Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 UniBond Repair Extreme Page 1 of 9 sds no. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier: UniBond Repair Extreme Relevant identified uses of the substance or mixture and uses advised against: Intended use: Reaction adhesives Details of the supplier of the safety data sheet: Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com Emergency Telephone Number: 24 Hours Emergency Tel: For further general health & safety, technical and practical advice on this product, please call +44 (0) or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate; Winsford; Cheshire; CW7 3QY- technical.services@henkel.co.uk Classification of the substance or mixture: Classification (DPD): No classification required. SECTION 2: Hazards identification Label elements (DPD): Safety phrases: S2 Keep out of the reach of children. Contains N-((Trimethoxysilyl)propyl)ethylenediamine. May produce an allergic reaction. Other hazards: Persons suffering from allergic reactions to amines should avoid contact with the product. General chemical description: 1-Component assembly adhesive Base substances of preparation: Trimethoxysilane SECTION 3: Composition/information on ingredients

2 UniBond Repair Extreme Page 2 of 9 Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No. content Classification < 0,2 % Acute toxicity 3; Oral H301 Flammable liquids 2 H225 Specific target organ toxicity - single exposure 1 H370 Acute toxicity 3; Inhalation H331 Acute toxicity 3; Dermal H311 Only dangerous ingredients for which a CLP classification is already available are displayed in this table. For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: (Trimethoxysilyl)propylamine Trimethoxyvinylsilane N-( (Trimethoxysilyl)propyl)ethylenediami ne Bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate EC Number content Classification REACH-Reg No < 5 % Xi - Irritant; R38, R < 10 % Xn - Harmful; R10, R < 1 % R52/53 Xn - Harmful; R20 Xi - Irritant; R41, R < 0,2 % T - Toxic; R23/24/25, R39/23/24/25 F - Highly flammable; R < 1 % Xi - Irritant; R36 N - Dangerous for the environment; R51/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. Description of first aid measures: General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. SECTION 4: First aid measures Skin contact: Wipe off affected skin area immediately with a soft cloth and then wash with running water and mild soap; apply skin care product. Eye contact: Rinse immediately with plenty of running water, seek medical advice from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Most important symptoms and effects, both acute and delayed: No data available. Indication of any immediate medical attention and special treatment needed: See section: Description of first aid measures

3 UniBond Repair Extreme Page 3 of 9 SECTION 5: Firefighting measures Extinguishing media: Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet Special hazards arising from the substance or mixture: In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. Advice for firefighters: Wear protective equipment. Wear self-contained breathing apparatus. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures: Avoid contact with skin and eyes. Ensure adequate ventilation. Wear protective equipment. Environmental precautions: Do not empty into drains / surface water / ground water. Methods and material for containment and cleaning up: Remove mechanically. Dispose of contaminated material as waste according to Chapter 13. Reference to other sections: See advice in chapter 8 Precautions for safe handling: Ensure that workrooms are adequately ventilated. Avoid skin and eye contact. See advice in chapter 8 Hygiene measures: Avoid skin and eye contact. Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. SECTION 7: Handling and storage Conditions for safe storage, including any incompatibilities: Store frost-free. Temperatures between + 5 C and + 35 C Do not store together with food or other consumables (coffee, tea, tobacco, etc.). Specific end use(s): Reaction adhesives

4 UniBond Repair Extreme Page 4 of 9 SECTION 8: controls/personal protection Control parameters: Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks Skin designation: Can be absorbed through the ECTLV skin Short Term EH40 WEL Limit (STEL): Skin designation: Can be absorbed through the EH40 WEL skin Time Weighted Average EH40 WEL (TWA): Time Weighted Average (TWA): Indicative ECTLV controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. When processing large amounts. Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation < 30s).Gloves should be replaced after each short contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. Eye protection: Protective goggles Skin protection: Suitable protective clothing SECTION 9: Physical and chemical properties Information on basic physical and chemical properties: Appearance liquid high viscosity colourless, clear Odor odorless ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity (Brookfield; 23 C (73.4 F)) Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits lower upper Partition coefficient: n-octanol/water Evaporation rate 74 C (165.2 F); no method 1,10 g/cm mpa.s 1,4 %(V) 50,0 %(V)

5 Vapor density Oxidising properties UniBond Repair Extreme Page 5 of 9 Other information: Reactivity: None if used for intended purpose. Chemical stability: Stable under recommended storage conditions. Possibility of hazardous reactions: See section reactivity Conditions to avoid: Avoid moisture. Incompatible materials: None if used properly. Hazardous decomposition products: None known SECTION 10: Stability and reactivity SECTION 11: Toxicological information General toxicological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Persons suffering from allergic reactions to amines should avoid contact with the product. Skin irritation: Primary skin irritation: slightly irritating, does not require labeling Eye irritation: Primary eye irritation: slightly irritating, does not require labeling Sensitizing: May cause sensitization by skin contact. Acute toxicity: Value type LD50 LC50 Value mg/kg 87,5 mg/l Route of application oral inhalation 6 h Species rat rat Method Skin corrosion/irritation: not irritating Result Species rabbit Method

6 UniBond Repair Extreme Page 6 of 9 Serious eye damage/irritation: (Trimethoxysilyl)propyla mine Result Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) not irritating rabbit Respiratory or skin sensitization: (Trimethoxysilyl)propyla mine not sensitising not sensitising Result Test type Species Method Guinea pig maximisat ion test Guinea pig maximisat ion test guinea pig guinea pig OECD Guideline 406 (Skin Sensitisation) Repeated dose toxicity Result Route of application / Frequency of treatment NOAEL=6,63 mg/l inhalation 4 weeks 6 h/d, 5 d/w rat Species SECTION 12: Ecological information Method General ecological information: The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water.

7 UniBond Repair Extreme Page 7 of 9 Toxicity: (Trimethoxysilyl)propylamine (Trimethoxysilyl)propylamine Trimethoxyvinylsilane Trimethoxyvinylsilane Trimethoxyvinylsilane Bis(2,2,6,6-tetramethyl-4- piperidyl) sebacate Bis(2,2,6,6-tetramethyl-4- piperidyl) sebacate Bis(2,2,6,6-tetramethyl-4- piperidyl) sebacate Value type Value Acute Toxicity Study Species Method LC mg/l Fish Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 100 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 100 mg/l Algae 72 h OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 > mg/l Fish 48 h Leuciscus idus EC50 > mg/l Daphnia 48 h Daphnia magna EC50 28,44 g/l Algae Chlorella pyrenoidosa OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 13 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 17 mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 1,9 mg/l Algae 72 h Scenedesmus sp. OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability: (Trimethoxysilyl)propylamine Bis(2,2,6,6-tetramethyl-4- piperidyl) sebacate Result Route of application Degradability Method aerobic 67 % OECD Guideline 301 A (new version) (Ready Biodegradability: DOC Die Away Test) readily biodegradable aerobic % EU Method C.4-E (Determination of the "Ready" BiodegradabilityClosed Bottle Test) aerobic 29 % OECD Guideline 301 E (Ready biodegradability: Modified OECD Screening Test) Bioaccumulative potential / Mobility in soil: N-( (Trimethoxysilyl)propyl)ethyl enediamine LogKow Bioconcentration factor (BCF) -1,67-0,77 Species Temperature Method SECTION 13: Disposal considerations Waste treatment methods:

8 UniBond Repair Extreme Page 8 of 9 Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances Road transport ADR: Railroad transport RID: Inland water transport ADN: Marine transport IMDG: Air transport IATA: SECTION 14: Transport information SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture: VOC content 0,11 % (VOCV VOC regulation CH)

9 UniBond Repair Extreme Page 9 of 9 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R36 Irritating to eyes. R38 Irritating to skin. R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H225 Highly flammable liquid and vapor. H301 Toxic if swallowed. H311 Toxic in contact with skin. H331 Toxic if inhaled. H370 Causes damage to organs. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.