HENKEL LOCTITE CORPORATION 10/28/02 ROCKY HILL, CONNECTICUT EMERGENCY PHONE: (860) MATERIAL SAFETY DATA SHEET Page 01 of 06
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1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL SAFETY DATA SHEET Page 01 of 06 Product Type: Aerosol Lubricant 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Mineral oil n-heptane BUTANE n-hexane* PROPANE NICKEL* Graphite Oxygenated aliphatic hydrocarbon Proprietary 1-5 Lithium soap ALUMINUM * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Mineral oil 5 mg/m3 mist 5 mg/m3 mist None n-heptane 400 ppm TWA 500 ppm TWA None 1640 mg/m mg/m3 BUTANE 800 ppm TWA 800 ppm TWA None 1900mg/M3 1900mg/M3 n-hexane 50 ppmtwa(skin) 500 ppm TWA None 1800 mg/m3 PROPANE 2500 ppm 1000 ppm None 1800 mg/m3 NICKEL 1.5mg/m3 TWA 1 mg/m3 TWA None inhalable fract Graphite 2 mg/m3 resp 15 mg/m3 total None 5 mg/m3 resp ALUMINUM 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir.
2 MATERIAL SAFETY DATA SHEET Page 02 of COMPOSITION, INFORMATION ON INGREDIENTS (continued) Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) Mineral oil 10 mg/m3 mist None n-heptane 500 ppm 500 ppm 2050 mg/m mg/m3 PROPANE Asphyxiant Asphyxiant 3. HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Existing Conditions Aggravated by Exposure: Inhalation of high concentrations of vapors may irritate nose and throat and cause symptoms of intoxication. Direct spray or vapors will irritate and may harm eyes. product may cause irritation due to defatting of skin upon skin contact. This material may be harmful or fatal if swallowed. Ingestion may result in vomiting. Aspiration of vomitus into lungs must be avoided as even small quantities may result in aspiration pneumonitis. Ingestion, inhalation, skin and eye contact. May cause skin or eye irritation, dermatitis, oil acne, or defatting of skin on prolonged or repeated contact. Inhalation may cause nausea, dizziness, irritation of nose and throat, watering of eyes. Ingestion may cause irritation, vomiting, diarrhea, nausea. Symptoms of intoxication include dizziness, nausea headache, indigestion. Skin and respiratory disorders. Graphite powder: emphysema, asthma. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Mineral oil IRR NO NO NO n-heptane CNS IRR NO NO NO BUTANE CAR CNS IRR LUN NO NO NO n-hexane DEV IRR LUN NER REP NO NO NO PROPANE CAR CNS IRR NO NO NO NICKEL ALG CAN IRR KID MUT REP RES YES 2B NO Graphite LUN NO NO NO Oxygenated aliphatic hydrocarbon No Data NO NO NO Lithium soap No Data NO NO NO ALUMINUM CNS IRR LUN NO NO NO
3 MATERIAL SAFETY DATA SHEET Page 03 of HAZARDS IDENTIFICATION (continued) Abbreviations 2B Possibly carcinogenic to humans CAN Human carcinogen CNS Central nervous system IRR Irritant LUN Lung NER Nervous System RES Respiratory ALG Allergen CAR Cardiac DEV Developmental KID Kidney MUT Mutagen REP Reproductive 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Do not induce vomiting. Keep individual calm. Drink water or milk. Obtain medical attention. Remove victim to fresh air. Apply artificial respiration if needed. Obtain medical attention. Remove contaminated clothing and wash skin with soap and water. Obtain medical attention if irritation persists. Eye Contact: Immediately flush eyes with water for at least 15 minutes. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: <100 F (Concentrate) Method: Tag Closed Cup -156 F (Propellant) Recommended Extinguishing Agents: Special Firefighting Procedures: Carbon dioxide, foam, dry chemical (B-C) Do not use water. Keep containers cool using water spray to avoid bursting. Use NIOSH approved self contained breathing apparatus and full protective gear. Hazardous Products formed by Fire or Thermal Decomp Metal vapors; oxides of carbon, barium, and zinc; smoke; fumes; hydrocarbons. Unusual Fire or Explosion Hazards: Explosive Limits: (% by volume in air)lower Propellant: 1.5% (% by volume in air)upper Propellant: 9.5% Contents under pressure. Exposure to temperatures above 120 F may cause container to burst.
4 MATERIAL SAFETY DATA SHEET Page 04 of ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Remove sources of ignition. Contain spill. Absorb spill with inert material, then place in a chemical waste container until disposal. 7. HANDLING AND STORAGE Safe Storage: Do not store near heat, sparks, or flame. Do not puncture or incinerate container. Exposure to temperatures above 120 F may cause container to burst. (Contact Loctite Customer Service for shelf life information) Handling: Keep away from eyes. Avoid skin contact. Avoid breathing of vapors. Use with adequate ventilation Keep out of reach of children. Do not use near heat, sparks, or flame. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Safety glasses or goggles. Chemical resistant plastic gloves. Sufficient to maintain vapor concnetration below TLV. NIOSH approved respitator if ventilation is inadequate. 9. PHYSICAL AND CHEMICAL PROPERTIES See Section 2 for Exposure Limits. Appearance: Grey spray Odor: Petroleum distillate Boiling Point: Not available ph: Does not apply Solubility in Water: Insoluble Specific Gravity Concentrate: 1.1 Volatile Organic Compound (EPA Method 24) Concentrate: 2.47%; 27 grams per liter Solvent: grams per liter Propellant: grams per liter Vapor Pressure: psig Vapor Density: Not available Evaporation Rate (Ether = 1) Not available
5 MATERIAL SAFETY DATA SHEET Page 05 of STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers Conditions to Avoid: Hazardous Decomposition Products (non-thermal): Do not use or store near fire, sparks, or flame. Do not puncture or incinerate container. Exposure to temperatures above 120 F may cause container to burst. None 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS See Section 3. No data available Recommended methods of disposal: EPA Hazardous Waste Number Contact disposal contractor licensed to handle flammable aerosols. D TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Aerosols, flammable Class or Division: Division 2.1 UN or ID Number: UN REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Nickel
6 MATERIAL SAFETY DATA SHEET Page 06 of OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 4 Reactivity Hazard: 0 Specific Hazard: No water Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 4 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Louis Fabrizio Title: Regulatory Affairs Specialist Company: Henkel Loctite Corporation, Rocky Hill CT (24hr.) Phone: (860) Revision Date: October 29, 1999 Revision: First Issue
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