive Limits: Upper Explosive Limit = 19.0 (UEL) Lower Explosive Limit = 1.0 (LEL) Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam. Fire and Explosion Hazards: Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Special Fire Fighting Procedures: Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. 6 ACCIDENTAL RELEASE MEASURES SPILL OR LEAK PROCEDURES Recovery: Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. 7 HANDLING AND STORAGE HANDLING Safe Handling Procedures: Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Do not take internally. Keep out of the reach of children. Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. STORAGE Storage Conditions: STORAGE CATEGORY: Not available. Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120 F. Heat from sunlight, radiators, and other heat sources could cause container to burst. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Measures: Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , ,

3 Page: 3 of 12 EXPOSURE LIMITS : Chemical Name CAS Number Type Value Specificati on ACETONE PEL-T 1000ppm - OSHA - ACETONE GM ACETONE GM ACETONE TLV- ACETONE TLV- ACETONE State- ACETONE State- ACETONE State- ACETONE State- ACETONE State- ACETONE State- PROPANE PEL-T PROPANE GM PROPANE TLV- PROPANE State- PROPANE State- PROPANE State- BUTANE TLV- 500ppm - GM 750ppm - GM 500ppm - Threshold 750ppm - Threshold 750ppm - MICHIGAN 1000ppm - MICHIGAN 750ppm - NEW YORK 1000ppm - NEW YORK 750ppm - TENNESSEE 1000ppm - TENNESSEE 1000ppm - OSHA ppm - GM 1000ppm - Threshold 1000ppm - MICHIGAN 1000ppm - NEW YORK 1000ppm - TENNESSEE 1000ppm - Threshold TOLUENE PEL-T 200ppm - OSHA - Memo

4 Page: 4 of 12 Chemical Name CAS Number Type Value Specificati on TOLUENE PEL-C eiling TOLUENE GM TOLUENE TLV- TOLUENE State- TOLUENE State- TOLUENE State- TOLUENE State- TOLUENE State- TOLUENE State- 2-BUTANONE PEL-T 2-BUTANONE GM 2-BUTANONE GM 2-BUTANONE TLV- 2-BUTANONE TLV- 300ppm - OSHA - 50ppm - GM 50ppm - Threshold 100ppm - MICHIGAN 150ppm - MICHIGAN 100ppm - NEW YORK 150ppm - NEW YORK 100ppm - TENNESSEE 150ppm - TENNESSEE 200ppm - OSHA - 200ppm - GM 300ppm - GM 200ppm - Threshold 300ppm - Threshold 200ppm - MICHIGAN 2-BUTANONE State- 2-BUTANONE State- 300ppm - MICHIGAN 2-BUTANONE State- 200ppm - NEW YORK 2-BUTANONE State- 300ppm - NEW YORK 2-BUTANONE State- 200ppm - TENNESSEE 2-BUTANONE State- 300ppm - TENNESSEE Memo Skin Skin

5 Page: 5 of 12 Chemical Name CAS Number Type Value Specificati on TITANIUM OXIDE PEL-T 15mg/m3 - OSHA - TITANIUM OXIDE GM TITANIUM OXIDE TLV- TITANIUM OXIDE State- TITANIUM OXIDE State- TITANIUM OXIDE State- ACETIC ACID, ETHYL ESTER PEL-T ACETIC ACID, ETHYL ESTER GM ACETIC ACID, ETHYL ESTER TLV- ACETIC ACID, ETHYL ESTER State- ACETIC ACID, ETHYL ESTER State- ACETIC ACID, ETHYL ESTER State- ISOPROPYL ALCOHOL PEL-T ISOPROPYL ALCOHOL GM ISOPROPYL ALCOHOL GM ISOPROPYL ALCOHOL TLV- ISOPROPYL ALCOHOL TLV- 10mg/m3 - GM 10mg/m3 - Threshold 10mg/m3 - MICHIGAN 5mg/m3 - NEW YORK 10mg/m3 - TENNESSEE 400ppm - OSHA - 400ppm - GM 400ppm - Threshold 400ppm - MICHIGAN 400ppm - NEW YORK 400ppm - TENNESSEE 400ppm - OSHA - 200ppm - GM 400ppm - GM 200ppm - Threshold 400ppm - Threshold Memo

6 Page: 6 of 12 Chemical Name CAS Number Type Value Specificati on ISOPROPYL ALCOHOL State- 400ppm - MICHIGAN ISOPROPYL ALCOHOL State- 500ppm - MICHIGAN ISOPROPYL ALCOHOL State- 400ppm - NEW YORK ISOPROPYL ALCOHOL State- 500ppm - NEW YORK ISOPROPYL ALCOHOL State- 400ppm - TENNESSEE ISOPROPYL ALCOHOL State- 500ppm - TENNESSEE TALC (powder), containing no TLV- 2mg/m3 - Threshold asbestos fibers TALC (powder), containing no asbestos fibers CARBONIC ACID, CALCIUM SALT (1:1) CARBONIC ACID, CALCIUM SALT (1:1) GM TLV PEL-T ACETIC ACID, BUTYL ESTER PEL-T ACETIC ACID, BUTYL ESTER GM ACETIC ACID, BUTYL ESTER GM ACETIC ACID, BUTYL ESTER TLV- ACETIC ACID, BUTYL ESTER TLV- 2mg/m3 - GM 10mg/m3 - Threshold 15mg/m3 - OSHA - 150ppm - OSHA - 150ppm - GM 200ppm - GM 150ppm - Threshold 200ppm - Threshold ACETIC ACID, BUTYL ESTER State- 150ppm - MICHIGAN ACETIC ACID, BUTYL ESTER State- 200ppm - MICHIGAN ACETIC ACID, BUTYL ESTER State- 150ppm - NEW YORK ACETIC ACID, BUTYL ESTER State- 200ppm - NEW YORK ACETIC ACID, BUTYL ESTER State- 150ppm - TENNESSEE Memo

7 Page: 7 of 12 Chemical Name CAS Number Type Value Specificati on ACETIC ACID, BUTYL ESTER State- 200ppm - TENNESSEE ALUMINUM OXIDE (2:3) PEL-T 15mg/m3 - OSHA - ALUMINUM OXIDE (2:3) GM ALUMINUM OXIDE (2:3) TLV- ALUMINUM OXIDE (2:3) State- ALUMINUM OXIDE (2:3) State- ALUMINUM OXIDE (2:3) State- ACETIC ACID, PROPYL ESTER PEL-T ACETIC ACID, PROPYL ESTER GM ACETIC ACID, PROPYL ESTER GM ACETIC ACID, PROPYL ESTER TLV- ACETIC ACID, PROPYL ESTER TLV- ACETIC ACID, PROPYL ESTER State- ACETIC ACID, PROPYL ESTER State- ACETIC ACID, PROPYL ESTER State- ACETIC ACID, PROPYL ESTER State- ACETIC ACID, PROPYL ESTER State- ACETIC ACID, PROPYL ESTER State- CARBON BLACK PEL-T 10mg/m3 - GM 10mg/m3 - Threshold 10mg/m3 - MICHIGAN 10mg/m3 - NEW YORK 10mg/m3 - TENNESSEE 200ppm - OSHA - 200ppm - GM 250ppm - GM 200ppm - Threshold 250ppm - Threshold 200ppm - MICHIGAN 250ppm - MICHIGAN 200ppm - NEW YORK 250ppm - NEW YORK 200ppm - TENNESSEE 250ppm - TENNESSEE 3.5mg/m3 - OSHA - CARBON BLACK GM 3.5mg/m3 - GM Memo

8 Page: 8 of 12 Chemical Name CAS Number Type Value Specificati on CARBON BLACK TLV- CARBON BLACK State- CARBON BLACK State- CARBON BLACK State- ETHYL ALCOHOL PEL-T ETHYL ALCOHOL GM ETHYL ALCOHOL TLV- ETHYL ALCOHOL State- ETHYL ALCOHOL State- ETHYL ALCOHOL State- Additional : 3.5mg/m3 - Threshold 3.5mg/m3 - MICHIGAN 3.5mg/m3 - NEW YORK 3.5mg/m3 - TENNESSEE 1000ppm - OSHA ppm - GM 1000ppm - Threshold 1000ppm - MICHIGAN 1000ppm - NEW YORK 1000ppm - TENNESSEE Chemical Name CAS Number Prefix Value Unit Comme nt COATED MICA = 3 mg/m3 Resp. Dust. COATED MICA = 3 mg/m3 Resp. Dust. Memo Threshold Limit Values OSHA - Limits (PELs) These coatings may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are TLV 10 mg./m3 (total dust), 3 mg./m3 (respirable fraction), OSHA PEL 15 mg./m3 (total dust), 5 mg./m3 (respirable fraction). PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment (PPE): Eye Protection Wear safety spectacles with unperforated sideshields. Respiratory If personal exposure cannot be controlled below applicable Protection limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding, wirebrushing, abrading, burning or welding the dried film,

9 Page: 9 of 12 wear a particulate respirator approved by NIOSH/MSHA for protection against non-volatile materials in Section 2. Hand Protection None required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear chemical resistant gloves. Hygiene Measures: USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR. AVOID CONTACT WITH SKIN AND EYES. SH HANDS AFTER USING. PROTECT AGAINST DUST WHICH MAY BE GENERATED BY SANDING OR ABRADING THE DRIED FILM. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Physical State: Liquid. PHYSICAL PROPERTIES Changes of State: Boiling Point Range <0-342 F (< C) Melting/Freezing Point Not Vapor Pressure: = 760 mm. Propane ( ). = 760 mm. Butane ( ). = 22 mm. Toluene ( ). = 44 mm. Ethanol ( ). = 33 mm. 2-Propanol ( ). = 180 mm. Acetone ( ). = 70 mm. Methyl Ethyl Ketone ( ). = 86 mm. Ethyl Acetate ( ). = 23 mm. n-propyl Acetate ( ). = 1.11 mm. Ethyl 3-Ethoxypropionate ( ). = 10 mm. n-butyl Acetate ( ). Vapor Density: Heavier than air. Evaporation Rate: Faster than ether. Density: Density Range lb/gal ( g/l) Specific Gravity: Range Solubility: Water N/A VOC: Theoretical VOC (by. wt.) Range %Wt Less water and Federally Exempt Solvents. Total Amount Of:: Percent Volatile by Volume Range %Vol Additional Chemical and Physical Data: PHOTOCHEMICALLY No. REACTIVE: 10 STABILITY AND REACTIVITY STABILITY INFORMATION Stability Under Normal Conditions: Stable Conditions to Avoid: None known. Incompatible Materials: None known. Hazardous Polymerization: WILL NOT OCCUR. HAZARDOUS DECOMPOSITION Reactions:

10 Page: 10 of 12 Type of Reaction Reaction Products Decomposition By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metals in Section 2 11 TOXICOLOGICAL INFORMATION OCCUPATIONAL EXPERIENCES Experiences By Chemical: Chemical Name CAS Number Observation 2-BUTANONE Methyl Ethyl Ketone may increase the nervous system effects of other solvents. SCIENTIFIC OBSERVATIONS LETHAL LIMIT VALUES Data By Chemical: Chemical Name CAS Number Type Prefix Value Unit Species Comment PROPANE LC50 Not PROPANE LD50 Not BUTANE LC50 Not BUTANE LD50 Not TOLUENE LC50 = 4000 ppm TOLUENE LD50 = 5000 mg/kg ETHYL ALCOHOL LC50 Not ETHYL ALCOHOL LD50 = 7060 mg/kg ISOPROPYL LC50 Not ALCOHOL ISOPROPYL LD50 = 5045 mg/kg ALCOHOL ACETONE LC50 Not ACETONE LD50 = 5800 mg/kg 2-BUTANONE LC50 Not 2-BUTANONE LD50 = 2740 mg/kg ACETIC ACID, LC50 Not ETHYL ESTER ACETIC ACID, LD50 = 5600 mg/kg ETHYL ESTER ACETIC ACID, LC50 Not PROPYL ESTER ACETIC ACID, LD50 = 9370 mg/kg PROPYL ESTER PROPIONIC ACID, LC50 Not 3-ETHOXY-, ETHYL ESTER PROPIONIC ACID, LD50 = 5000 mg/kg 3-ETHOXY-, ETHYL ESTER ACETIC ACID, LC50 = 2000 ppm BUTYL ESTER ACETIC ACID, LD50 = mg/kg BUTYL ESTER ALUMINUM OXIDE LC50 Not (2:3) ALUMINUM OXIDE (2:3) LD50 Not

11 Page: 11 of 12 Chemical Name CAS Number Type Prefix Value Unit Species Comment TALC (powder), containing no asbestos fibers LC50 Not TALC (powder), containing no asbestos fibers CARBONIC ACID, CALCIUM SALT (1:1) CARBONIC ACID, CALCIUM SALT (1:1) LD50 Not LC50 Not LD50 Not TITANIUM OXIDE LC50 Not TITANIUM OXIDE LD50 Not CARBON BLACK LC50 Not CARBON BLACK LD50 Not CLASSIFICATION OF INGREDIENTS Carcingenicity: CHRONIC HEALTH HAZARDS: Carbon Black ( ) is classified by IARC as possibly carcinogenic to humans (group 2B) based upon experimental animal data, however, there is insufficient evidence in humans for its carcinogenicity. Rats exposed to titanium dioxide ( ) dust at 250 mg./m3 developed lung cancer, however, such exposure levels are not attainable in the workplace. CALIFORNIA PROPOSITION 65: RNING: These products contain chemicals known to the State of California to cause cancer. Reproductive Effects: CHRONIC HEALTH EFFECTS: Prolonged overexposure to solvent ingredients in Section 2 may cause adverse effects reproductive systems. CALIFORNIA PROPOSITION 65: RNING: These products contain chemicals known to the State of California to cause birth defects or other reproductive harm. 12 ECOLOGICAL INFORMATION ECOTOXICITY No data available. 13 DISPOSAL CONSIDERATIONS Waste Disposal Information: Waste from these products may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability and extractability to determine the applicable EPA hazardous waste numbers. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. 14 TRANSPORT INFORMATION DOT Information: LIMITED QUANTITY DOT Shipping Name: AEROSOLS DOT Hazard Class: 2.1 DOT UN Code: UN1950 Canada Land AEROSOLS, CLASS 2.1, UN1950, LIMITED QUANTITY.. Mexico Land AEROSOLS, 2.1, UN1950 International AEROSOLS, CLASS 2.1, UN1950, LIMITED QUANTITY. IATA AEROSOLS, FLAMMABLE, 2.1, UN1950, LIMITED QUANTITY. NOTE: Transport information may change depending upon container size. Exemptions and exceptions may apply. 15 REGULATORY INFORMATION LABELLING Hazard Codes: 4HR.

12 Page: 12 of 12 HMIS Health 2 HMIS Flammability 4 NFPA Flammability 4 NFPA Health 2 NFPA Reactivity 1 HMIS Reactivity 1 NFPA assigned by General Motors Technical Review. HMIS CODES: HEALTH 2*. NATIONAL REGULATIONS SARA 311/312: No SARA 313: Yes Immediate Health: No Delayed Health: No Fire: No Sudden Pressure Release: No Reactive: No Other Regulation: SARA 313 (40 CFR C) SUPPLIER NOTIFICATION TSCA CERTIFICATION Toluene ( ): max 12 % by wt. Methyl Ethyl Ketone ( ): max 14 % by wt. All chemicals in these products are listed, or are exempt from listing, on the TSCA Inventory. This document is provided to meet specific regulatory requirements. It contains additional composition information beyond that required by the OSHA Hazard Communication Standard (29 CFR ) and other regulatory regulations. STATE/LOCAL REGULATIONS CALIFORNIA PROPOSITION 65: RNING: These products contain chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. 16 OTHER INFORMATION Comments: ADDITIONAL EXPOSURE LIMITS: GM and State-'s were provided General Motors.