Safety Data Sheet according to (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to (EC) No 1907/2006 Marine Epoxy part B Page 1 of 12 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Marine Epoxy part B Contains: 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Epoxy Hardener 1.3. Details of the supplier of the safety data sheet Henkel Limited 2 Bishop Square Business Park AL109EY Herfordshire Hatfield Great Britain Phone: Fax-no.: ua-productsafety.uk@uk.henkel.com 1.4. Emergency telephone number 24 Hours Emergency Tel: +44 (0) Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Acute toxicity Category 4 H302 Harmful if swallowed. Route of : Oral Skin corrosion Category 1B H314 Causes severe skin burns and eye damage. Skin sensitizer Category 1 H317 May cause an allergic skin reaction. Chronic hazards to the aquatic environment Category 3 H412 Harmful to aquatic life with long lasting effects Label elements Label elements (CLP):

2 Marine Epoxy part B Page 2 of 12 Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Prevention Precautionary statement: Response Danger H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting effects. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. P333+P313 If skin irritation or rash occurs: Get medical advice/attention Other hazards None if used properly. SECTION 3: Composition/information on ingredients 3.2. Mixtures General chemical description: Part B of a two part adhesive Declaration of the ingredients according to CLP (EC) No 1272/2008: EC Number REACH-Reg No content Classification % Acute Tox. 3; Dermal H311 Acute Tox. 4; Oral H302 Skin Corr. 1B H314 Aquatic Chronic 3 H412 Skin Sens. 1 H < 25 % Aquatic Chronic 2 H411 Skin Irrit. 2 H315 Skin Sens. 1 H % Acute Tox. 4; Oral H302 Acute Tox. 4; Inhalation H332 Eye Irrit. 2 H319 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available.

3 Marine Epoxy part B Page 3 of 12 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Immediately wash skin thoroughly with soap and water. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Seek medical advice Most important symptoms and effects, both acute and delayed SKIN: Rash, Urticaria. Causes burns. INGESTION: Nausea, vomiting, diarrhea, abdominal pain Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: None known 5.2. Special hazards arising from the substance or mixture Oxides of carbon, oxides of nitrogen, irritating organic vapors Advice for firefighters Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact Environmental precautions Do not let product enter drains. Waste disposal with the approval of the responsible local authority Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Dispose of contaminated material as waste according to Section 13.

4 Marine Epoxy part B Page 4 of Reference to other sections See advice in section 8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid skin and eye contact. Use only in well-ventilated areas. Hygiene measures: Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place Specific end use(s) Epoxy Hardener SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for Great Britain None Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) sediment (freshwater) sediment (marine water) soil STP period Value mg/l ppm mg/kg others 0,058 mg/l 215 mg/kg 21,5 mg/kg 42,9 mg/kg aqua (intermittent releases) soil 0,456 mg/kg STP sediment (freshwater) sediment (marine water) aqua (marine water) aqua (intermittent releases) aqua (freshwater) 5,27 mg/kg 0,527 mg/kg 0,0058 mg/l 250 mg/l 0,58 mg/l 39 mg/l 0,1 mg/l 2,3 mg/l 1 mg/l Remarks

5 Marine Epoxy part B Page 5 of 12 Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect Workers Dermal Acute/short term Workers Inhalation Acute/short term Workers Dermal Acute/short term local effects Workers Dermal Workers Inhalation Workers Dermal local effects Dermal Acute/short term Inhalation oral oral Dermal Inhalation oral Dermal oral oral Acute/short term Acute/short term Acute/short term local effects local effects Acute/short term Workers Inhalation Acute/short term Workers Inhalation Inhalation Inhalation Acute/short term Workers Dermal Acute/short term Workers Dermal Dermal Dermal Acute/short term Time Value 20 mg/kg bw/day 21,4 mg/m3 0,04 mg/cm2 3,3 mg/kg bw/day 3,6 mg/m3 0,006 mg/cm2 10 mg/kg bw/day 5,3 mg/m3 1,5 mg/kg bw/day 0,02 mg/cm2 1,7 mg/kg bw/day 0,9 mg/m3 0,3 mg/kg bw/day 0,003 mg/cm2 20 mg/kg bw/day 5 mg/kg bw/day 110 mg/m3 22 mg/m3 27 mg/m3 5,4 mg/m3 40 mg/kg bw/day 8 mg/kg bw/day 20 mg/kg bw/day 4 mg/kg bw/day Remarks

6 Marine Epoxy part B Page 6 of 12 Biological Indices: None 8.2. controls: Respiratory protection: Use only in well-ventilated areas. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor characteristic Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density () Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties > 150 C (> 302 F) > 150 C (> 302 F); Supplier method 0,91 g/cm Other information

7 Marine Epoxy part B Page 7 of 12 SECTION 10: Stability and reactivity Reactivity Reaction with strong bases Reaction with strong acids. Reaction with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Avoid contact with acids and oxidizing agents Incompatible materials None if used properly Hazardous decomposition products None if used for intended purpose Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Oral toxicity: Harmful if swallowed. Skin irritation: Causes severe skin burns and eye damage. Eye irritation: Corrosive Avoid eye contact. Sensitizing: May cause an allergic skin reaction. Acute oral toxicity: Value type Value Route of application time Species LD50 > mg/kg oral rat LD mg/kg oral rat Method Acute inhalative toxicity: Value type Value Route of application time Species Method Acute 4,17 mg/l Aerosol Expert judgement toxicity estimate (ATE) LC50 > 4,178 mg/l 4 h rat

8 Marine Epoxy part B Page 8 of 12 Acute dermal toxicity: 2-Piperazin-1- ylethylamine Value Value Route of Species Method type application time LD mg/kg dermal rabbit Draize Test Skin corrosion/irritation: 2-Piperazin-1- ylethylamine Result time Species corrosive 20 min rabbit Method not irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: Result time Species Method Category II 24 h rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Respiratory or skin sensitization: 2-Piperazin-1- ylethylamine sensitising not sensitising Result Test type Species Method Guinea pig maximisat ion test Guinea pig maximisat ion test guinea pig guinea pig Magnusson and Kligman Method Magnusson and Kligman Method Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without Species Method SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Harmful to aquatic life with long lasting effects. Do not empty into drains / surface water / ground water.

9 Marine Epoxy part B Page 9 of 12 Value type Value Acute Toxicity Study time Species LC50 > 100 mg/l Fish 96 h Salmo gairdneri (new name: Oncorhynchus mykiss) Method OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 32 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC 31 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) EC mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) LC50 3,2 mg/l Fish 96 h Brachydanio rerio (new name: Danio rerio) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 201 (Alga, Growth Inhibition Test) OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 > 1-10 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 3,14 mg/l Algae 72 h OECD Guideline 201 (Alga, Growth Inhibition Test) LC mg/l Fish 48 h Leuciscus idus DIN EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC mg/l Algae 96 h Scenedesmus quadricauda OECD Guideline 201 (Alga, Growth Inhibition Test) Persistence and degradability Persistence and Biodegradability: No data available for the product Result Route of application Degradability Method under test conditions no aerobic 0 % OECD Guideline 301 D (Ready biodegradation observ Biodegradability: Closed Bottle Test) aerobic 7 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution Test) readily biodegradable aerobic % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available for the product. LogKow Bioconcentration factor (BCF) time Species Temperature Method -1,48 OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask Method) 1,08

10 Marine Epoxy part B Page 10 of Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. SECTION 13: Disposal considerations Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Waste code waste adhesives and sealants containing organic solvents and other dangerous substances

11 Marine Epoxy part B Page 11 of 12 SECTION 14: Transport information UN number ADR 3267 RID 3267 ADN 3267 IMDG 3267 IATA UN proper shipping name ADR RID ADN IMDG IATA CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (N-Aminoethylpiperazine) CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (N-Aminoethylpiperazine) CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (N-Aminoethylpiperazine) CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (N-Aminoethylpiperazine) Corrosive liquid, basic, organic, n.o.s. (N-Aminoethylpiperazine) Transport hazard class(es) ADR 8 RID 8 ADN 8 IMDG 8 IATA Packaging group ADR RID ADN IMDG IATA III III III III III Environmental hazards ADR RID ADN IMDG IATA Special precautions for user ADR RID ADN IMDG IATA Tunnelcode: (E) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 3 % (1999/13/EC) Chemical safety assessment A chemical safety assessment has not been carried out.

12 Marine Epoxy part B Page 12 of 12 SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Label elements (DPD): C - Corrosive Risk phrases: R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Contains:, Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.