Proper 11% OD Oil Dispersent (OD)

Transcription

1 Proper 11% OD Oil Dispersent (OD) Introduction Proper 11% OD is systemic and contact insecticide combination for the control broad spectrum effi cacy in a wide range of crops. With the combination of the two different active ingredients, Thiacloprid & Deltamethrin, Proper combines a fast knockdown effect with long-lasting residual control. Proper is excellent biological effi cacy based on optimised retention, rainfastness and penetration activity. Composition Each liter contains: Thiacloprid g w/v Deltamethrin g w/v Formulation Oil Dispersent (OD) Physical & chemical properties of active ingredients Common name accepted by ISO and synonyms: 1. Thiacloprid 2. Deltamethrin CAS no.: Chemical name (IUPAC): 1. (Z)-N-{3-[(6- Chloro-3-pyridinyl)methyl]-1,3-thiazolan-2-yliden}cyanamide 2. (S)-α-cyano-3-phenoxybenzyl (1R)-cis-3-(2,2-dibromovinyl)- 2,2-dimethylcyclo-propanecarboxylate. Empirical formula: 1. C 10 H 9 ClN 4 S 2. C 22 H 19 Br 2 NO 3 1

2 Structural formula: Chemical class: 1. A neonicotinoid insecticide (belonging to the chloronicotinoid chemical class,) 2. Synthetic pyrethroid Mol. Weight: g/mol Purity (%w/w) of technical active (%) minimum % : 1. > 97.5% w/w min. 2. > 98% w/w min. Colour: 1. Yellowish solid 2. White (colourless en Pest.Man) Physical state: 1. Crystalline powder 2. Crystalline powder Odour: 1. Odorless 2. Odorless. Melting point: ºC Density: 1.46 g/ml (20 ºC) Solubility: 1. in water: g/l Solubility in organic solvents at 20 ºC: n-heptane: < 0.1 g/l at 20 ºC xylene: 0.30 g/l at 20 ºC 1-octanol: 1.4 g/l at 20 ºC 2-propanol: 3.0 g/l at 20 ºC ethyl acetate: 9.4 g/l at 20 ºC polyethylen glycol (PEG): 42 g/l at 20 ºC acetonitrile: 52 g/l at 20 ºC 2

3 acetone: 64 g/l at 20 ºC dichloromethane: 160 g/l at 20 ºC dimethylsulfoxide: 150 g/l at 20 ºC 2. In water: mg/ (20 ºC). 500 g/l acetone 750 g/l cyclohexanone 450 g/l benzene, dimethyl sulfoxide 900 g/l dioxane 15 g/l ethanol 250g/l xylene ph (acidity/alkalinity): 1. NP Physical & chemical properties of finish product Colour: Beige liquid Physical state: liquid Odour: Slight Odour ph: 6-8 Density: 1.08 gm/cm 3 Viscosity: sec Explosivity: Non Explosive % Persistent foam: Less than 10ml after 60 sec. Acute toxicity 1. Thiacloprid Route of application Animal Active ingredient Formulated product Oral LD50 Rat 836 mg/kg 1000 mg/kg Dermal (LD50) Rat >2000 mg/kgb.w. >4000 mg/kg Inhalation (LC50) Rat >2,535 mg/l >2.484mg/l Skin irritation Rabbit Not irritant Not irritant Eye irritation Rabbit Not irritant Not irritant Skin sensitisation Guinea pig Not sensitiser Not Sensitizer 3

4 Classified in the WHO class as: active ingredient and formulated product is classifi ed by WHO under class II, Moderately Hazardous. 2. Deltamethrin Route of application Animal Active ingredient Formulated product Oral LD50 Rat > mg/kg Dermal (LD50) Rat >2.940 mg/kg >4000 mg/kg Inhalation (LC50) Rat 0.60 mg/l >2.484mg/l Skin irritation Rabbit Not irritant Not irritant Eye irritation Rabbit Slightly to moderate primary irritation: reversible in 72 hours Not irritant Skin sensitisation Guinea pig No sensitization Not Sensitizer Classified in the WHO class as: active ingredient and formulated product WHO Class II, as Moderately hazardous. Acceptable daily intake: Thiacloprid: ADI: 0.01 mg/kg bw/day Deltamethrin: ADI: 0.01 mg/kg Ecotoxicology Effect on bees: slightly toxic for bees Effect on Fish: HighlyToxic to fi sh Effect on Birds: toxic to birds. 4

5 Usage & recommendation: Main crops Typical Pests Dosage: ml/ 20Lt water PHI* Cabbage Caulifl ower Clover Tomato Pepper Eggplant Cucumber Zucchini watermelon Potato Aphids, Diamond back moth Aphids, Cotton leaves worm Cotton leaves worm Tomato fruit moth White fl y Cotton leaves worm Aphids White fl y 20 7 days days days days days Maize Corn moth days Crop tolerance: Thiacloprid: not considered as a product that causes damages in the crops if is used as recommended. Deltamethrin: Not phytotoxic included in higher dose that the recommended. Don t apply in crops in dry season or any adverse situation. It can be damage in cyclamen fl owers, gloxinia and others ornamentals if it s sprayed directly. Finish Product: not considered as a product that causes damages in the crops if is used as recommended. Compatibility: it compatible with commonly used fungicides. Safety handling HAZARDS AND SAFETY PRECAUTIONS Keep out of reach of children. Avoid contact with skin and inhalation of spray mist Keep away from food, drink and animal feeding stuffs. 5

6 Store in original containers, tightly closed. Avoid contamination of any water supply with chemical or empty container Keep product in original tightly closed container. Remove sources of naked fl ame or sparks. Avoid contact with eyes. Prolonged contact with skin, and inhalation of dust and vapour. Use with adequate ventilation. Wash hands before eating, drinking, chewing gum, smoking, or using the toilet. Remove clothing immediately if the product gets inside. Then wash skin thoroughly using a non-abrasive soap and puton clean clothing. Do not apply directly to areas where surface water is present, or to intertidal areas below the mean high water mark. Water used to clean equipment must be disposed of correctly to avoid contamination. Handling precautions: Use adequate safety/protective equipment. Handle product carefully and shower after manipulation. Avoid contact with skin and eyes. Do not smoke. Storage areas should be kept well-protected, clean, cool and well ventilated. Install exhaust-fans for storage area and formulation plant ventilation. Avoid contamination of foodstuffs, animal feed, drinking water, fi sh hatcheries, lakes, rivers and canals. Empty packaging and reamanins of product should be disposed of in a responsible manner following all legal requirements. Symptoms of intoxication: Treatment should be symptomatic after decontamination. In case if skin or eyes contamination, treat as fi rst aid measures. First aid: Inhalation: move the victim to fresh air immediately. Skin contact: If skin contact occurs, remove contaminated clothing and fl ush skin with running water. Eye contact: If splashed in eyes, wash out immediately with water, if irritation persist get medical advice. Ingestion: do NOT induce vomiting. Antidote: No specifi c antidote is available. If poisoning is suspected apply symptomatic therapy. 6

7 Shelf life: for temperate climates: Two years from manufacturing date. for hot climates: Two years from manufacturing date. Storage & container disposal: Store in original container tightly closed and in a locked dry, cool, well ventilated area, away from foodstuffs. When stored appropriately this product should show no signifi cant degradation for 2 years from the date of manufacture. Contact your supplier for further information about the use of this product if it is older than this. 7