Safety Data Sheet according to Regulation (EC) No 1907/2006 Page 1 of 10 Unibond One for All Crystal SDS No. : 536606 Revision: 20.11.2017 printing date: 05.03.2018 Replaces version from: 30.03.2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Unibond One for All Crystal 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Assembly adhesive, reaction 1.3. Details of the supplier of the safety data sheet Henkel Ltd Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: +44 (1442) 278000 Fax-no.: +44 (1442) 278071 ua-productsafety.uk@henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 0 8701 906777 - For further general health & safety, technical and practical advice on this product, please call +44 (0) 1606 593933 or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate; Winsford; Cheshire; CW7 3QY- Email: technical.services@henkel.co.uk 2.1. Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): The substance or mixture is not hazardous according to Regulation (EC) No 1272/2008 (CLP). 2.2. Label elements Label elements (CLP): The substance or mixture is not hazardous according to Regulation (EC) No 1272/2008 (CLP). Precautionary statement: P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. P262 Do not get in eyes, on skin, or on clothing. P271 Use only outdoors or in a well-ventilated area. 2.3. Other hazards Evolves methanol during cure. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria.
Unibond One for All Crystal Page 2 of 10 SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: 1-Component assembly adhesive Base substances of preparation: Reaction product of : Silane & Polyole Filler Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No. 220-449-8 01-2119513215-52 content Classification 1- < 5 % Flam. Liq. 3 H226 Acute Tox. 4; Inhalation H332 STOT RE 2; Inhalation H373 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. 4.1. Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. SECTION 4: First aid measures Skin contact: Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. Eye contact: Rinse immediately with plenty of running water, seek medical advice if necessary. Ingestion: Rinse mouth and throat. Drink 1-2 glasses of water. Seek medical advice. 4.2. Most important symptoms and effects, both acute and delayed No data available. 4.3. Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released.
Unibond One for All Crystal Page 3 of 10 5.3. Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Ensure adequate ventilation. Avoid contact with skin and eyes. 6.2. Environmental precautions Do not empty into drains / surface water / ground water. 6.3. Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Section 13. 6.4. Reference to other sections See advice in section 8 7.1. Precautions for safe handling Ensure that workrooms are adequately ventilated. Avoid skin and eye contact. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Store in sealed original container. Store in a cool, dry place. Temperatures between 0 C and + 30 C Do not store together with food or other consumables (coffee, tea, tobacco, etc.). 7.3. Specific end use(s) Assembly adhesive, reaction
Unibond One for All Crystal Page 4 of 10 SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 type Short term exposure limit category / Remarks Silane, dichlorodimethyl-, reaction products 2,4 Time Weighted Average with silica 68611-44-9 [SILICA, AMORPHOUS, RESPIRABLE DUST] Silane, dichlorodimethyl-, reaction products with silica 68611-44-9 [SILICA, AMORPHOUS, INHALABLE DUST] 6 Time Weighted Average 250 333 Short Term Limit (STEL): Skin designation: 200 266 Time Weighted Average 200 260 Time Weighted Average Can be absorbed through the skin. Indicative Regulatory list EH40 WEL EH40 WEL EH40 WEL EH40 WEL EH40 WEL ECTLV Occupational Limits Valid for Ireland Ingredient [Regulated substance] ppm mg/m 3 type Short term exposure limit category / Remarks Silane, dichlorodimethyl-, reaction products 6 Time Weighted Average with silica 68611-44-9 [SILICA, AMORPHOUS, TOTAL INHALABLE DUST] Silane, dichlorodimethyl-, reaction products with silica 68611-44-9 [SILICA, AMORPHOUS, RESPIRABLE DUST] 2,4 Time Weighted Average 200 260 Time Weighted Average Skin designation: 200 260 Time Weighted Average Indicative OELV Can be absorbed through the skin. Indicative Regulatory list IR_OEL IR_OEL IR_OEL IR_OEL ECTLV
Unibond One for All Crystal Page 5 of 10 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment period mg/l ppm mg/kg others aqua 0,36 mg/l (freshwater) aqua (marine 0,036 mg/l water) aqua 2,4 mg/l (intermittent releases) sewage 6,6 mg/l treatment plant (STP) sediment 1,3 mg/kg (freshwater) sediment 0,13 mg/kg (marine water) soil 0,055 mg/kg Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers dermal Long term Workers Inhalation Long term General dermal Acute/short term population General population General population General population General population Inhalation dermal Inhalation oral Acute/short term Long term Long term Long term Workers dermal Acute/short term Workers Inhalation Acute/short term Time 0,2 mg/kg 2,6 mg/m3 0,1 mg/kg 0,7 mg/m3 0,1 mg/kg 0,7 mg/m3 0,1 mg/kg 0,2 mg/kg 2,6 mg/m3 Remarks Biological Indices: None 8.2. controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Filter : AX (EN 14387) This recommendation should be matched to local conditions. Hand protection: Not needed.
Unibond One for All Crystal Page 6 of 10 Eye protection: Not needed. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste pasty transparent Odor alcohol-like Odour threshold ph Melting point Solidification temperature Initial boiling point Flash point Evaporation rate Flammability Explosive limits Vapour pressure Relative vapour density: Density (20 C (68 F)) Bulk density Solubility Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity (kinematic) Explosive properties Oxidising properties 109 C (228.2 F) 1,04 g/cm3 Insoluble 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity None if used for intended purpose. 10.2. Chemical stability Stable under recommended storage conditions. 10.3. Possibility of hazardous reactions See section reactivity 10.4. Conditions to avoid None if used for intended purpose. 10.5. Incompatible materials None if used properly. 10.6. Hazardous decomposition products Evolves methanol during cure.
Unibond One for All Crystal Page 7 of 10 11.1. Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Acute oral toxicity: type Route of application Species Method LD50 7.120 mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute inhalative toxicity: type Route of application Species Method LC50 16,8 mg/l vapour 4 h rat OECD Guideline 403 (Acute Inhalation Toxicity) Acute dermal toxicity: Route of Species Method type application LD50 3.540 mg/kg dermal rabbit not specified Skin corrosion/irritation: Result Species Method not irritating rabbit other guideline: Serious eye damage/irritation: Result Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: not sensitising Result Test type Species Method Guinea pig maximisat ion test guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g positive negative Ames test) in vitro mammalian chromosome aberration test mammalian cell gene mutation assay Metabolic activation / Species Method with and without OECD Guideline 471 (Bacterial Reverse Mutation with and without with and without Assay) OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) negative intraperitoneal mouse other guideline:
Unibond One for All Crystal Page 8 of 10 Reproductive toxicity: Hazardous substances Result / Classification Species NOAEL P = 250 mg/kg onegeneration study oral: gavage NOAEL P = 1.000 mg/kg NOAEL F1 = 1.000 mg/kg onegeneration study oral: gavage onegeneration study oral: gavage Species rat rat rat Method OECD Combined Repeated Dose and Reproductive / Developmental Toxicity Screening Test (Precursor Protocol of GL 422) OECD Combined Repeated Dose and Reproductive / Developmental Toxicity Screening Test (Precursor Protocol of GL 422) OECD Combined Repeated Dose and Reproductive / Developmental Toxicity Screening Test (Precursor Protocol of GL 422) Repeated dose toxicity Result NOAEL=< 62,5 mg/kg Route of application / Frequency of treatment Species Method oral: gavage daily rat OECD Guideline 422 (Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) inhalation: vapour 5 days/week for 14 weeks6 hours/day rat SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water. 12.1. Toxicity type Acute Toxicity Study Species Method LC50 191 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 100 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae 72 h OECD Guideline 201 (Alga, Growth Inhibition Test) EC 50 > 2.500 mg/l Bacteria 3 h OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test)
Unibond One for All Crystal Page 9 of 10 12.2. Persistence and degradability No data available. 12.3. Bioaccumulative potential / 12.4. Mobility in soil No data available. 12.5. Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. 12.6. Other adverse effects No data available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code 080410 SECTION 14: Transport information 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards 14.6. Special precautions for user 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code not applicable
Unibond One for All Crystal Page 10 of 10 SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 0,0 % (VOCV 814.018 VOC regulation CH) 15.2. Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H226 Flammable liquid and vapor. H332 Harmful if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.