Safety Data Sheet according to Regulation (EC) No1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No1907/2006 LOCTITE ABLESTIK 64C PTA Page 1 of 15 SDS No. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE ABLESTIK 64C PTA Contains: Nickel powder [particle diameter < 1 mm] RP Bisphenol F-epichlorohydrin resin, MW<=700 1,4-Bis(2,3-epoxypropoxy)butane 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy adhesive 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Skin irritation Category 2 H315 Causes skin irritation. Serious eye irritation Category 2 H319 Causes serious eye irritation. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Carcinogenicity Category 2 H351 Suspected of causing cancer. Specific target organ toxicity - repeated exposure Category 1 H372 Causes damage to organs through prolonged or repeated exposure. Chronic hazards to the aquatic environment Category 3 H412 Harmful to aquatic life with long lasting effects.

2 LOCTITE ABLESTIK 64C PTA Page 2 of 15 Classification (DPD): T - Toxic R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. carcinogenic, category 3 R40 Limited evidence of a carcinogenic effect. Sensitizing R43 May cause sensitisation by skin contact. Xi - Irritant R36/38 Irritating to eyes and skin. Dangerous for the environment R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Label elements Label elements (CLP): Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Prevention Precautionary statement: Response Danger H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention.

3 LOCTITE ABLESTIK 64C PTA Page 3 of 15 Label elements (DPD): T - Toxic Risk phrases: R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S23 Do not breathe vapour. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S51 Use only in well-ventilated areas. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Additional labeling: Contains epoxy constituents. See information supplied by the manufacturer. Contains: Nickel powder [particle diameter < 1 mm],,, RP Bisphenol F-epichlorohydrin resin, MW<= Other hazards None if used properly. General chemical description: Adhesive Base substances of preparation: Epoxy resin SECTION 3: Composition/information on ingredients

4 LOCTITE ABLESTIK 64C PTA Page 4 of 15 Declaration of the ingredients according to CLP (EC) No 1272/2008: Nickel powder [particle diameter < 1 mm] RP Bisphenol F-epichlorohydrin resin, MW<= EC Number REACH-Reg No content Classification >= 60- < 100 % Specific target organ toxicity - repeated exposure 1 H372 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 3 H412 Carcinogenicity 2 H351 >= 10- < 20 % Skin irritation 2 H315 Skin sensitizer 1 H317 Serious eye irritation 2 H319 Chronic hazards to the aquatic environment 2 H411 >= 1- < 3 % Acute toxicity 4 H302 Acute toxicity 4 H312 Eye Damage/Irritation 2 H319 Acute toxicity 2 H330 Specific target organ toxicity - single exposure 3 H335 Carcinogenicity 2 H351 Specific target organ toxicity - repeated exposure 2 H373 >= 1- < 2,5 % Serious eye irritation 2 H319 Skin irritation 2 H315 Skin sensitizer 1 H317 Chronic hazards to the aquatic environment 2 H411 1,4-Bis(2,3-epoxypropoxy)butane >= 0,1- < 1 % Acute toxicity 4; Inhalation H332 Acute toxicity 4; Dermal H312 Serious eye irritation 2 H319 Skin irritation 2 H315 Skin sensitizer 1 H317 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

5 LOCTITE ABLESTIK 64C PTA Page 5 of 15 Declaration of ingredients according to DPD (EC) No 1999/45: Nickel powder [particle diameter < 1 mm] RP Bisphenol F-epichlorohydrin resin, MW<= EC Number REACH-Reg No content Classification >= 60 - < 100 % carcinogenic, category 3; R40 T - Toxic; R48/23 R43 R52/53 >= 10 - < 20 % R43 Xi - Irritant; R36/38 N - Dangerous for the environment; R51/53 >= 1 - < 3 % carcinogenic, category 3; R40 T - Toxic; R23 Xn - Harmful; R21/22, R48/20 Xi - Irritant; R36/37 >= 1 - < 2,5 % Xi - Irritant; R36/38, R43 N - Dangerous for the environment; R51/53 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed SKIN: Redness, inflammation. SKIN: Rash, Urticaria. EYE: Irritation, conjunctivitis Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: water, carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: High pressure waterjet 5.2. Special hazards arising from the substance or mixture In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

6 LOCTITE ABLESTIK 64C PTA Page 6 of 15 Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes. Wear protective equipment Environmental precautions Do not empty into drains / surface water / ground water Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in section Precautions for safe handling Avoid skin and eye contact. See advice in section 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Keep container tightly sealed. Store at room temperature Specific end use(s) Epoxy adhesive SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain Ingredient ppm mg/m 3 Type Category Remarks NICKEL AND ITS INORGANIC COMPOUNDS (EXCEPT NICKEL TETRACARBONYL): NICKEL AND WATER-INSOLUBLE NICKEL COMPOUNDS (AS NI) 0,5 Time Weighted Average (TWA): EH40 WEL NICKEL AND ITS INORGANIC COMPOUNDS (EXCEPT NICKEL TETRACARBONYL): NICKEL AND WATER-INSOLUBLE NICKEL COMPOUNDS (AS NI) Skin designation: Can be absorbed through the skin. EH40 WEL

7 LOCTITE ABLESTIK 64C PTA Page 7 of 15 Predicted No-Effect Concentration (PNEC): Name on list Nickel Nickel Environmental Compartment soil aqua (freshwater) aqua (freshwater) aqua (marine water) aqua (intermittent releases) STP sediment (freshwater) sediment (marine water) period mg/l ppm mg/kg others 29,9 mg/kg 0,996 mg/kg 0,0996 mg/kg soil 0,196 mg/kg oral 3,55 µg/l 0,006 mg/l 0,0006 mg/l 0,018 mg/l 10 mg/l 11 mg/kg food aqua 0,17 mg/l (freshwater) aqua (marine 0,017 mg/l water) aqua 1,7 mg/l (intermittent releases) sediment 0,861 (freshwater) mg/kg sediment 0,0861 (marine water) mg/kg soil 0,0724 mg/kg oral 35,3 mg/kg Remarks

8 LOCTITE ABLESTIK 64C PTA Page 8 of 15 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker Dermal Acute/short term worker inhalation Acute/short term worker Dermal Long term worker inhalation Long term general population general population general population general population general population general population Dermal Dermal inhalation inhalation oral oral Acute/short term Long term Acute/short term Long term Acute/short term Long term worker Dermal Long term worker inhalation Long term worker inhalation Acute/short term worker inhalation Acute/short term local effects worker inhalation Long term local effects Time 8,33 mg/kg bw/day 12,25 mg/m3 8,33 mg/kg bw/day 12,25 mg/m3 3,571 mg/kg bw/day 3,571 mg/kg bw/day 0,75 mg/m3 0,75 mg/m3 0,75 mg/kg bw/day 0,75 mg/kg bw/day 4 mg/kg bw/day 31 mg/m3 143 mg/m3 8 mg/m3 8 mg/m3 Remarks Biological Indices: None 8.2. controls: Engineering controls: Ensure good ventilation/extraction.

9 LOCTITE ABLESTIK 64C PTA Page 9 of 15 Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor Mild Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) (Solvent: Water) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 100 C (> 212 F) 3 g/cm3 Insoluble Not available Other information

10 LOCTITE ABLESTIK 64C PTA Page 10 of 15 SECTION 10: Stability and reactivity Reactivity Reacts with alcohols and amines. Reacts with oxidants, acids and lyes Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway polymerization Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if stored and applied as directed Incompatible materials See section reactivity Hazardous decomposition products Hydrocarbons carbon oxides. nitrogen oxides Rapid polymerisation may generate excessive heat and pressure Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Causes damage to organs through prolonged or repeated exposure Oral toxicity: May cause irritation to the digestive tract. Skin irritation: Causes skin irritation. Eye irritation: Causes serious eye irritation. Sensitizing: May cause an allergic skin reaction.

11 LOCTITE ABLESTIK 64C PTA Page 11 of 15 Carcinogenicity: Suspected of causing cancer Acute oral toxicity: type Route of application time Species LD mg/kg oral rat LD50 > mg/kg rat LD50 > mg/kg rat Method Acute inhalative toxicity: type Route of application time Species Method Acute dermal toxicity: RP Bisphenol F- epichlorohydrin resin, MW<= type Route of application time Species LD mg/kg dermal rabbit LD50 > mg/kg dermal rabbit Method Skin corrosion/irritation: Result time Species Method slightly irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Result time Species Method not irritating rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion)

12 LOCTITE ABLESTIK 64C PTA Page 12 of 15 Respiratory or skin sensitization: 1,4-Bis(2,3- epoxypropoxy)butane sensitising sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) Guinea pig maximisat ion test mouse guinea pig OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: 1,4-Bis(2,3- epoxypropoxy)butane Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without Species Method OECD Guideline 472 (Genetic Toxicology: Escherichia coli, Reverse Mutation Assay) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Harmful to aquatic life with long lasting effects. Do not empty into drains, soil or bodies of water.

13 LOCTITE ABLESTIK 64C PTA Page 13 of 15 Nickel powder [particle diameter < 1 mm] Nickel powder [particle diameter < 1 mm] bisphenol- A- bisphenol- A- RP Bisphenol F- epichlorohydrin resin, MW<= ,4-Bis(2,3- epoxypropoxy)butane ,4-Bis(2,3- epoxypropoxy)butane type Acute Toxicity Study time Species LC50 > 100 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) Method OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 100 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) LC50 1, mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC 0,3 mg/l chronic Daphnia 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LC mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 25 mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) EC50 3,5 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation LC50 24 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) Test) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 75 mg/l Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. RP Bisphenol F- epichlorohydrin resin, MW<= ,4-Bis(2,3- epoxypropoxy)butane Result Route of application Degradability Method aerobic % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) 37 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. LogKow Bioconcentration factor (BCF) 0,28 time Species Temperature Method

14 LOCTITE ABLESTIK 64C PTA Page 14 of Results of PBT and vpvb assessment Nickel powder [particle diameter < 1 mm] (epichlorhydrin); epoxy molecular weight <= 700) PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR UN proper shipping name Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Transport hazard class(es) Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Packaging group Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Environmental hazards Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Special precautions for user Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable

15 LOCTITE ABLESTIK 64C PTA Page 15 of 15 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R21/22 Harmful in contact with skin and if swallowed. R23 Toxic by inhalation. R36/37 Irritating to eyes and respiratory system. R36/38 Irritating to eyes and skin. R40 Limited evidence of a carcinogenic effect. R43 May cause sensitisation by skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H330 Fatal if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.