Material Safety Data Sheet Goldstar Plus Positive Developer/USA 1. Chemical Product and Company Identification Common Name Goldstar Plus Positive Developer/USA MSDS# 223 Synonym Catalog number Area of Application 47 5913; 47 651; 38 82; 38 299; 846 149 Industrial applications. Graphic Arts Imaging. Version 2.54 Validation Date 211 Responsible Name Kodak Polychrome Graphics Supplier Kodak Polychrome Graphics 41 Merrit 7 Norwalk, CT 6851 USA Tel. (23) 8457 KPG# 441 Emergency telephone number In Case of Emergency (medical/roadside) (24hrs) CALL 184518346 For other EHS Information Kodak Polychrome Graphics, Environmental Solutions Department; 11465 Johns Creek Parkway, #26, Duluth, GA 397; USA Phone 18775747274 ext. 511, Additional phone (77) 2322133 Email PEP@kpgraphics.com, Fax (77) 232215; 2. Composition, Information on Ingredients Name CAS # % by Weight Exposure Limits 1) Water 7732185 995 2) Disodium metasilicate 683492 51 TWA 6 from MAK [Germany] Inhalation Respirable. 3) Phosphate ester, potassium salt 15 3. Hazards Identification Physical State and Appearance Emergency Overview Routes of Entry Liquid. DANGER! CAUSES EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. Mist or vapor causes eye, skin and respiratory irritation. Avoid contact with eyes, skin and clothing. Avoid breathing vapors or spray mists. Do not ingest. Wash thoroughly after handling. Absorbed through skin. Eye contact. Ingestion. Potential Acute Health Effects Eyes Hazardous in case of eye contact (irritant, corrosive). Skin Inhalation Ingestion Potential Chronic Health Effects Medical Conditions Aggravated by Overexposure Sensitization of the product Hazardous in case of skin contact (corrosive, irritant). Skin contact may produce burns. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Slightly hazardous in case of inhalation. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Overexposure by inhalation may cause respiratory irritation. May be fatal if swallowed. May cause burns to mouth, throat, and stomach. CARCINOGENIC EFFECTS MUTAGENIC EFFECTS TERATOGENIC EFFECTS Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. See Toxicological Information (section 11)
Goldstar Plus Positive Developer/USA Page 2/5 4. First Aid Measures Eye Contact Skin Contact Inhalation Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Seek medical attention. After contact with skin, wash immediately with plenty of water. Remove contaminated clothing immediately and wash with soap and water until no evidence of chemical remains. If irritation persists, seek medical attention. Allow the victim to rest in a wellventilated area. If irritation persists, seek medical attention. Ingestion Do not induce vomiting. Have conscious person drink several glasses of water or milk. Seek immediate medical attention. 5. Fire Fighting Measures Flammability of the Product AutoIgnition Temperature Hazardous thermal (de)composition products Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Explosion Hazards Nonflammable. None. Use DRY chemicals, CO2, water spray or foam. No special protection is required. Thermal decomposition may release toxic and/or hazardous gases. 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak 7. Handling and Storage Handling Storage Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary Neutralize the residue with a dilute solution of acetic acid. Do not touch spilled material. Absorb with DRY earth, sand or other noncombustible material. Neutralize the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Avoid contact with eyes, skin, and clothing. Do not ingest. Wash thoroughly after handling. Avoid breathing vapors or spray mists. Keep container tightly closed. Keep container in a cool, wellventilated area. Store between 5 to 25 C (41 to 77 F). 8. Exposure Controls, Personal Protection Engineering Controls Personal Protection Eyes Body Respiratory Use good general ventilation(>1 air changes/hour) and engineering controls (local exhaust, filter's, process enclosures if necessary) to maintain airborne levels below ACGIH Threshold Limit Values (TLV) and OSHA Permissible Exposure Limits(PEL). Ensure that eyewash station and safety shower is proximal to the workstation location. Face shield. Synthetic apron. Wear appropriate respirator when ventilation is inadequate.
Goldstar Plus Positive Developer/USA Page 3/5 Protective Clothing (Pictograms) Hands Feet Gloves (impervious). Personal Protection in Case of a Large Spill Product Name Face shield. Full suit. Gloves (impervious). Ventilation is normally required when handling or using this product. Exposure Limits 1) Water 2) Disodium metasilicate TWA 6 from MAK [Germany] Inhalation Respirable. 3) Phosphate ester, potassium salt Consult local authorities for acceptable exposure limits. 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Odorless. Molecular Weight Molecular Formula Color Orange. ph >13 [Basic.] Boiling/Condensation Point >1 C (212 F) Melting/Freezing Point < C (32 F) Specific Gravity 1.88 (Water = 1) Vapor Pressure 2.4 kpa (@ 2 C) Vapor Density.6 (Air = 1) Odor Threshold Evaporation Rate VOC by EPA Method 24 VOC Calculated g/l ( lbs/gal.). LogK ow Ionicity (in Water) Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. 1. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization The product is stable. Incompatible with some strong acids. None. Will not occur.
Goldstar Plus Positive Developer/USA Page 4/5 11. Toxicological Information Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Water ORAL (LD5) Acute >9 mg/kg [Rat]. Disodium metasilicate ORAL (LD5) Acute 1153 mg/kg [Rat]. Phosphate ester, potassium salt LD5 LC5 Hazardous in case of skin contact (corrosive, irritant), of eye contact (corrosive), of ingestion. Slightly hazardous in case of inhalation. 12. Ecological Information Biodegradable/OECD BOD5 and COD Ecotoxicity Bioaccumulative potential 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities. 14. Transport Information DOT Classification Class 8 Corrosive material Marine Pollutant Not designated as a marine pollutant by D.O.T. Special Provisions for Transport TDG Classification ADR/RID Classification IMO/IMDG Classification ICAO/IATA Classification Class 8 Corrosive material CLASS 8 Corrosive liquid. Slightly corrosive. CLASS 8 Corrosive liquid. CLASS 8 Corrosive liquid.
Goldstar Plus Positive Developer/USA Page 5/5 15. Regulatory Information HCS Classification U.S. Federal Regulations International Regulations WHMIS (Canada) CLASS Corrosive material TSCA 8(b) inventory Water; Disodium metasilicate; Phosphate ester, potassium salt SARA 32/34/311/312 extremely hazardous substances No products were found. SARA 32/34 emergency planning and notification No products were found. SARA 32/34/311/312 hazardous chemicals No products were found. SARA 311/312 MSDS distribution chemical inventory hazard identification Disodium metasilicate immediate health hazard SARA 313 toxic chemical notification and release reporting No products were found. Clean Water Act (CWA) 37 No products were found. Clean Water Act (CWA) 311 No products were found. Clean air act (CAA) 112 accidental release prevention No products were found. Clean air act (CAA) 112 regulated flammable substances No products were found. Clean air act (CAA) 112 regulated toxic substances No products were found. CLASS E Corrosive liquid. This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. DSCL (EEC) International Lists State Regulations CEPA DSL Water; Disodium metasilicate R36/38 Irritating to eyes and skin. WGK 1 No products were found. California prop. 65 No products were found. 16. Other Information Label Requirements CAUSES EYE AND SKIN BURNS. HARMFUL IF SWALLOWED. Mist or vapor causes eye, skin and respiratory irritation. Hazardous Material Information System (U.S.A.) Health Fire Hazard Reactivity Personal Protection 3 D National Fire Protection Association (U.S.A.) Health 2 Fire Hazard Reactivity Specific Hazard References Other Special Considerations Validated by Kodak Polychrome Graphics on 211. In Case of Emergency CALL 184518346 Verified by Kodak Polychrome Graphics. Printed 211. Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.