Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 UniBond Repair Metal For Good Page 1 of 11 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier UniBond Repair Metal For Good Part A Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Reaction adhesives 1.3. Details of the supplier of the safety data sheet Henkel Ltd Adhesives Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: +44 (1442) Fax-no.: +44 (1442) ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: For further health & safety, technical and practical advice on this product, please call +44 (0) or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate; Winsford; Cheshire; CW7 3QY- technical.services@henkel.co.uk 2.1. Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Flammable liquids Category 3 H226 Flammable liquid and vapor. Skin irritation Category 2 H315 Causes skin irritation. Serious eye irritation Category 2 H319 Causes serious eye irritation. Toxic to reproduction Category 2 H361d Suspected of damaging the unborn child. Specific target organ toxicity - repeated exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure Label elements Label elements (CLP):

2 MSDS-No.: UniBond Repair Metal For Good Page 2 of 11 Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Danger H226 Flammable liquid and vapor. H315 Causes skin irritation. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. P102 Keep out of reach of children. Precautionary statement: Prevention Precautionary statement: Response Precautionary statement: Storage Precautionary statement: Disposal P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe mist/vapours. P280 Wear protective gloves/eye protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/attention if you feel unwell. P405 Store locked up. P501 Dispose of contents/container in accordance with national regulation Other hazards None if used properly. SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: Screeding compound Base substances of preparation: Polyester-resin combination

3 MSDS-No.: UniBond Repair Metal For Good Page 3 of 11 Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification >= 1- < 15 % Flam. Liq. 3 H226 Acute Tox. 4; Inhalation H332 Asp. Tox. 1 H304 Eye Irrit. 2 H319 Skin Irrit. 2 H315 Repr. 2 H361d STOT RE 1; Inhalation H372 Aquatic Chronic 3 H412 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. SECTION 4: First aid measures Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting, sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital. Ingestion: Rinse mouth, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed SKIN: Redness, inflammation. Causes serious eye irritation. Suspected of damaging the unborn child Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet

4 MSDS-No.: UniBond Repair Metal For Good Page 4 of Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment. Danger of slipping on spilled product Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Section Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ventilate working rooms thoroughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Do not empty waste into waste water drains. Avoid skin and eye contact. Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work Conditions for safe storage, including any incompatibilities Keep away from sources of ignition. Store in a cool, well-ventilated place. Temperatures between 0 C and + 30 C Do not store together with food or other consumables (coffee, tea, tobacco, etc.) Specific end use(s) Reaction adhesives SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit category / Remarks Short Term Limit (STEL): [STYRENE] [STYRENE] Time Weighted Average (TWA): Regulatory list EH40 WEL EH40 WEL

5 MSDS-No.: UniBond Repair Metal For Good Page 5 of 11 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) soil period Value mg/l ppm mg/kg others 0,028 mg/l 0,0028 mg/l 0,04 mg/l 5 mg/l 0,614 mg/kg 0,0614 mg/kg 0,2 mg/kg Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers Inhalation Acute/short term Workers Inhalation Acute/short term local effects Workers Dermal Long term Workers Inhalation Long term Inhalation Acute/short term Inhalation Dermal Inhalation oral Acute/short term local effects Long term Long term Long term Time Value 289 mg/m3 306 mg/m3 406 mg/kg 85 mg/m3 174,25 mg/m3 182,75 mg/m3 343 mg/kg 10,2 mg/m3 2,1 mg/kg Remarks Biological Indices: None 8.2. controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Combination filter: ABEKP This recommendation should be matched to local conditions.

6 MSDS-No.: UniBond Repair Metal For Good Page 6 of 11 Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374. material thickness > 0.4 mm Perforation time > 240 minutes In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions. Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste pasty grey Odor characteristic Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density (23 C (73.4 F)) Bulk density Viscosity (Physica Rheolab) Viscosity (kinematic) Explosive properties Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 100,0 C (> 212 F) 32 C (89.6 F); no method 1,6700 g/cm pa.s Insoluble 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reaction with oxidants Chemical stability Stable under recommended storage conditions.

7 MSDS-No.: UniBond Repair Metal For Good Page 7 of Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials See section reactivity Hazardous decomposition products None known Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. STOT-repeated exposure: Causes damage to organs through prolonged or repeated exposure. Skin irritation: Causes skin irritation. Eye irritation: Causes serious eye irritation. Reproductive toxicity: Suspected of damaging fertility or the unborn child. Acute oral toxicity: Value type Value Route of application time Species Method Acute mg/kg oral Expert judgement toxicity estimate (ATE) LD rat mg/kg Acute inhalative toxicity: Acute dermal toxicity: Value Value Route of Species type application time LC50 11,8 mg/l 4 h rat Method Value type Value Route of application time Species Method LD50 > mg/kg dermal rat OECD Guideline 402 (Acute Dermal Toxicity) Respiratory or skin sensitization: not sensitising Result Test type Species Method Guinea pig maximisat ion test guinea pig Magnusson and Kligman Method

8 MSDS-No.: UniBond Repair Metal For Good Page 8 of 11 Germ cell mutagenicity: Carcinogenicity: Result Type of study / Route of administration positive sister chromatid exchange assay in mammalian cells Metabolic activation / time with and without Species negative inhalation: vapour mouse Method OECD Guideline 479 (Genetic Toxicology: In Vitro Sister Chromatid Exchange Assay in Mammalian Cells) Result Species Sex timefrequenc y of treatment not carcinogenic rat male/female 104 w 6 h/d, 5 d/w Route of application inhalation: vapour Method OECD Guideline 453 (Combined Chronic Toxicity / Carcinogenicity Studies) Repeated dose toxicity Result LOAEL=2.000 mg/kg NOAEL=1.000 mg/kg Route of application time / Frequency of treatment oral: gavage daily (5 d/w) rat oral: gavage daily (5 d/w) rat inhalation: vapour 4 w6 h/d, 5 d/w rat Species Method SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water Toxicity Value type Value Acute Toxicity Study time Species Method LC50 10 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 4,7 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC10 0,28 mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC50 6,3 mg/l Algae 96 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) NOEC 1,01 mg/l chronic Daphnia EPA OTS (Algal Toxicity, Tiers I and II) EPA OTS (Algal Toxicity, Tiers I and II) 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test)

9 MSDS-No.: UniBond Repair Metal For Good Page 9 of Persistence and degradability Result Route of application Degradability Method readily biodegradable aerobic 87 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) Bioaccumulative potential / Mobility in soil LogKow Bioconcentration factor (BCF) 74 time Species Temperature Method 2,96 25 C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) Results of PBT and vpvb assessment No data available Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances

10 MSDS-No.: UniBond Repair Metal For Good Page 10 of 11 SECTION 14: Transport information UN number ADR 2055 RID 2055 ADN 2055 IMDG 2055 IATA UN proper shipping name ADR RID ADN IMDG IATA STYRENE MONOMER, STABILIZED (solution) STYRENE MONOMER, STABILIZED (solution) STYRENE MONOMER, STABILIZED (solution) STYRENE MONOMER, STABILIZED (solution) monomer, stabilized (solution) Transport hazard class(es) ADR 3 RID 3 ADN 3 IMDG 3 IATA Packaging group ADR RID ADN IMDG IATA III III III III III Environmental hazards ADR RID ADN IMDG IATA Special precautions for user ADR RID ADN IMDG IATA Tunnelcode: (D/E) When transporting as a set (component A and B) then the following dangerous good classification is used: UN 3269 Polyester resin kit, 3, III Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 14,8 % (VOCV VOC regulation CH)

11 MSDS-No.: UniBond Repair Metal For Good Page 11 of 11 VOC Paints and Varnishes (EU): max. VOC content: 130 g/l Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.

12 Safety Data Sheet according to (EC) No 1907/2006 UniBond Repair Metal For Good Page 1 of 12 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier UniBond Repair Metal For Good Part B Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Reaction adhesives 1.3. Details of the supplier of the safety data sheet Henkel Ltd Adhesives Wood Lane End HP2 4RQ Hemel Hempstead Great Britain Phone: +44 (1442) Fax-no.: +44 (1442) ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: For further health & safety, technical and practical advice on this product, please call +44 (0) or write to: Technical Services; Henkel Limited; Road 5; Winsford Industrial Estate; Winsford; Cheshire; CW7 3QY- technical.services@henkel.co.uk 2.1. Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Organic peroxides Type E H242 Heating may cause a fire. Serious eye irritation Category 2 H319 Causes serious eye irritation. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Acute hazards to the aquatic environment Category 1 H400 Very toxic to aquatic life. Chronic hazards to the aquatic environment Category 2 H411 Toxic to aquatic life with long lasting effects Label elements Label elements (CLP):

13 MSDS-No.: UniBond Repair Metal For Good Page 2 of 12 Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Warning H242 Heating may cause a fire. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H410 Very toxic to aquatic life with long lasting effects. P102 Keep out of reach of children. Precautionary statement: Prevention Precautionary statement: Response Precautionary statement: Storage Precautionary statement: Disposal P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/eye protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container in accordance with national regulation Other hazards Persons suffering from allergic reactions to peroxides should avoid contact with the product Mixtures General chemical description: Screeding compound Base substances of preparation: SECTION 3: Composition/information on ingredients Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification >= 30 % Eye Irrit. 2 H319 Aquatic Acute 1 H400 Skin Sens. 1 H317 Aquatic Chronic 2 H411 Org. Perox. B H241 M factor: 10 >= 10- < 30 % Aquatic Chronic 3 H412 For full text of the H - statements and other abbreviations see section 16 "Other information".

14 MSDS-No.: UniBond Repair Metal For Good Page 3 of 12 Substances without classification may have community workplace exposure limits available Description of first aid measures General information: In case of adverse health effects seek medical advice. Inhalation: Move to fresh air, consult doctor if complaint persists. SECTION 4: First aid measures Skin contact: Rinse with running water and soap. Skin care. Remove contaminated clothes immediately. Eye contact: Immediately flush eyes with soft jet of water or eye rinse solution for at least 5 minutes. If pains remains (intensive smarting, sensivity to light, visual disturbance) continue flushing and contact/seek doctor or hospital. Ingestion: Rinse mouth, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: carbon dioxide, foam, powder, water spray jet, fine water spray Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO) and carbon dioxide (CO2) can be released Advice for firefighters Wear self-contained breathing apparatus. Wear protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment. Danger of slipping on spilled product Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up Remove mechanically. Dispose of contaminated material as waste according to Section 13.

15 MSDS-No.: UniBond Repair Metal For Good Page 4 of Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Ventilate working rooms throughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Avoid skin and eye contact. Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work Conditions for safe storage, including any incompatibilities Keep away from sources of ignition. Store in a cool, well-ventilated place. Temperatures between 0 C and + 30 C Do not store together with food or other consumables (coffee, tea, tobacco, etc.) Specific end use(s) Reaction adhesives SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain None

16 MSDS-No.: UniBond Repair Metal For Good Page 5 of 12 Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP period Value mg/l ppm mg/kg others 0,602 µg/l sediment 0,338 (freshwater) mg/kg soil 0,0758 mg/kg oral aqua (freshwater) aqua (marine water) aqua (intermittent releases) sediment (freshwater) sediment (marine water) soil STP oral 1,49 mg/kg 0,149 mg/kg 1 mg/kg 0,0602 µg/l 0,602 µg/l 0,35 mg/l 6,67 mg/kg food 0,0037 mg/l 0,00037 mg/l 0,037 mg/l 10 mg/l 333 mg/kg food Remarks

17 MSDS-No.: UniBond Repair Metal For Good Page 6 of 12 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers Inhalation Long term Workers Dermal Long term Inhalation Long term Dermal oral Long term Long term Workers Dermal Acute/short term Workers Inhalation Acute/short term Workers Inhalation Long term Workers Dermal Long term Dermal Inhalation oral Dermal Inhalation oral Acute/short term Acute/short term Acute/short term Long term Long term Long term Time Value 11,75 mg/m3 6,6 mg/kg bw/day 2,9 mg/m3 3,3 mg/kg bw/day 1,65 mg/kg bw/day 170 mg/kg bw/day 35,08 mg/m3 8,8 mg/m3 10 mg/kg bw/day 80 mg/kg bw/day 8,7 mg/m3 80 mg/kg bw/day 0,22 mg/kg bw/day 8,69 mg/m3 5 mg/kg bw/day Remarks Biological Indices: None 8.2. controls: Respiratory protection: Suitable breathing mask when there is inadequate ventilation. Combination filter: ABEKP This recommendation should be matched to local conditions.

18 MSDS-No.: UniBond Repair Metal For Good Page 7 of 12 Hand protection: Recommended are gloves made from Nitril rubber ( Material thickness >0,1 mm, Perforation time < 30s).Gloves should be replaced after each short time contact or contamination. Available at laboratory specialized trade or at pharmacies / chemist's shops. In the case of longer contact protective gloves made from nitrile rubber are recommended according to EN 374. material thickness > 0.4 mm Perforation time > 240 minutes In the case of longer and repeated contact please note that in practice the penetration times may be considerably shorter than those determined according to EN 374. The protective gloves must always be checked for their suitability for use at the specific workplace (e.g. mechanical and thermal stress, product compatibility, antistatic effects, etc.). The gloves must be replaced immediately at the first signs of wear and tear. The information provided by the manufacturers and given in the relevant trade association regulations for industrial safety must always be observed. We recommend that a hand care plan is drawn up in cooperation with a glove manufacturer and the trade association in accordance with the local operating conditions. Eye protection: Goggles which can be tightly sealed. Skin protection: Suitable protective clothing SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste yellow Odor mild Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (23 C (73.4 F); Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties Not applicable 51 C (123.8 F); Supplier method 1,2000 g/cm3 Partially soluble Not determined 9.2. Other information SECTION 10: Stability and reactivity Reactivity None if used for intended purpose Chemical stability Stable under recommended storage conditions.

19 MSDS-No.: UniBond Repair Metal For Good Page 8 of Possibility of hazardous reactions See section reactivity Conditions to avoid None if used for intended purpose Incompatible materials None if used properly Hazardous decomposition products None known Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Persons suffering from allergic reactions to peroxides should avoid contact with the product. Skin irritation: Primary skin irritation: slightly irritating, does not require labeling Eye irritation: Causes serious eye irritation. Sensitizing: May cause an allergic skin reaction. Acute oral toxicity: Value Value Route of Species type application time LD50 > mg/kg oral rat Method LD mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute inhalative toxicity: Acute dermal toxicity: Value Value Route of Species type application time LC50 > 200 mg/l 4 h rat Method Value type Value Route of application time Species Method LD50 > mg/kg dermal rat OECD Guideline 402 (Acute Dermal Toxicity) Skin corrosion/irritation: Result time Species Method not irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion)

20 MSDS-No.: UniBond Repair Metal For Good Page 9 of 12 Serious eye damage/irritation: Result time Species Method slightly irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) not sensitising guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administration negative in vitro mammalian chromosome aberration test negative bacterial reverse mutation assay (e.g Ames test) negative mammalian cell gene mutation assay Metabolic activation / time with and without Species Method OECD Guideline 473 (In vitro Mammalian Chromosome Aberration Test) with and without OECD Guideline 471 (Bacterial Reverse Mutation Assay) with and without OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) Repeated dose toxicity Result NOAEL=> mg/kg Route of application time / Frequency of treatment Species Method oral: feed 90 daysdaily rat OECD Guideline 408 (Repeated Dose 90-Day Oral Toxicity in Rodents) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water Toxicity Ecotoxicity: Very toxic to aquatic life with long lasting effects.

21 MSDS-No.: UniBond Repair Metal For Good Page 10 of 12 Value type Value Acute Toxicity Study time Species Method LC50 0,06 mg/l Fish 96 h OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 0,11 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 0,07 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC 0,02 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 3,7 mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 19,3 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC 1 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC50 4,9 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Result Route of application Degradability Method readily biodegradable aerobic > 60 % OECD Guideline 301 D (Ready Biodegradability: Closed Bottle Test) readily biodegradable aerobic 87 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) Bioaccumulative potential / Mobility in soil LogKow Bioconcentration factor (BCF) time Species Temperature Method 66,6 fish OECD Guideline 305 (Bioconcentration: Flowthrough Fish Test) 3,2 22 C OECD Guideline 117 (Partition Coefficient (noctanol / water), HPLC Method) 3,9 OECD Guideline 117 (Partition Coefficient (noctanol / water), HPLC Method) Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available.

22 MSDS-No.: UniBond Repair Metal For Good Page 11 of 12 SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of waste and residues in accordance with local authority requirements. Disposal of uncleaned packages: Use packages for recycling only when totally empty. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances SECTION 14: Transport information UN number ADR 3108 RID 3108 ADN 3108 IMDG 3108 IATA UN proper shipping name ADR RID ADN IMDG IATA ORGANIC PEROXIDE TYPE E, SOLID (DIBENZOYL PEROXIDE) ORGANIC PEROXIDE TYPE E, SOLID (DIBENZOYL PEROXIDE) ORGANIC PEROXIDE TYPE E, SOLID (DIBENZOYL PEROXIDE) ORGANIC PEROXIDE TYPE E, SOLID (DIBENZOYL PEROXIDE) (Dipropylenglycol dibenzoate) Organic peroxide type E, solid () Transport hazard class(es) ADR 5.2 RID 5.2 ADN 5.2 IMDG 5.2 IATA 5.2 (HEAT) Packaging group ADR RID ADN IMDG IATA II II Environmental hazards ADR RID ADN IMDG IATA Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Special precautions for user ADR

23 MSDS-No.: UniBond Repair Metal For Good Page 12 of 12 RID ADN IMDG IATA Tunnelcode: (D) IMDG-Code: Segregation group 16- Peroxides When transporting as a set (component A and B) then the following dangerous good classification is used: UN 3269 Polyester resin kit, 3, III Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 0,00 % (VOCV VOC regulation CH) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H241 Heating may cause a fire or explosion. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.