Date : January 19, 2017 SAMPLE IDENTIFICATION Internal code : 17A03-TOB24-1-DM Customer identification : Geranium - 07-2530-BP Type : Essential Oil Source : Pelargonium graveolens Customer : Serene Living ANALYSIS Method : PC-PA-001-15E06, "Analysis of the composition of a liquid essential oil by GC-FID" (in French). Analyst : Sylvain Mercier, M. Sc., chimiste Analysis date : 2017-01-18 Checked and approved by : Alexis St-Gelais, M. Sc., chimiste 2013-174 Note: This report may not be published, including online, without the written consent from Laboratoire PhytoChemia. This report is digitally signed, it is only considered valid if the digital signature is intact. Page 1 of 7
IDENTIFIED COMPOUNDS Identification Column: BP5 Column: WAX R.T. R.I. % % R.I. R.T. Molecular Class 3-Methylpentanol 2.39 861 0.04 0.04 1280 5.09 Aliphatic alcohol cis-hex-3-en-1-ol 2.51 871 0.03 0.03 1330 5.90 Aliphatic alcohol Heptanal 3.00 906 0.01 0.01 1136 3.02 Aliphatic aldehyde α-pinene 3.36 928 0.54 0.55 946 1.27 Monoterpene Geranic oxide 4.03 970 0.06 0.06 1058 2.08 Monoterp. ether β-pinene 4.13 977 0.02 0.02 1044 1.98 Monoterpene Myrcene 4.42 995 0.11 0.09 1117 2.76 Monoterpene 6-Methyl-5-hepten-2-one 4.51 1000 0.07 0.09 1281 5.11 Aliphatic ketone α-phellandrene 4.69* 1008 0.08 0.07 1110 2.67 Monoterpene Δ3-Carene 4.69* 1008 [0.08] 0.03 1096 2.47 Monoterpene α-terpinene 4.88 1018 0.01 0.01 1124 2.85 Monoterpene para-cymene 5.08 1028 0.07 0.09 1211 4.05 Monoterpene Limonene 5.10 1030 0.19 0.19 1142 3.09 Monoterpene β-phellandrene 5.14 1031 0.04 0.05 1149 3.18* Monoterpene 1,8-Cineole 5.17 1033 0.02 [0.05] 1149 3.18* Monoterp. ether cis-β-ocimene 5.29 1039 0.08 0.11 1189 3.71 Monoterpene trans-β-ocimene 5.47 1049 0.09 0.09 1203 3.93 Monoterpene γ-terpinene 5.66 1058 0.01 0.01 1194 3.79 Monoterpene cis-linalool oxide (fur.) 5.96 1074 0.28 0.28 1384 6.76 Monoterp. alcohol Terpinolene 6.13 1083 0.03 0.03 1225 4.26 Monoterpene trans-linalool oxide (fur.) 6.28 1091 0.16 0.16 1402 7.19 Monoterp. alcohol para-cymenene 6.36 1095 0.03 0.02 1372 6.56 Monoterpene 6,7-Epoxymyrcene 6.45 1099 0.02 0.01 1361 6.38 Monoterp. ether Linalool 6.73* 1109 6.93 6.06 1499 9.72* Monoterp. alcohol cis-rose oxide 6.73* 1109 [6.93] 1.28 1296 5.34 Monoterp. ether trans-rose oxide 7.08 1122 0.51 0.51 1307 5.53 Monoterp. ether Isopulegol 7.77 1148 0.11 [6.06] 1499 9.72* Monoterp. alcohol Menthone 7.95* 1154 2.14 2.09 1391 6.91 Monoterp. ketone Citronellal 7.95* 1154 [2.14] 0.10 1414 7.49 Monoterp. aldehyde Isomenthone 8.23 1165 5.92 6.04 1413 7.46 Monoterp. ketone Terpinen-4-ol 8.74 1183 0.05 0.08 1528 10.82 Monoterp. alcohol Menthol 9.09 1196 0.15 0.13 1560 12.02 Monoterp. alcohol α-terpineol 9.44 1204 0.36 0.46 1624 15.03* Monoterp. alcohol Nerol 10.63 1231 0.49 0.49 1732 21.44 Monoterp. alcohol Citronellol 11.21* 1244 32.50 32.85 1715 20.26 Monoterp. alcohol Neral 11.21* 1244 [32.50] 0.52 1600 13.73* Monoterp. aldehyde cis-isogeraniol 11.60 1252 0.03 0.03 1741 22.02 Monoterp. alcohol Geraniol 12.27 1267 15.79 16.05 1790 25.28 Monoterp. alcohol Citronellyl formate 12.72* 1277 7.68 7.28 1558 11.97* Monoterp. ester Geranial 12.72* 1277 [7.68] 0.66 1648 16.30 Monoterp. aldehyde Neryl formate 12.79 1279 0.14 Monoterp. ester Page 2 of 7
Geranyl formate 14.03 1303 3.16 3.42 1636 15.63* Monoterp. ester α-cubebene 15.76 1330 0.15 0.17 1408 7.33 Sesquiterpene Citronellyl acetate 17.10 1350 0.22 [0.32] 1600 13.78* Monoterp. ester α-copaene 17.46 1355 0.45 0.43 1426 7.77 Sesquiterpene β-bourbonene 17.90 1362 1.03 0.90 1448 8.31 Sesquiterpene β-elemene 18.70 1373 0.04 0.05 1523 10.63 Sesquiterpene Geranyl acetate 19.21 1381 0.35 0.33 1691 18.62 Monoterp. ester α-gurjunene 19.38 1384 0.05 0.05 1459 8.60 Sesquiterpene Isocaryophyllene 19.66 1388 0.03 0.03 1506 9.96 Sesquiterpene β-caryophyllene 20.35* 1398 1.18 1.19 1515 10.32* Sesquiterpene Geranic acid 20.35* 1398 [1.18] 0.12 2264 44.81 Monoterp. acid β-copaene 21.24 1408 0.11 [1.19] 1515 10.32* Sesquiterpene Aromadendrene 22.29 1421 0.36 0.28 1531 10.93 Sesquiterpene Seychellene 22.76* 1427 0.43 0.07 1547 11.55 Sesquiterpene 6,9-Guaiadiene 22.76* 1427 [0.43] 0.30 1542 11.33 Sesquiterpene α-humulene 23.12 1431 0.24 0.38 1580 12.78 Sesquiterpene allo-aromadendrene 23.36 1434 0.17 [7.28] 1558 11.97* Sesquiterpene Citronellyl propionate 23.79 1439 0.36 Monoterp. ester Neryl propionate 24.75 1451 0.25 0.37 1735 21.64 Monoterp. ester Germacrene D 25.34 1458 1.11 1.12 1614 14.50 Sesquiterpene γ-muurolene 25.53 1460 0.13 0.16 1607 14.16 Sesquiterpene β-selinene 25.94 1465 0.11 [0.46] 1624 15.03* Sesquiterpene Viridiflorene 26.12 1467 0.24 0.16 1618 14.74 Sesquiterpene Geranyl propionate 26.43 1471 0.60 0.53 1751 22.72 Monoterp. ester α-selinene 26.56* 1472 0.35 [3.42] 1636 15.63* Sesquiterpene Bicyclogermacrene 26.56* 1472 [0.35] [3.42] 1636 15.63* Sesquiterpene Eremophilene 26.94 1477 0.09 0.10 1622 14.92 Sesquiterpene α-muurolene 27.34 1482 0.23 0.15 1639 15.81 Sesquiterpene γ-cadinene 28.39 1494 0.21 0.67 1663 17.09* Sesquiterpene δ-cadinene 29.06 1504 0.78 0.71 1670 17.45 Sesquiterpene Zonarene 29.22 1506 0.13 [0.67] 1663 17.09* Sesquiterpene trans-calamenene 29.45 1509 0.22 0.20 1729 21.24 Sesquiterpene Geranyl isobutyrate 29.64 1512 0.08 0.05 1800 26.02 Monoterp. ester trans-γ-bisabolene 30.17 1519 0.10 0.15 1687 18.41 Sesquiterpene α-agarofuran 30.92 1529 0.24 0.21 1761 23.37 Sesquiterp. ether Citronellyl butyrate 31.20 1533 0.43 Monoterp. ester Geranyl butyrate 33.60 1566 0.90 0.74 1826 27.96 Monoterp. ester Spathulenol 33.90* 1570 0.17 0.03 2025 38.40 Sesquiterp. alcohol Caryophyllene oxide 33.90* 1570 [0.17] 0.12 1830 28.28 Sesquiterp. ether Phenylethyl tiglate 35.16 1588 0.67 0.63 2078 40.07 Phenolic ester 10-epi-γ-Eudesmol 36.06 1604 3.70 3.59 1979 36.79 Sesquiterp. alcohol 1,10-diepi-Cubenol 36.51 1615 0.09 0.17 1951 35.50* Sesquiterp. alcohol 1-epi-Cubenol 36.90 1624 0.18 0.18 1974 36.52 Sesquiterp. alcohol γ-eudesmol 37.02* 1627 0.16 0.09 2065 39.67 Sesquiterp. alcohol Page 3 of 7
Hinesol 37.02* 1627 [0.16] 0.08 2118 41.19 Sesquiterp. alcohol Cubenol 37.13 1630 0.08 [0.17] 1951 35.50* Sesquiterp. alcohol τ-cadinol 37.47 1638 0.21 0.15 2070 39.81 Sesquiterp. alcohol τ-muurolol 37.58 1641 0.06 0.06 2084 40.25 Sesquiterp. alcohol α-muurolol 37.79* 1646 0.58 0.18 2105 40.85 Sesquiterp. alcohol β-eudesmol 37.79* 1646 [0.58] 0.21 2112 41.03 Sesquiterp. alcohol α-eudesmol 37.79* 1646 [0.58] 0.20 2126 41.39 Sesquiterp. alcohol α-cadinol 38.04 1652 0.14 0.14 2134 41.60 Sesquiterp. alcohol Geranyl valerate 38.27 1657 0.13 0.14 1925 34.30 Monoterp. ester Citronellyl tiglate 38.58 1665 0.23 0.18 1934 34.72 Monoterp. ester Geranyl tiglate 39.93 1698 1.02 0.92 2030 38.57* Monoterp. ester Geranyl caproate isomer 40.47 1715 0.13 0.21 2018 38.19 Monoterp. ester Geranyl caproate 41.63 1751 0.07 [0.92] 2030 38.57* Monoterp. ester Geranyl caprylate 47.02 1944 0.03 0.02 2227 43.94 Monoterp. ester Total identified 96.97% 97.01% *: Two or more compounds are coeluting on this column [xx]: Duplicate percentage due to coelutions, not taken account in the identified total Note: no correction factor was applied Page 4 of 7
OTHER DATA Physical aspect : Yellow liquid Refractive index : 1.4660 ± 0.0003 (20 C) COMPLIANCE WITH ISO 4731:2011(PELARGONIUM X, NORTH AFRICAN TYPE) Compound North Africa Min. % Max. % Observed % Complies? cis-rose oxide 0.7 1.5 1.3 Yes trans-rose oxide 0.3 0.6 0.5 Yes Menthone 2.1 2.1 Yes Isomenthone 4.0 8.0 5.9 Yes Linalool 4.0 8.5 6.1 Yes 6,9-Guaiadiene 0.5 0.1 Yes Citronellyl formate 4.0 8.0 7.3 Yes α-terpineol 0.3 0.6 0.4 Yes Geranyl formate 2.0 7.0 3.2 Yes Citronellol 25.0 36.0 32.9 Yes Geraniol 10.0 18.0 15.8 Yes Geranyl butyrate 0.7 2.0 0.9 Yes 10-epi-γ-Eudesmol 3.0 6.2 3.7 Yes Geranyl tiglate 0.9 2.0 1.0 Yes Phenylethyl tiglate 0.5 1.2 0.7 Yes Refractive index 1.461 1.475 1.4660 Yes CONCLUSION No adulterant, contaminant or diluent were detected using this method. The oil complies with the ISO norm. Page 5 of 7
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