HENKEL LOCTITE CORPORATION 10/28/02 ROCKY HILL, CONNECTICUT EMERGENCY PHONE: (860) MATERIAL SAFETY DATA SHEET Page 01 of 06
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1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Type: Aerosol cleaner 2. COMPOSITION, INFORMATION ON INGREDIENTS MATERIAL SAFETY DATA SHEET Page 01 of 06 Ingredients CAS No. % XYLENES* ACETONE PROPANE ETHYL BENZENE* ISOPROPYL ALCOHOL METHYL ALCOHOL* * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) XYLENES 100 ppm TWA 100 ppm TWA None 434 mg/m3 435 mg/m3 ACETONE 500 ppm TWA 1000 ppm TWA None 1188 mg/m mg/m3 PROPANE 2500 ppm 1000 ppm None 1800 mg/m3 ETHYL BENZENE 100 ppm 100 ppm None 434 mg/m3 435 mg/m3 ISOPROPYL ALCOHOL 400 ppm TWA 400 ppm TWA 400 ppm TWA 983 mg/m3 980 mg/m3 DuPont AEL METHYL ALCOHOL 200ppm TWA skin 200ppm TWA skin None 262 mg/m3 skin 262 mg/m3 skin Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) XYLENES 150 ppm 150 ppm 651 mg/m3 655 mg/m3 ACETONE 750 ppm None 1782 mg/m3 PROPANE Asphyxiant Asphyxiant ETHYL BENZENE 125 ppm 125 ppm 543 mg/m3 545 mg/m3 ISOPROPYL ALCOHOL 500 ppm 500 ppm
2 MATERIAL SAFETY DATA SHEET Page 02 of COMPOSITION, INFORMATION ON INGREDIENTS (continued) 1230 mg/m mg/m3 METHYL ALCOHOL 250 ppm skin 250 ppm skin 328 mg/m3 skin 325 mg/m3 skin 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: Inhalation High concentrations may irritate nose, throat and lungs. Symptoms may include blurred vision, sore throat, dizziness, nausea, headache,central nervous system depression, fatigue, tremors, convulsions, drowsiness and incoordination. Eye Contact Direct spray or vapors will irritate and may cause pain tears, burns, sensitivity to light, swelling and possible corneal damage. Skin Contact May cause irritation, reddening, itching, pain and cracking due to defatting of skin. Ingestion Causes irritation, narcosis, and liver and kidney damage. Aspiration into lings may cause chemical pneumonia and ling damage. Inhalation, skincontact, eye contact. Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure. Preexisting disorders of the skin, eye, heart, kidney, liver, blood, respiratory system, neurological and hemopoletic organs. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA XYLENES CAR CNS IRR KID LIV NO NO NO ACETONE BLO CNS IRR NO NO NO PROPANE CAR CNS IRR NO NO NO ETHYL BENZENE CNS IRR NO 2B NO ISOPROPYL ALCOHOL ALG BLO CNS IRR KID NO N/A NO METHYL ALCOHOL EYE HRT IRR KID LIV MET NER REP NO NO NO
3 MATERIAL SAFETY DATA SHEET Page 03 of HAZARDS IDENTIFICATION (continued) Abbreviations N/A Not Applicable ALG Allergen CAR Cardiac EYE Eyes IRR Irritant LIV Liver NER Nervous System 2B Possibly carcinogenic to humans BLO Blood CNS Central nervous system HRT Heart KID Kidney MET Metabolic REP Reproductive 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Never give anything by mouth to an unconscious person. Do not induce vomiting. Give conscious patient several glasses of water. Seek medical attention. If affected, remove from exposure. Restore breathing by artificial respiration if necessary, Keep affected person warm and at rest. Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before reuse. Eye Contact: Flush eyes with large amounts of water for 15 minutes. Get medical attention. 5. FIRE FIGHTING MEASURES Flash Point: Recommended Extinguishing Agents: Special Firefighting Procedures: Less than 0 F (Propellant) Method: Tag closed cup Carbon dioxide, foam, dry chemical Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon. Unusual Fire or Explosion Hazards: Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition
4 MATERIAL SAFETY DATA SHEET Page 04 of FIRE FIGHTING MEASURES (continued) Explosive Limits: (% by volume in air)lower 1.0% (% by volume in air)upper 36.5% 6. ACCIDENTAL RELEASE MEASURES products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Steps to be taken in case of spill or leak: Remove all sources of ignition. Maintain good ventilation. Soak up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Keep away from heat, sparks, and open flame. (Contact Loctite Customer Service for shelf life information) Handling: Keep away from heat, sparks or open flame. Vapors will accumulate readily and ignite explosively. Use only with adequate ventilation. Avoid breathing vapors and spray mists. Avoid contact with skin and eyes. During use and until all vapors are gone: Keep area ventilated. Do not smoke. Extinguish all flames, pilot lights, and heaters. Turn off stoves, electric tools and appliances, and other sources of ignition. Consult NFPA Code. Use approved bonding and grounding procedures. Do not puncture, incinerate, or expose to temperature above 120 F. Heat from sunlight radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Wash hands after using. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Wear safety spectacles with unperforated sideshields. Rubber or plastic chemical resistant gloves. Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards , ,
5 MATERIAL SAFETY DATA SHEET Page 05 of EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) Respiratory If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic/particulate respirator approved by NIOSH/MSHA for protection against materials in Section PHYSICAL AND CHEMICAL PROPERTIES See Section 2 for Exposure Limits. Appearance: Clear liquid Odor: Aromatic Boiling Point: Range: Less than 0 F to 292 F ph: Does not apply Solubility in Water: Not available Specific Gravity 0.74 (Base only) Volatile Organic Compound (EPA Method 24) 75%; 555 grams per liter of material less exempt solvents Vapor Pressure: (Propellant) psig Vapor Density: More than 1 (base only) Evaporation Rate (Ether = 1) > Butyl Acetate 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS See Section 3. No data available Recommended methods of disposal: Incinerate liquid obtained by spray-emptying cans following EPA and local regulations. Do not puncture or incinerate pressurized cans.
6 MATERIAL SAFETY DATA SHEET Page 06 of DISPOSAL CONSIDERATIONS (continued) EPA Hazardous Waste Number D001 - Hazardous waste per 40CFR TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Aerosols, flammable Class or Division: Division 2.1 UN or ID Number: UN REGULATORY INFORMATION CA Proposition 65: No California Proposition 65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 3 Fire Hazard: 4 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 3* Flammability Hazard: 4 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Louis Fabrizio. Title: Regulatory Affairs Specialist Company: Henkel Loctite Corporation, Rocky Hill CT (24hr.) Phone: (860) Revision Date: March 14, 2002 Revision: 0006
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